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Materials polymeric

The best known polymeric materials are natural rubber and synthetic rubber. These materials have low modulus of elasticity. The flexibility of these materials enables their application in tubing, belting and automotive tires as encountered in everyday usage. Resistance to chemicals, abrasive attack and insulating property can be advantageous in corrosion control applications. [Pg.300]

Naturally occurring rubber consists of a long-chain polymer with isoprene as the basic building unit. The rubber has high elasticity and a temperature limit of 160°F. Vulcanization consists of addition of elemental sulfur to rubber, followed by heating. The [Pg.300]

Some common elastomers with salient features are as follows 113 [Pg.301]

Ethylene propylene (Nordel) Epichlorhydrin (Hydrin) Fluoroelastomers (Viton) [Pg.301]

Close resemblance to neoprene with greater resistance to heat, ozone and some chemicals Similar to butyl rubber good resistance to ozone, heat, water, and sunlight [Pg.301]

Essentially all polymers freely exposed to the elements will change in some manner. The active rays of the sun become potent agents of change in the organic materials. Further polymerization of the resin can occur to produce embrittlement. Other types of new bonding can be triggered to make polymers more crystalline. Any volatile component of the material, such as a plasticizer, can be evaporated. The polymer chains may be simply oxidized and broken up to destroy the product. [Pg.381]

The external evidence of attack may be blushing (loss of gloss), chalking, change in color of the product, or extreme brittleness as in Fig. 9.52. These effects are often readily observed on epoxy and polyester polymers when they have been boldly exposed to the environment. However, mechanical tests will usually be required to reveal the extent of degradation of either thermoplastic or thermosetting resins unless they have been exposed for decades to direct sunlight, as in Fig. 9.52. [Pg.382]

The effect of high atmospheric temperatures or heating from direct exposure to the sun can be particularly severe on thermoplastic polymers. Creep or distension of the pol5winyl chloride and polyethylene plastics will occur readily unless provision is made to prevent overheating or stressing of the materials. [Pg.382]

Polymeric materials should be thoroughly tested if they are to be exposed freely in the atmosphere. ASTM Recommended Practice D1435 describes the appropriate conditions for such test exposures and suggests tests that might be used to evaluate changes in the materials. [Pg.382]

Changes in mechanical and physical properties of the polymers are determined for definitive results. Weight gains or losses may be of interest, but typically do not provide substantive results. [Pg.383]

The onset temperature of the exothermic decomposihon is about 432 K, and the re-achon is complete at about 480 K without a residue. The activation energy for the exothermic decomposition process ranges from 117 kj moh to 151 kj mokh [Pg.77]

medical applications (e.g., catheters, gloves, n inflatable splints) [Pg.350]

Food packaging, refrigerator trays, upholstery, carpets [Pg.350]

Tire treads/ sidewalls, golf ball n cores [Pg.350]

Hosiery, lingerie soft-sided luggage, upholstery [Pg.350]


Other series reactions form unwanted polymeric material. [Pg.52]

The Computation of Polymeric Material s Viscoelastic Properties by Dynamic Indentation Method. [Pg.239]

The paper discusses the application of dynamic indentation method and apparatus for the evaluation of viscoelastic properties of polymeric materials. The three-element model of viscoelastic material has been used to calculate the rigidity and the viscosity. Using a measurements of the indentation as a function of a current velocity change on impact with the material under test, the contact force and the displacement diagrams as a function of time are plotted. Experimental results of the testing of polyvinyl chloride cable coating by dynamic indentation method and data of the static tensile test are presented. [Pg.239]

The radiation and temperature dependent mechanical properties of viscoelastic materials (modulus and loss) are of great interest throughout the plastics, polymer, and rubber from initial design to routine production. There are a number of laboratory research instruments are available to determine these properties. All these hardness tests conducted on polymeric materials involve the penetration of the sample under consideration by loaded spheres or other geometric shapes [1]. Most of these tests are to some extent arbitrary because the penetration of an indenter into viscoelastic material increases with time. For example, standard durometer test (the "Shore A") is widely used to measure the static "hardness" or resistance to indentation. However, it does not measure basic material properties, and its results depend on the specimen geometry (it is difficult to make available the identity of the initial position of the devices on cylinder or spherical surfaces while measuring) and test conditions, and some arbitrary time must be selected to compare different materials. [Pg.239]

Obtained results allow to conclude that the dynamic indentation method can be applied to periodical express evaluation of polymeric material state being exposured to the radiation or temperature aging on purpose to early diagnostic of products to avoid emergency situations. [Pg.244]

The successful preparation of polymers is achieved only if tire macromolecules are stable. Polymers are often prepared in solution where entropy destabilizes large molecular assemblies. Therefore, monomers have to be strongly bonded togetlier. These links are best realized by covalent bonds. Moreover, reaction kinetics favourable to polymeric materials must be fast, so tliat high-molecular-weight materials can be produced in a reasonable time. The polymerization reaction must also be fast compared to side reactions tliat often hinder or preclude tire fonnation of the desired product. [Pg.2515]

An eiegant theoreticai treatise of poiymer physics which conveys an intuitive understanding of the behaviour of macromoiecuies. Charrier J-M 1990 Polymeric Materials and Processing Plastics, Elastomers and Composites (Munich Hanser)... [Pg.2542]

Computer modelling provides powerful and convenient tools for the quantitative analysis of fluid dynamics and heat transfer in non-Newtonian polymer flow systems. Therefore these techniques arc routmely used in the modern polymer industry to design and develop better and more efficient process equipment and operations. The main steps in the development of a computer model for a physical process, such as the flow and deformation of polymeric materials, can be summarized as ... [Pg.1]

About 2 X 10 Ib/year of 1 2 epoxypropane is produced in the United States as an intermediate in the preparation of various polymeric materials including polyurethane plastics and foams and polyester resins A large fraction of the 1 2 epoxypropane is made from propene by way of its chlorohydrm... [Pg.678]

The various elastic and viscoelastic phenomena we discuss in this chapter will be developed in stages. We begin with the simplest the case of a sample that displays a purely elastic response when deformed by simple elongation. On the basis of Hooke s law, we expect that the force of deformation—the stress—and the distortion that results-the strain-will be directly proportional, at least for small deformations. In addition, the energy spent to produce the deformation is recoverable The material snaps back when the force is released. We are interested in the molecular origin of this property for polymeric materials but, before we can get to that, we need to define the variables more quantitatively. [Pg.134]

We shall follow the same approach as the last section, starting with an examination of the predicted behavior of a Voigt model in a creep experiment. We should not be surprised to discover that the model oversimplifies the behavior of actual polymeric materials. We shall continue to use a shear experiment as the basis for discussion, although a creep experiment could be carried out in either a tension or shear mode. Again we begin by assuming that the Hookean spring in the model is characterized by a modulus G, and the Newtonian dash-pot by a viscosity 77. ... [Pg.168]

In the last three chapters we have examined the mechanical properties of bulk polymers. Although the structure of individual molecules has not been our primary concern, we have sought to understand the influence of molecular properties on the mechanical behavior of polymeric materials. We have seen, for example, how the viscosity of a liquid polymer depends on the substituents along the chain backbone, how the elasticity depends on crosslinking, and how the crystallinity depends on the stereoregularity of the polymer. In the preceding chapters we took the existence of these polymers for granted and focused attention on their bulk behavior. In the next three chapters these priorities are reversed Our main concern is some of the reactions which produce polymers and the structures of the products formed. [Pg.264]

We noted above that the presence of monomer with a functionality greater than 2 results in branched polymer chains. This in turn produces a three-dimensional network of polymer under certain circumstances. The solubility and mechanical behavior of such materials depend critically on whether the extent of polymerization is above or below the threshold for the formation of this network. The threshold is described as the gel point, since the reaction mixture sets up or gels at this point. We have previously introduced the term thermosetting to describe these cross-linked polymeric materials. Because their mechanical properties are largely unaffected by temperature variations-in contrast to thermoplastic materials which become more fluid on heating-step-growth polymers that exceed the gel point are widely used as engineering materials. [Pg.314]

The search for substances which quahfy for proposed applications has always been a driving force for the synthesis and characterization of new compounds. This is especially true in polymer chemistry, where it is the potential of polymers as engineering materials that often stimulates research. Polymeric materials frequently fail to be serviceable in engineering applications for one of the following reasons ... [Pg.334]

Note that this method of standardizing D values makes no allowance for the possibility that a molecule may change size, shape, or solvation with changes in temperature. In the next section we shall survey the behavior of polymeric materials in an ultracentrifuge. We shall see that diffusion coefficients can be... [Pg.634]

Polymeric materials are unique owing to the presence of a glass-transition temperature. At the glass-transition temperatures, the specific volume of the material and its rate of change changes, thus, affecting a multitude of physical properties. Numerous types of devices could be developed based on this type of stimuli—response behavior however, this technology is beyond the scope of this article. [Pg.250]

Sonochemistry is also proving to have important applications with polymeric materials. Substantial work has been accomplished in the sonochemical initiation of polymerisation and in the modification of polymers after synthesis (3,5). The use of sonolysis to create radicals which function as radical initiators has been well explored. Similarly the use of sonochemicaHy prepared radicals and other reactive species to modify the surface properties of polymers is being developed, particularly by G. Price. Other effects of ultrasound on long chain polymers tend to be mechanical cleavage, which produces relatively uniform size distributions of shorter chain lengths. [Pg.263]

Table 3. Adhesive Bond Properties of 2-Cyanoacrylic Esters with Metals and Various Polymeric Materials... Table 3. Adhesive Bond Properties of 2-Cyanoacrylic Esters with Metals and Various Polymeric Materials...
Diffusion Theory. The diffusion theory of adhesion is mosdy appHed to polymers. It assumes mutual solubiUty of the adherend and adhesive to form a tme iaterphase. The solubiUty parameter, the square root of the cohesive eaergy deasity of a material, provides a measure of the iatermolecular iateractioas occurring within the material. ThermodyaamicaHy, solutioas of two materials are most likely to occur whea the solubiUty parameter of oae material is equal to that of the other. Thus, the observatioa that "like dissolves like." Ia other words, the adhesioa betweea two polymeric materials, oae an adherend, the other an adhesive, is maximized when the solubiUty parameters of the two are matched ie, the best practical adhesion is obtained when there is mutual solubiUty between adhesive and adherend. The diffusion theory is not appHcable to substantially dissimilar materials, such as polymers on metals, and is normally not appHcable to adhesion between substantially dissimilar polymers. [Pg.229]

Health and safety information is available from the manufacturer of every adhesive sold in the United States. The toxicology of a particular adhesive is dependent upon its components, which mn the gamut of polymeric materials from natural products which often exhibit low toxicity to isocyanates which can cause severe allergic reactions. Toxicological information may be found in articles discussing the manufacture of the specific chemical compounds that comprise the adhesives. [Pg.236]


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A. Akelah, Functionalized Polymeric Materials in Agriculture and the Food Industry

Abbreviations Polymeric Materials

Advanced Polymeric Materials

Advanced specialty polymeric materials

Amorphous carbon materials polymeric carbons

Analytical Pyrolysis of Polymeric Materials with Lipid Moieties

Animal polymeric materials

Asbestos polymeric material

Atom transfer radical polymerization materials

Azopolymers polymeric materials

Bioartificial materials polymerization

Biobased and Biodegradation Standards for Polymeric Materials

Biobased polymeric materials

Biobased polymeric materials others

Biobased polymeric materials product

Biodegradable polymeric materials

Biodegradable water-soluble polymers Polymeric materials

Bioresorbable polymeric materials

Bioresorbable polymeric materials natural polymers

Blends, composites and multiphase polymeric materials

Carbon arcs, polymeric materials

Carbon materials polymeric carbons

Carbon-based materials electrochemical polymerization

Catalyzed ring-opening polymerization materials

Characterization of polymeric materials

Chemical Modification of Polymeric Materials

Chemical morphology of multi-component polymeric materials

Chemically Unstable Materials Decomposition and Polymerization

Clothing and Shelters Polymeric Material

Combustion of Crystalline and Polymeric Materials

Combustion of Polymeric Materials

Conductive polymeric materials

Configurations and Crystallinity of Polymeric Materials

Contact lenses polymeric materials

Creep behaviour polymeric materials

Crystalline and Polymeric Materials

Degradation of polymeric materials

Dielectric properties, polymeric materials

Diffusion in Polymeric Materials

Dyeing of Polymeric Materials

Electro-optic polymeric materials

Electrochromic device polymeric materials

Electrode materials polyaniline electrochemical polymerization

Electron-beam curing of polymeric materials

Emulsion-polymerized material

Energetic materials polymeric

Environmental Stability and Degradation Mechanisms of Polymeric Materials

Enzymatic polymerization materials

Evaluation of Supercritical Fluid Interactions with Polymeric Materials

Extracellular polymeric material

FTIR - An Essential Characterization Technique for Polymeric Materials

FTIR Imaging of Polymeric Materials

Failure Analysis of Polymeric Materials

Fire polymeric materials

Fire resistant polymeric materials

Flame retardant polymeric materials

Flame retardation polymeric materials

Fluorinated materials, plasma polymerization

Forming of polymeric materials

Fraction polymerized material

Free volume polymeric material

Fundamental Characteristics of Polymeric Materials

Fundamental Principles of Polymeric Materials, Third Edition. Christopher S. Brazel and Stephen L. Rosen

Heating and Cooling of Nondeforming Polymeric Materials

Heterogeneous polymeric material

High-performance polymeric materials for separation and reaction, prepared by radiation-induced graft polymerization

High-tonnage polymeric materials

Hindered amine light stabilizers polymeric materials

History of polymeric materials

Hydroperoxide decomposers, polymeric material stabilization

Hydrophilicity or Hydrophobicity of Polymeric Materials and Their Behavior toward Protein Adsorption

In Nonlinear Optical Properties of Organic and Polymeric Materials Williams

In Nonlinear Optical Properties of Organic and Polymeric Materials Williams ACS Symposium Series American Chemical Society: Washington

In situ Polymerized Materials

In situ crosslinking or polymerizing materials

Indicator product analysis polymeric materials

Intumescence and Nanocomposites a Novel Route for Flame-Retarding Polymeric Materials

Irradiation polymeric materials

Lignin-based polymeric materials

Lignin-based polymeric materials preparation

Lipid-derived polymeric material

Liquids Gelation with Polymeric Materials The Ion Jelly Approach

Materials and Polymeric Combinatorial Libraries

Materials polymeric, self-reinforced

Materials polymerization

Materials polymerization

Materials polymerization Laser

Mechanical properties of polymeric materials

Mesoporous materials, polymerization

Microfiltration polymeric materials

Microfluidic chips polymeric materials

Migration from Polymeric Food Contact Material

Moisture polymeric materials

Molding of polymeric materials

Molecular engineering polymeric materials

Monomer and Solvent Rests in Polymeric Materials

Multicomponent Polymeric Materials

Natural Polymeric Material

New Polymeric Materials Derived from Industrial Lignins and Related Biomass

Non-polymeric materials

Non-polymeric thiophene organic materials

Nonlinear materials polymeric devices

Nonlinear viscoelasticity, polymeric materials

Optic polymerization materials

Organic molecular crystals polymeric materials

Orthopedics, biodegradable polymeric materials

Oxygen polymeric materials

Ozone, polymeric materials

POLYMERIC MATERIALS FOR CORROSION CONTROL

Patterning Polymeric and Organic Materials

Photochemical Reactions in Polymeric Materials

Physical properties of polymeric materials

Physicochemical Properties of Polymeric Materials

Plasma deposition polymerization, surface materials

Pollution polymeric materials

Polylactic acid, biodegradable polymeric materials

Polymer nanocomposites polymeric materials

Polymer, chemical physics polymeric material formation

Polymeric (Amorphous) Materials

Polymeric Bionanocomposites as Promising Materials for Controlled Drug Delivery

Polymeric Materials Are Elastic

Polymeric Materials Composition, Uses and Applications

Polymeric Materials and Interfaces

Polymeric Materials and Interfaces Laboratory

Polymeric Materials for Surface Modification

Polymeric Materials in Organic Synthesis and Catalysis

Polymeric Materials with Ionic Functional Groups and Their Protein Adsorptive Behavior

Polymeric Membrane Materials and Potential Use in Gas Separation

Polymeric Waveguide Materials for Integrated Optics

Polymeric composite materials

Polymeric electrooptic material

Polymeric inert material

Polymeric liquid crystalline material

Polymeric material compositional analyses

Polymeric material elements

Polymeric material flexural properties

Polymeric material properties

Polymeric material service performance

Polymeric material specific volume

Polymeric material thermal expansion

Polymeric material, characterization

Polymeric material, fibrillar

Polymeric materials Biodegradable polymers

Polymeric materials Biodegradable water-soluble

Polymeric materials Block copolymers

Polymeric materials PAHs)

Polymeric materials Polymerization, modeling

Polymeric materials aging

Polymeric materials aliphatic polyamides

Polymeric materials aluminum

Polymeric materials aromatic polyamides

Polymeric materials atmospheric corrosion

Polymeric materials atmospheric pollutants

Polymeric materials biodegradation assessment

Polymeric materials compared

Polymeric materials connection between molecular

Polymeric materials containing finely

Polymeric materials degradation mechanisms

Polymeric materials dendrimers

Polymeric materials densification

Polymeric materials elastomers

Polymeric materials electrically conductive

Polymeric materials environmental weathering tests

Polymeric materials failure analysis

Polymeric materials for electronics packaging

Polymeric materials for electronics packaging and interconnection

Polymeric materials from natural resource

Polymeric materials generally

Polymeric materials glassy

Polymeric materials impedance measurements

Polymeric materials irradiance

Polymeric materials laboratory-accelerated weathering tests

Polymeric materials light sources

Polymeric materials macroscopic scale changes

Polymeric materials nature

Polymeric materials overview

Polymeric materials polyamides

Polymeric materials polycarbonate

Polymeric materials polycarbonates

Polymeric materials polyesters

Polymeric materials polyethylene

Polymeric materials polymers Ruthenium complex

Polymeric materials polyolefins

Polymeric materials polypropylene

Polymeric materials polystyrene

Polymeric materials polystyrene beads

Polymeric materials polyurethanes

Polymeric materials polyvinyl alcohol

Polymeric materials polyvinyl chloride

Polymeric materials production

Polymeric materials research opportunities

Polymeric materials rigid foam

Polymeric materials rubbery

Polymeric materials science and engineering

Polymeric materials solar radiation

Polymeric materials stabilization methods

Polymeric materials stabilizer types

Polymeric materials structure

Polymeric materials styrenic polymers

Polymeric materials synthesizing

Polymeric materials techniques

Polymeric materials temperature

Polymeric materials testing

Polymeric materials that

Polymeric materials useful lifetime

Polymeric materials weather factors

Polymeric materials with high

Polymeric materials, advantages

Polymeric materials, advantages nonlinear optical material

Polymeric materials, columns

Polymeric materials, combustion

Polymeric materials, controlled synthesis

Polymeric materials, core electron

Polymeric materials, functionalization

Polymeric materials, influence

Polymeric materials, limitations

Polymeric materials, molecular

Polymeric materials, monomer/solvent

Polymeric materials, polarizability

Polymeric materials, requirements imposed

Polymeric materials, stress

Polymeric materials, thermal

Polymeric materials, thermal decomposition studies

Polymeric materials, viii

Polymeric materials/polymers

Polymeric materials/polymers Kevlar

Polymeric materials/polymers acrylate

Polymeric materials/polymers aramid

Polymeric materials/polymers automotive applications

Polymeric materials/polymers chemical engineering contributions

Polymeric materials/polymers composites

Polymeric materials/polymers elastomeric

Polymeric materials/polymers electrically active

Polymeric materials/polymers glassy

Polymeric materials/polymers methacrylate

Polymeric materials/polymers molecular design

Polymeric materials/polymers multicomponent blends

Polymeric materials/polymers optoelectronic applications

Polymeric materials/polymers photoresists

Polymeric matrix materials

Polymeric metal complexes materials based

Polymeric monolithic material

Polymeric nonlinear optical materials

Polymeric packing materials

Polymeric solid materials

Polymeric wire insulation materials

Polymerization electrode materials

Polymerization fabrication, materials selection

Polymerization of Langmuir-Blodgett materials

Polymerization organic-inorganic hybrid materials

Polymerized materials

Polymerized materials

Polymers polymeric materials biodegradability

Polymers polymeric silica-based materials

Predicting Elevated Temperature Ratings of Polymeric Materials

Preparation of Polymeric Materials

Preparation of Synthetic Polymeric Materials

Properties of Polymeric Materials

RADIATION CURING OF POLYMERIC MATERIALS

REX Synthesis of PLA-based Materials via Ring-opening Polymerization

Relative Thermal Stability of Polymeric Materials

Rheological Properties of Polymeric Materials

Rheology and Viscoelasticity of Polymeric Materials

Ring-opening polymerizations materials

Role of polymeric materials

SUPRAMOLECULAR POLYMERIZATION OF PEPTIDES AND PEPTIDE DERIVATIVES NANOFIBROUS MATERIALS

Selection of polymeric packaging materials

Self-Doped Polymers, Polymeric Composites, and Hybrid Materials

Self-healing materials polymeric systems

Self-repairing polymeric materials

Self-reporting Polymeric Materials with Mechanochromic Properties

Solid-state nuclear magnetic resonance polymeric material

Solvent-Stable Polymeric Membrane Materials

Stabilization of Polymeric Materials Against Environmental Effects

Starch as Source of Polymeric Materials

Stiffness Analysis of Solid Polymeric Materials

Supercritical carbon dioxide polymeric materials

Supramolecular organic polymeric materials

Surface chemical modification polymeric materials, plasma

Sustainability, biobased polymeric materials

Synthesis of polymeric materials

Synthetic polymeric materials

Tensile strength of polymeric materials

Test for polymeric materials

Testing of Polymeric Materials

The Hierarchical Structure of Polymeric Materials

The Modulus of Multicomponent Polymeric Materials

The Morphology of Multiphase Polymeric Materials

Thermal Characterization of Polymeric Materials

Thermal properties, polymeric materials

Thermal properties, polymeric materials differential scanning calorimetry

Thermal properties, polymeric materials diffusivity

Thermal properties, polymeric materials overview

Thermal properties, polymeric materials thermomechanical analysis

Thermal stability of polymeric materials

Thermoplastics Polymeric Materials

Thermoplastics Polymeric materials specific

Thermoresponsive materials radical polymerization

Thermoset Polymeric Materials

Ultraviolet absorbers, polymeric material

Ultraviolet absorbers, polymeric material stabilization

Ultraviolet radiation polymeric materials

Vegetable polymeric materials

Viscoelasticity polymeric materials

Waveguide polymeric materials, property

Waveguide structures by ion irradiation of polymeric materials

Weathering polymeric materials effects

Weathering, polymeric materials

Woven geotextile from polymeric materials

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