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Self-assembled monolayers molecular recognition

Fig. 28. Self-assembly monolayer to function as molecular recognition iaterface (182). Fig. 28. Self-assembly monolayer to function as molecular recognition iaterface (182).
Biology and organic chemistry are replete with examples of self-assembly. Examples include lipid bilayers, the DNA duplex, proteins in their correctly folded forms, self-assembled monolayers, and crystals. In MESA, we extend ideas abstracted from molecular recognition - shape recognition, chirality, directional interactions, hierarchy of bonds, and hydrophobicity - to the mesoscale. [Pg.143]

K.D. Schierbaum, T. Weiss, E.U.T. van Velzen, J.F.J. Engbersen, D.N. Reinhoudt, W. Gbpel, Molecular Recognition by Self-Assembled Monolayers of Cavitand Receptors , Science, 265, 1413 (1994)... [Pg.132]

Molecular Recognition at LB Films and Self-Assembled Monolayers... [Pg.159]

Fig. 2. Virus electrode construction (A) M13 phage is covalently tethered to a self-assembled monolayer of NHS-TE, through formation of amide bonds between free amines on the phage and the activated carboxylate. (B) Gaps in the monolayer and unreacted NHS esters are capped with BSA. (C) A control experiment is first performed by reacting with n-Ab. (D) PSMA is added next to bind molecular recognition scaffolds on the surface of the phage (hooks). (E) Last, p-Ab can react with the virus electrode. Fig. 2. Virus electrode construction (A) M13 phage is covalently tethered to a self-assembled monolayer of NHS-TE, through formation of amide bonds between free amines on the phage and the activated carboxylate. (B) Gaps in the monolayer and unreacted NHS esters are capped with BSA. (C) A control experiment is first performed by reacting with n-Ab. (D) PSMA is added next to bind molecular recognition scaffolds on the surface of the phage (hooks). (E) Last, p-Ab can react with the virus electrode.
Chen ZD, Nagaoka T (2000) Recognition of vitamin K1 with a molecularly imprinted self-assembled monolayer film. Bunsekikagaku, 49(7) 543-546... [Pg.208]

Spinke J, Liley M, Schmitt F J, Guder H J, Angermaier L and Knoll W1993 Molecular recognition at self-assembled monolayers—optimization of surface functionalization J. Chem. Phys. 99 7012-9... [Pg.2639]

Schierbaum K D, Weiss T, Thoden van Velzen E U, Engbersen J F J, Reinhoudt D N and Gopel W1994 Molecular recognition by self-assembled monolayers of cavitand receptors Science 265 1413-5... [Pg.2639]

Interspersed among these milestones is the parallel birth of self-assembly as in the formation of self-assembled monolayers first observed as the spreading of oil on water by Benjamin Franklin in 1774, and the birth of nanochemistry (the 1818 recognition of the particle size-dependent color of colloidal gold). We can also see the evolution of crystal engineering from the early topochemical postulate and molecular engineering of von Hippel in the 1960s to... [Pg.2]

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See also in sourсe #XX -- [ Pg.613 , Pg.614 , Pg.615 , Pg.616 , Pg.617 , Pg.618 ]

See also in sourсe #XX -- [ Pg.613 , Pg.614 , Pg.615 , Pg.616 , Pg.617 , Pg.618 ]



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Assembled monolayers

Molecular Recognition at LB Films and Self-Assembled Monolayers

Molecular Self-Assembling

Molecular monolayers

Molecular recognition

Molecular self-assembly

Monolayer assembly

Monolayer, self-assembling

Self-assembled molecular

Self-assembled monolayer monolayers)

Self-assembled monolayers

Self-assembling monolayers

Self-assembly monolayer

Self-assembly monolayers

Self-recognition

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