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Self-assembly monolayers

A logical division is made for the adsorption of nonelectrolytes according to whether they are in dilute or concentrated solution. In dilute solutions, the treatment is very similar to that for gas adsorption, whereas in concentrated binary mixtures the role of the solvent becomes more explicit. An important class of adsorbed materials, self-assembling monolayers, are briefly reviewed along with an overview of the essential features of polymer adsorption. The adsorption of electrolytes is treated briefly, mainly in terms of the exchange of components in an electrical double layer. [Pg.390]

As discussed in Chapter III, the progression in adsoiptivities along a homologous series can be understood in terms of a constant increment of work of adsorption with each additional CH2 group. This is seen in self-assembling monolayers discussed in Section XI-IB. The film pressure r may be calculated from the adsorption isotherm by means of Eq. XI-7 as modified for adsorption from dilute solution ... [Pg.394]

Deposited Langmuir-Blodgett films take on many of the same stmctures as the Langmuir monolayers discussed in Section IV-4C, and they are often compared to the self-assembling monolayers described in Section XI-IB. The area... [Pg.558]

Investigate the differences between LB films and self-assembled monolayer SAMs (Chapter XI). Which are finding more practical use, and what are the potential applications of each ... [Pg.563]

Freunscht P, Van Duyne R P and Schneider S 1997 Surface-enhanced Raman spectroscopy of trans-stilbene adsorbed on platinum- or self-assembled monolayer-modified silver film over nanosphere surfaces Chem. Phys. Lett. 281 372-8... [Pg.1228]

Straniok S J, Parikh A N, Tao Y-T, Allara D L and Weiss P S 1994 Phase separation of mixed-oomposition self-assembled monolayers into nanometer soale moleoular domains J. Phys. Chem. 98 7636... [Pg.1722]

Salmeron M, Neubauer G, Folch A, Tomitori M, Ogletree D F and Sautet P 1993 Viscoelastic and electrical properties of self-assembled monolayers on Au(111) films Langmuirs 3600... [Pg.1726]

Salmeron M, Liu G-Y and Ogletree D F 1995 Molecular arrangement and mechanical stability of self-assembled monolayers on Au(111) under applied load Force in Scanning Probe Methods ed H-J Guntherodt et al (Amsterdam Kluwer)... [Pg.1726]

Figure Bl.22.3. RAIRS data in the C-H stretching region from two different self-assembled monolayers, namely, from a monolayer of dioctadecyldisulfide (ODS) on gold (bottom), and from a monolayer of octadecyltrichlorosilane (OTS) on silicon (top). Although the RAIRS surface selection rules for non-metallic substrates are more complex than those which apply to metals, they can still be used to detemiine adsorption geometries. The spectra shown here were, in fact, analysed to yield the tilt (a) and twist (p) angles of the molecular chains in each case with respect to the surface plane (the resulting values are also given in the figure) [40]. Figure Bl.22.3. RAIRS data in the C-H stretching region from two different self-assembled monolayers, namely, from a monolayer of dioctadecyldisulfide (ODS) on gold (bottom), and from a monolayer of octadecyltrichlorosilane (OTS) on silicon (top). Although the RAIRS surface selection rules for non-metallic substrates are more complex than those which apply to metals, they can still be used to detemiine adsorption geometries. The spectra shown here were, in fact, analysed to yield the tilt (a) and twist (p) angles of the molecular chains in each case with respect to the surface plane (the resulting values are also given in the figure) [40].
C2.4 Organics films (Langmuir-Blodgett films and self-assembled monolayers)... [Pg.2608]

Self-assembled monolayers (SAMs) are molecular layers tliat fonn spontaneously upon adsorjDtion by immersing a substrate into a dilute solution of tire surface-active material in an organic solvent [115]. This is probably tire most comprehensive definition and includes compounds tliat adsorb spontaneously but are neither specifically bonded to tire substrate nor have intennolecular interactions which force tire molecules to organize tliemselves in tire sense tliat a defined orientation is adopted. Some polymers, for example, belong to tliis class. They might be attached to tire substrate via weak van der Waals interactions only. [Pg.2620]

Gao W, Dickinson L, Grozinger C, Morin F G and Reven L 1996 Self-assembled monolayers of alkylphosphonic acids on metal oxides Langmuir M 6429-35... [Pg.2635]

Sheen C W, Martensson J, Shi J, Parikh A N and Allara D L A 1992 New class of organized self-assembled monolayers—alkane thiols on GaAs(IOO) J. Am. Chem. Soc. 114 1514-5... [Pg.2635]

Aronoff Y G, Chen B, Lu G, Seto C, Schwartz J and Bernasek S L 1997 Stabilization of self-assembled monolayers of carboxylic acids on native oxides of metals J. Am. Chem. Soc. 119 259-62... [Pg.2635]

Laibinis P E, Flickman J J, Wrighton M S and Whitesides G M 1989 Orthogonal self-assembled monolayers— alkanethiols on gold and alkane carboxylic-acids on alumina Science 245 845-7... [Pg.2635]

Folkers J P, Gorman C B, Laibinis P E, Buchholz S and Whitesides G M 1995 Self-assembled monolayers of long-chain hydroxamic acids on the native oxides of metals Langmuir 813-24... [Pg.2635]

Woodward J T, Ulman A and Schwartz D K Self-assembled monolayer growth of octadecylphosphonic acid on mica Langmuir 12 3626-9... [Pg.2635]

Deiamarche E, Michei B, Biebuyck FI A and Gerber C 1996 Golden interfaces the surface of self-assembled monolayers Adv. Mater. 8 719-29... [Pg.2636]

Kumar A, Biebuyok FI A and Whitesides G M 1994 Patterning self-assembled monolayers—applioations in materials soienoe Langmuir 10 1498-511... [Pg.2637]

Wilbur J L, Kumar A, Kim E and Whitesides G M 1994 Miorofabrioation by mioroeontaot printing of self-assembled monolayers Adv. Mater. 6 600-4... [Pg.2637]

Pale-Grosdemange C, Simon E S, Prime K L and Whitesides G M 1991 Formation of self-assembled monolayers by ohemisorption of derivatives of oligo(ethylene glyool) of struoture FIS(CFl2),, (OCFl2CFl2)meta-OFI on gold J. Am. Chem. Soc. 113 12-20... [Pg.2639]

Flaussling L, Ringsdorf FI, Sohmitt F J and Knoll W Biotin-funotionalized self-assembled monolayers on gold— surfaoe-plasmon optioal studies of speoifio reoognition reaotions Langmuir 1837-40... [Pg.2639]

Spinke J, Liley M, Sohmitt F J, Guder FI J, Angermaier L and Knoll W 1993 Moieouiar reoognition at self-assembled monolayers—optimization of surfaoe funotionalization J. Chem. Phys. 99 7012-9... [Pg.2639]

Sohierbaum K D, Weiss T, Thoden van Velzen E U, Engbersen J F J, Reinhoudt D N and Gdpel W 1994 Moieouiar reoognition by self-assembled monolayers of oavitand reoeptors Sc/e/ ce 265 1413-5... [Pg.2639]

Harder P, Grunze M, Dahint R, Whitesides G M and Laibinis P E 1998 Molecular conformation in oligo(ethylene glycol)-terminated self-assembled monolayers on gold and silver surfaces determines their ability to resist protein adsorption J. Rhys. Chem. B 102 426-36... [Pg.2640]

Feldman K, Hahner G, Spencer N D, Harder P, and Grunze M 1999 Probing resistance to protein adsorption of oligo(ethylene glycol)-terminated self-assembled monolayers by scanning force microscopy J. Am. Chem. Soc. at press... [Pg.2640]

DiMilla P A, Folkers J P, Biebuyck H A, Harter R, Lopez G P and Whitesides G M 1994 Wetting and protein adsorption of the self-assembled monolayers of alkanethiolates which are supported on transparent films of gold J. Am. Chem. Soc. 116 2225-6... [Pg.2640]

Batchelder D N, Evans S D, Freeman T L, Haussling L, Ringsdorf H and Wolf H 1994 Self-assembled monolayers containing polydiacetylenes J. Am. Chem. See. 116 1050-3... [Pg.2641]

Koutsos V, van der Vegte E W, Grim PCM and Hadziioannou G Isolated polymer chains via mixed self-assembled monolayers morphology and friction studied by scanning force microscopy Macromolecules 116-23... [Pg.2641]

Hostetler M J, Stokes J J and Murray R W 1996 Infrared speotrosoopy of three-dimensional self-assembled monolayers n-alkanethiolate monolayers on gold oluster oompounds Langmuir M 3604... [Pg.2917]

Colvin V L, Goldstein A N and Alivisatos A P 1992 Semioonduotor nanoorystals oovalently bound to metal surfaoes using self-assembled monolayers J. Am. Chem. Soc. 114 5221... [Pg.2918]

Siepmann JI and IR McDonald 1993a. Domain Formation and System-size Dependence in Simulatio of Self-assembled Monolayers. Langmuir 9 2351-2355. [Pg.471]


See other pages where Self-assembly monolayers is mentioned: [Pg.2]    [Pg.358]    [Pg.370]    [Pg.394]    [Pg.394]    [Pg.406]    [Pg.466]    [Pg.1714]    [Pg.2609]    [Pg.2620]    [Pg.2639]    [Pg.2641]    [Pg.868]    [Pg.877]    [Pg.191]   
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See also in sourсe #XX -- [ Pg.177 ]

See also in sourсe #XX -- [ Pg.519 ]

See also in sourсe #XX -- [ Pg.404 ]




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Adhesion Self-assembled monolayers

Alkanethiol self-assembled monolayers

Alkanethiols, self-assembled monolayers

Assembled monolayers

Biomaterial self-assembled monolayers

Contact angle self-assembled monolayers

Design using self-assembled monolayers

Disulfides, self-assembled monolayers

Electroactive monolayers/multilayers self-assembly

Electroactive self-assembled monolayers, with

Electrochemical sensors self-assembled monolayers

Electrochemistry and Self-Assembled Monolayers

Electrochemistry on Self-assembled Monolayers

Fluorinated self-assembled monolayer

Fluorinated self-assembled monolayer SAM) film

Formation of Self-Assembled Monolayers

Gate self-assembled monolayer

General Factors Affecting the Behavior of Metals Deposited onto Self-Assembled Monolayers

Gold nanoparticles self-assembled monolayers

Gold surfaces, chromophores self-assembled monolayers

Grafting-from methods self-assembled monolayer

High-density self-assembled monolayers

Hydroxy-terminated self-assembled monolayers

Immunoassays and immunosensors, recent self-assembled monolayers

Interfacial reactions self-assembled monolayers

Langmuir—Blodgett deposition self-assembled monolayers

Low-density self-assembled monolayers

Macroscopic self-assembled monolayers

Mercaptoundecanoic acid, self-assembled monolayer

Microcontact Printing of Self-Assembled Monolayers

Molecular Recognition at LB Films and Self-Assembled Monolayers

Molecular self-assembled monolayer

Monolayer assembly

Monolayer self-assembled

Monolayer, self-assembling

Monolayer, self-assembling

Monolayers, self-assembled, nucleation

N-Alkanoic acid self-assembled monolayers

Nanoparticle-based corrosion inhibitors and self-assembled monolayers

Nanoparticles and self-assembled monolayers

Nanopores in Self-Assembled Monolayers

Organic reactions, self-assembled monolayers

Patterned Self-assembled Monolayers

Patterned self-assembling monolayers

Polymer brushes self-assembled monolayers

Polymers patterned self-assembling monolayers

Preparation of Self-Assembled Monolayers

SAM = self-assembled monolayer

Selectivity self-assembled” monolayers

Self assembled monolayers chemical transformations

Self assembled monolayers computational studies

Self assembled monolayers definition

Self assembled monolayers formation, mechanism

Self assembled monolayers synthesis

Self assembled monolayers systems

Self assembly of monolayers

Self-Assembled Monolayer Gate Dielectrics

Self-Assembled Monolayers and Multilayers

Self-Assembled Monolayers and Multilayers Derived from Organosilicon Derivatives

Self-Assembled Monolayers characterisation

Self-Assembled Monolayers with Hydroquinone Incorporation

Self-Assembled Monolayers, Biological Membranes, and Biosensors

Self-Assembled Monolayers—Lipids in Materials Science and Bioengineering

Self-Assembly Monolayer Formation

Self-Assembly Monolayers (SAMs)

Self-assembled Alkanethiol Monolayer on Mercury

Self-assembled DNA monolayers

Self-assembled Monolayers as Tailored Functional Surfaces in Two and Three Dimensions

Self-assembled Monolayers for Surface Engineering

Self-assembled Monolayers of Rigid Mercaptobiphenyls

Self-assembled monolayer alkylthiol

Self-assembled monolayer antibody immobilization

Self-assembled monolayer chemistry

Self-assembled monolayer derivatization

Self-assembled monolayer desorption

Self-assembled monolayer electron-transfer kinetics

Self-assembled monolayer hydrophobic

Self-assembled monolayer monolayers)

Self-assembled monolayer monolayers)

Self-assembled monolayer noble metals

Self-assembled monolayer on gold

Self-assembled monolayer preparation

Self-assembled monolayer response times

Self-assembled monolayer semiconductors

Self-assembled monolayer technique

Self-assembled monolayers

Self-assembled monolayers

Self-assembled monolayers , label-free

Self-assembled monolayers , scanning

Self-assembled monolayers , scanning electrochemical microscopy

Self-assembled monolayers , scanning electron transfer

Self-assembled monolayers SAMs)

Self-assembled monolayers and

Self-assembled monolayers applications

Self-assembled monolayers characterization

Self-assembled monolayers chemical reactions

Self-assembled monolayers chemistry

Self-assembled monolayers copper surfaces

Self-assembled monolayers corrosion inhibitors

Self-assembled monolayers cyclodextrins

Self-assembled monolayers development

Self-assembled monolayers electrochemical behavior

Self-assembled monolayers electrochemical studies

Self-assembled monolayers electrochemistry

Self-assembled monolayers electron transfer

Self-assembled monolayers electrostatic binding

Self-assembled monolayers energy transfer

Self-assembled monolayers enhancing stability

Self-assembled monolayers enzymatic surface-initiated

Self-assembled monolayers fluorescent

Self-assembled monolayers formation

Self-assembled monolayers future applications

Self-assembled monolayers hydroxyl terminated

Self-assembled monolayers hyperbranched

Self-assembled monolayers laboratory experiments

Self-assembled monolayers mechanism

Self-assembled monolayers micro-contact printing

Self-assembled monolayers modified electrodes

Self-assembled monolayers molecular conductance

Self-assembled monolayers molecular recognition

Self-assembled monolayers multilayering

Self-assembled monolayers nanotechnology

Self-assembled monolayers new approaches

Self-assembled monolayers of alkanethiols

Self-assembled monolayers of n-alkanoic

Self-assembled monolayers of n-alkanoic acids

Self-assembled monolayers of silanes

Self-assembled monolayers overview

Self-assembled monolayers oxidation

Self-assembled monolayers patterning

Self-assembled monolayers photoactive

Self-assembled monolayers photochemistry

Self-assembled monolayers pinholes

Self-assembled monolayers polymeric

Self-assembled monolayers polymerization

Self-assembled monolayers preparation

Self-assembled monolayers reactions

Self-assembled monolayers reduction

Self-assembled monolayers solution-phase deposition

Self-assembled monolayers solutions

Self-assembled monolayers stability

Self-assembled monolayers structure

Self-assembled monolayers surface characterization

Self-assembled monolayers surface modification

Self-assembled monolayers terminal groups

Self-assembled monolayers test solution

Self-assembled monolayers thiol

Self-assembled monolayers thiol-based

Self-assembled monolayers through, chains

Self-assembled monolayers transformations

Self-assembled monolayers tunneling microscopy

Self-assembled monolayers, of DNA

Self-assembled monolayers, reactive

Self-assembled monolayers, reactive surfaces

Self-assembled thiourea monolayer

Self-assembled, generally monolayers

Self-assembling monolayers

Self-assembling monolayers

Self-assembling monolayers, SAMs

Self-assembly monolayer

Self-assembly monolayer

Self-assembly monolayer imprinted

Self-assembly process, polymer monolayer

Self-assembly, organized assemblies monolayers

Silanes, self-assembled monolayers

Silicon surfaces, self-assembled monolayers

Stability self-assembled monolayer

Surface Self-Assembled Monolayers

The Self-assembled Monolayer Approach

Thiols, self-assembled monolayers

Use of self-assembly monolayers

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