Self-assembled monolayers patterning

Zhou, E, et al. 2004. Manipulation of the ultimate pattern of polypyrrole film on self-assembled monolayer patterned substrate by negative or positive electrodeposition. Surf Sci 561 1. 

Mino N, Ozaki S, Ogawa K, Hatada M (1994) Fabrication of self-assembled monolayer patterns by selective electron beam irradiation and a chemical adsorption technique. Thin Sohd Films 243 374-377... 

Husemann, M., Mecerreyes, D., Hawker, C.J., Hedrick, J.L., Shah, R., and Abbott, N.L. 1999. Surface-initiated polymerization for amplification of self-assembled monolayers patterned by microcontact printing. 

Saito, N., Hayashi, K., Sugimura, H., Takai, O., and Nakagiri, N. (2002) Surface potential images of self-assembled monolayers patterned by organosilanes ab initio molecular orbital calculations. Surf. Interface Anal, 34, 601-605. 

Kumar A, Biebuyok FI A and Whitesides G M 1994 Patterning self-assembled monolayers—applioations in materials soienoe Langmuir 10 1498-511... 

Peng, Y. T., Hu, Y. Z., and Wang, H., "Patterned Deposition of Multi-walled Carbon Nanotubes on Self-assembled Monolayers, Chinese Science Bulletin, Vol. 51, No. 2, 2006, pp. 147-150. 

The potential of photolithography for the construction of protein microarrays has also been demonstrated (Mooney et al., 1996). For these experiments, antibodies were assembled in precise two-dimensional patterns on silicon wafers. This was accomplished by first forming a self-assembled monolayer of n-octadecyltrimethoxysilane (OTMS) on a silicon-dioxide... 

Ryan D, Parviz BA, Linder V, Semetey V, Sia SK, Su J, Mrksich M, Whitesides GM (2004) Patterning multiple aligned self-assembled monolayers using light. Langmuir 20 9080-9088... 

Kumar A, Biebuyck HA, Whitesides GM (1994) Patterning self-assembled monolayers applications in materials science. Langmuir 10 1498-1511... 

Lopez GP, Albers MW, Schreiber SL, Carroll R, Peralta E, Whitesides GM (1993) Convenient methods for patterning the adhesion of mammalian cells to surfaces using self-assembled monolayers of alkanethiolates on gold. J Am Chem Soc 115 5877-5878... 

Rieke, P.C. Tarasevich, B.J. Wood, L.L. Engelhard, M.H. Baer, D.R. Fryxell, G.E. John, C.M. Laken, D.A. Jaehnig, M.C. (1994) Spatially resolved mineral deposition on patterned self-assembled monolayers. Langmuir 10 619-622... 

Zhou C, Nagy G, Walker AV (2005) Toward molecular electronic circuitry selective deposition of metals on patterned self-assembled monolayer surfaces. J Am Chem Soc 127 12160-12161... 

Park MH, Jang YJ, Sung-Suh HM, Sung MM (2004) Selective atomic layer deposition of titanium oxide on patterned self-assembled monolayers formed by microcontact printing. Langmuir 20 2257-2260... 

Fig. 5.1 Scheme for patterned deposition of PbS. (a) Self-assembled monolayer (SAM) of long-chain mercapto-carboxylic acid. On exposure to UV radiation through a mask, the exposed thiol group is oxidized to a sulphonate group (b) that is weakly bound to the An substrate and can be easily rinsed away (c). Subsequent formation of a long-chain alkyl thiol SAM occurs only on the exposed Au (d). CD of PbS occurs only on hydrophilic car-boxylate endgroups and not on hydrophobic methyl groups (e). (See Ref. 41). 

Using this deposition technique, TiOi was deposited onto patterned self-assembled monolayers [49]. Thioacetate-terminated trichlorosilane monolayers... 

Effenberger, F., Gotz, G., Bidlingmaier, B. and Wezstein, M. Photoactivated preparation and patterning of self-assembled monolayers with 1-alkenes and aldehydes on silicon hydride surfaces. Angewandte Chemie-International Edition 37, 2462 (1998). 

Microcontact Printing. An ink of alkanethiols is spread on a patterned PDMS stamp. The stamp is then brought into contact with the substrate, which can range from coinage metals to oxide layers. The thiol ink is transferred to the substrate where it forms a self-assembled monolayer that can act as a resist against etching. 

M. Mrksich and G. M. Whitesides, Patterning self-assembled monolayers using microcontact printing-a new technology for biosensors, Trends Biotechnol. 13, 228—235 (1995). 

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