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High screen

The second possibility (the direct magnetic effect of currents in Y) is shown to depend on the anisotropy of the magnetic susceptibility of Y. Quantitatively this shift is usually small, although it may account for the shift to high screening when some protons associate with an aromatic system, which has a large anisotropy due to the mobile electrons,... [Pg.71]

In the limit of high the electrostatic contributions are highly screened so that the chemical Interactions x X become important no adsorption occurs... [Pg.696]

Once candidate library members have been chosen, they must be validated by experiment. For each library member, the chemical structure is verified, the purity of the sample determined, and aqueous solubility measured. In addition, the fragments should be tested for their potential to aggregate at the high screening concentrations used for fragment-based NMR screening [51]. DMSO-d6 stock solutions of the library must be plated and stored in a way that minimizes freeze/... [Pg.91]

In the copolymer case, the simplest realistic model is as nsnal to have A monomers with probability p and B monomers with probability 1 — p. Then instead of jnst considering interactions between nearest neighbonr contacts, as in the homopolymer case, we associate different energies to AA, BB and AB contacts. Typically, one allows like monomers to attract and nnlike monomers to repel, or vice versa. In the former case we have a model of hydrophilic and hydrophobic monomers, and in the latter case we have a model of a highly screened Coulomb system. [Pg.63]

The value of Xy = 0 would foresee a high screen efficiency. Substituting values in Equation 9.8 ... [Pg.293]

The formation of bilayer vesicles was also observed for dialkyldimethylammonium bromide 33 in ether-containing ionic liquids 26, 27 (Figure 24) [124]. Ionic amphiphiles intrinsically possess solvophilic (or ionophilic) groups and electrostatic repulsions between them are highly screened in ionic liquids. In addition, the presence of ether-linkages in ionic liquids increases their net polarity. These factors contribute to enhance the association force of ammonium amphiphiles in ionic liquids and concurrently increase the thermal stability of gel(crystalline) state bilayers [124]. [Pg.503]

The initial surface charge is calculated with eq. /3/ using values obtained at low and at high screening on our experimental non-binding curves, and the mean value for is determined. This value is introduced in a computer program to fix the concentration domains where the error is minimal. [Pg.361]

In contrast, the polypeptides are assembled at neutral pH and in the presence of salt, where the charges of the NG and the PEs are highly screened. Consequently, the electrostatic attraction between the template and the PLL is considerably weaker than the NG-CHIT interaction, and the decrease in size is less drastic. Moreover, secondary cooperative interactions play a very important role in the assembly process. Upon adsorption of the PGA layer, both biopolymers also interact through H-bonds and hydrophobic interactions. To achieve the electrical neutrality required... [Pg.209]


See other pages where High screen is mentioned: [Pg.258]    [Pg.158]    [Pg.27]    [Pg.43]    [Pg.403]    [Pg.190]    [Pg.150]    [Pg.385]    [Pg.571]    [Pg.341]    [Pg.210]    [Pg.120]    [Pg.1717]    [Pg.1728]    [Pg.482]    [Pg.36]    [Pg.277]    [Pg.323]    [Pg.5]    [Pg.158]    [Pg.4834]    [Pg.262]    [Pg.198]    [Pg.627]    [Pg.170]    [Pg.115]    [Pg.369]    [Pg.361]   
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