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Salient Features

The ECPs are a class of conjugated polymers, which possess intrinsic electronic conductivity. This intrinsic electronic conductivity has envisaged their use in various electronic devices. [Pg.230]

Research is ongoing in the field of ECPs in order to discover various new polymers in this field, which shows the increased demand for these specialty conjugated polymers. It is necessary to use effective and stable dopants with the conducting polymers for the enhancement of their properties [1-4]. Conjugated polymers with good electronic conductivity have opened the door to various electronic devices. Various ECPs used nowadays are polyaniline, polypyrrole, polythiophene, polyacetylene, and their derivatives. The major advantages of these polymers are good electronic [Pg.230]

The ECPs are synthesized from their monomer units by a variety of techniques. Monomer units are joined together to form the polymer chain network, which constitutes the formation of ECPs. Various procedures are available for the synthesis, which include (i) chemical polymerization, (ii) electrochemical polymerization, and (iii) photopolymerization. [Pg.231]

Any variation in these parameters may lead to a change in the properties of the polymer product. [Pg.232]

In this method, electric field-assisted polymerization of monomer units takes place over the electrically conducting substrate. Any electrically conductive substrate can be used for the same purpose like metal plate, steel plate, etc. Application of electric field results in the formation of polymer chains. The electric field can be adjusted in two ways either in terms of electric potential or in terms of electric current. There will be a threshold potential for the polymerization to start. Knowledge on this optimal potential is mandatory for the polymer synthesis as the potential may be different for different polymers. For different nanostructures such as nanoparticles, thin films, etc., there should be proper optimization in various parameters such as electric field, processing time, temperature, and the process atmosphere. Any variation in these parameters may lead to a change in size and shape of the polymer. For example, in a prolonged elec-tropolymerization process, thick polymeric films are formed. [Pg.232]


A salient feature of natural surfaces is tliat tliey are overwhelmingly electron donors [133]. This is tlie basis for tlie ubiquitous hydrophilic repulsion which ensures tliat a cell can function, since massive protein-protein aggregation and protein-membrane adsorjition is tliereby prevented. In fact, for biomolecule interactions under typical physiological conditions, i.e. aqueous solutions of moderately high ionic strengtli, tlie donor-acceptor energy dominates. [Pg.2839]

In this section, only salient features of the synthesis, physicochemical properties, and reactivity of major derivatives of 2-aminothiazole and 2-imino-4-thiazoline are summarized. Further details on each compound are found in associated references collected in Section VII. The synthetic methods reported in this section exclude heterocydization methods treated in Chapter II but given in specific references found in Section VII. [Pg.90]

The hydrophobic character exhibited by dehydroxylated silica is not shared by the metal oxides on which detailed adsorption studies have been made, in particular the oxides of Al, Cr, Fe, Mg, Ti and Zn. With these oxides, the progressive removal of chemisorbed water leads to an increase, rather than a decrease, in the affinity for water. In recent years much attention has been devoted, notably by use of spectroscopic and adsorption techniques, to the elucidation of the mechanism of the physisorption and chemisorption of water by those oxides the following brief account brings out some of the salient features. [Pg.274]

Blood Calcium Ion Level. In normal adults, the blood Ca " level is estabhshed by an equiUbrium between blood Ca " and the more soluble intercrystalline calcium salts of the bone. Additionally, a subtle and intricate feedback mechanism responsive to the Ca " concentration of the blood that involves the less soluble crystalline hydroxyapatite comes into play. The thyroid and parathyroid glands, the fiver, kidney, and intestine also participate in Ca " control. The salient features of this mechanism are summarized in Figure 2 (29—31). [Pg.376]

The figures given in the table are obtained on mouldings relatively free from orientation and tested under closely controlled conditions of temperature, testing rate, and humidity. Changes in these conditions or the use of additives may profoundly affect these properties. Details of the influence of these factors on mechanical properties have been published in the trade literature but Figures 18.11-18.14 have been included to illustrate some salient features. [Pg.490]

A salient feature of the fluidized bed reactor is that it operates at nearly constant temperature and is, therefore, easy to control. Also, there is no opportunity for hot spots (a condition where a small increase in the wall temperature causes the temperature in a certain region of the reactor to increase rapidly, resulting in uncontrollable reactions) to develop as in the case of the fixed bed reactor. However, the fluidized bed is not as flexible as the fixed bed in adding or removing heat. The loss of catalyst due to carryover with the gas stream from the reactor and regenerator may cause problems. In this case, particle attrition reduces their size to such an extent where they are no longer fluidized, but instead flow with the gas stream. If this occurs, cyclone separators placed in the effluent lines from the reactor and the regenerator can recover the fine particles. These cyclones remove the majority of the entrained equilibrium size catalyst particles and smaller fines. The catalyst fines are attrition products caused by... [Pg.234]

There are many gas turbine CHP plants in operation for a range of purposes and applications. Here we describe the salient features of two such plants, each operating with a WHR but also with supplementary firing which can be introduced to meet increased heat demands. [Pg.177]

Here are the salient features from a typical Gaussian98 run on ethene at the HF/6-311G level of theory, using the Z-matrix option (Figure 14.3). I have forced D2h symmetry by setting all the C-H bonds equal, all HCC bond angles equal and all azimuthal angles equal. [Pg.242]

This chapter introduces the basic items of design and specification for the principal systems and components of an electrical industrial installation. Electrical supply systems are discussed with regard to interface with the supply authorities and the characteristics. Salient features of switchgear, transformers, protection systems, power factor correction, motor control equipment and standby supplies are identified and discussed together with reference to the relevant codes of practice and standards. The equipment and systems described are appropriate to industrial plant installations operating at typically 11 kV with supply capacities of around 20MVA. [Pg.210]

The exact details of industrial maximum demand tariffs vary between supply authorities. However, the salient features of most tariffs are as follows ... [Pg.210]

It would take us too far out of our way to explore the territory opened up by this way of looking at Polya s Theorem, but we can take a quick look at the view and pick out some of the salient features. The cycle index, in its new clothes, is expressible in terms of -functions conversely, an 5-function can be regarded as a sort of cycle index. The 5-function for a partition can be defined by... [Pg.122]

Half-wave potentials. The salient features of a typical current-applied voltage curve (polarogram) are shown in Fig. 16.4. [Pg.598]

The glycal epoxide method turned out to be useful for the construction of complex 2-branched [3-aryl glycosides, which are salient features of the potent antibiotic vancomycin [75a]. Glycal epoxide glycosylation with sodium salts of indoles pro-... [Pg.299]

No single mechanistic explanation of the S— T effect has been accepted as possessing general validity the salient features of the several alternative reaction models which remain under discussion are summarized below. There also exist the possibilities that there may be concurrent, consecutive or intermediate behaviour and that different mechanisms may operate for different solids. [Pg.126]

The flow patterns for single phase, Newtonian and non-Newtonian liquids in tanks agitated by various types of impeller have been repotted in the literature.1 3 27 38 39) The experimental techniques which have been employed include the introduction of tracer liquids, neutrally buoyant particles or hydrogen bubbles, and measurement of local velocities by means of Pitot tubes, laser-doppler anemometers, and so on. The salient features of the flow patterns encountered with propellers and disc turbines are shown in Figures 7.9 and 7.10. [Pg.294]

The basic idea of the pseudopotential theory is to replace the strong electron-ion potential by a much weaker potential - a pseudopotential that can describe the salient features of the valence electrons which determine most physical properties of molecules to a much greater extent than the core electrons do. Within the pseudopotential approximation, the core electrons are totally ignored and only the behaviour of the valence electrons outside the core region is considered as important and is described as accurately as possible [54]. Thus the core electrons and the strong ionic potential are replaced by a much weaker pseudopotential which acts on the associated valence pseudo wave functions rather than the real valence wave functions (p ). As... [Pg.19]

The mechanical concepts of stress are outlined in Fig. 1, with the axes reversed from that employed by mechanical engineers. The three salient features of a stress-strain response curve are shown in Fig. la. Initial increases in stress cause small strains but beyond a threshold, the yield stress, increasing stress causes ever increasing strains until the ultimate stress, at which point fracture occurs. The concept of the yield stress is more clearly realised when material is subjected to a stress and then relaxed to zero stress (Fig. Ih). In this case a strain is developed but is reversed perfectly - elastically - to zero strain at zero stress. In contrast, when the applied stress exceeds the yield stress (Fig. Ic) and the stress relaxes to zero, the strain does not return to zero. The material has irreversibly -plastically - extended. The extent of this plastic strain defines the residual strain. [Pg.11]

The salient features of the recent development and future trends in all areas of tire technology, i.e., materials, technology, and manufacmring, wiU be covered in the following sections. [Pg.920]

Many, if not most, of the key reactions of chemistry are second-order reactions, and understanding this type of reaction is central to understanding chemical kinetics. Cellular automata models of second-order reactions are therefore very important they can illustrate the salient features of these reactions and greatly aid in this understanding. [Pg.126]

Once a smooth signal has been constructed, how is the trend represented Most of the available techniques do not provide a framework for the representation (and thus, interpretation) of trends, because their representations (in the frequency or time domains) do not include primitives that capture the salient features of a trend, such as continuity, discontinuity, linearity, extremity, singularity, and locality. In other words, most of the approaches used to represent process signals are in fact data compaction techniques, rather than trend representation approaches. Furthermore, whether an approach employs a frequency or a time-domain representation, it must make several major decisions before the data are compacted. For frequency-domain representations, assumptions about the... [Pg.212]

While in this short space we have barely touched upon the salient features of this reaction, we hope it has been sufficient to wet the readers appetite to pursue the subject in more detail. This new approach to studying catalytic reactions is opening up major new avenues for their understanding. [Pg.220]

The salient features of surface analysis by ESCA of the oxidized ternary alloys are In general agreement with the results In the case of the binary Nl Th system. NIO, FCjO, and Th02 are the predoml-... [Pg.312]

This contribution Is concerned with the magnetic and Mossbauer characterization of (a) Fe/zeollte (mordenlte) systems, and that of (b) Fe and/or Ru on boron-doped carbon substrates. Some correlations between the characterization and CO hydrogenation parameters will be pointed out. Because of limitations of space, we shall present salient features of these Investigations. At the outset. It would be befitting to present a succinct background on the basic principles of magnetic and Mossbauer characterization. [Pg.499]

An alternative to most of these mechanisms is the existence of efficient efflux systems, so that toxic concentrations of the drug are not achieved. There are three major families of proton-dependent multidrug efflux systems (1) the major facilitator superfamily, (2) the small multidrug resistance family, and (3) the resistance/nodulation/cell division family (Paulsen et al. 1996). It should be emphasized that several of these systems are involved not with antibiotic efflux but with, for example, acriflavine, chlorhexidine, and crystal violet. An attempt is made only to outline a few salient features of the resistance/nodulation/cell division family that mediates antibiotic efflux, and these are given in Table 3.3 (Nikaido 1996). They consist of a transporter, a linker, and an outer membrane channel. [Pg.171]


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