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Self-assembling monolayer

Figure C3.2.4. Plot of the log of photocurrent against number of methyl units in a alkylsilane based monolayer self-assembled on a n silicon electrode. The electrode is immersed in a solution witli an electron donor. Best fits of experimental data collected at different light intensities ( ) 0.3 mW cm ( ) 0.05 mW cm. From [10]. Figure C3.2.4. Plot of the log of photocurrent against number of methyl units in a alkylsilane based monolayer self-assembled on a n silicon electrode. The electrode is immersed in a solution witli an electron donor. Best fits of experimental data collected at different light intensities ( ) 0.3 mW cm ( ) 0.05 mW cm. From [10].
Surface energies of different end-functionalized trichlorosilane monolayers self-assembled on oxidized PDMS ... [Pg.105]

Badia, A., Demers, L., Guccia, L., Morin, E. and Lennox, R.B. (1997) Structure and Dynamics in Alkanethiolate Monolayers Self-Assembled on Gold Nanoparticles A DSC, ET-IR, and Deuterium NMR Study. Journal of the American Chemical Society, 119, 2682-2692. [Pg.396]

Tarlov MJ, Burgess DRF Jr, Gillen G (1993) UV photopatteming of alkanethiolate monolayers self-assembled on gold and silver. J Am Chem Soc 115 5305-5306... [Pg.195]

Emberly EG, Kirczenow G (2001) Models of electron transport through organic molecular monolayers self-assembled on nanoscale metallic contacts. Phys Rev B 64(23) 235412... [Pg.34]

Girlando A, Sissa C, Terenziani F, Painelli A, Chwialkowska A, Ashwell GJ (2007) In situ spectroscopic characterization of rectifying molecular monolayers self-assembled on gold. Chem Phys Chem 8 2195-2201... [Pg.83]

Monolayer blown-film extrusion, VDC copolymers in, 25 725, 728-729 Monolayers, self-assembled, 77 57 Monolayer self-assembled systems, 16 800 Monolignols, 27 10—11, 13, 14 Monolithic drug delivery systems, 9 11 Monomagnesium phosphate, 78 839 Monomer addition, in PVC polymerization, 25 665-666... [Pg.601]

The structural state of dendritic macromolecules at air-water (Langmuir mono-layers) and air-solid (adsorbed monolayers, self-assembled films and cast films) interfaces have been reviewed by Tsukruk [17]. Although this work summarizes various characterization techniques for dendritic films by AFM techniques, in this chapter, we will present recent progress on the characterization of the dendritic film surface morphologies. [Pg.288]

Bhatia R, Garrison BJ (1997) Phase transitions in a methyl-terminated monolayer self-assembled on Au lll. Langmuir 13(4) 765-769... [Pg.267]

Tarlov MJ (1992) Silver metalization of octadecanethiol monolayers self-assembled on gold. Langmuir 8 80-89... [Pg.267]

Figure 7.5.2. C60 derivative monolayer self-assembled as a result of ammonium cation recognition by crown ether moiety. Figure 7.5.2. C60 derivative monolayer self-assembled as a result of ammonium cation recognition by crown ether moiety.
Kinetics and Thermodynamics of Au Colloid Monolayer Self-Assembly 111... [Pg.130]

The X-ray diffraction (XRD) measurements for 7a have been performed to examine the relationship between the photoluminescent properties and the self-assembled structures (Fig. 9). The XRD pattern of 7a in the Sm3 phase shows several diffractions in the small angle region, corresponding to (100), (200), (300), (400), and (500) reflections. The layer spacing is similar to the molecular length calculated to be 82 A. It is assumed that monolayer self-assembled structures are formed in the Sm3 phase (Fig. 9, top). In the SmA phase, only one peak appears at 38.2 A in the diffraction pattern obtain at 120 °C. The layer spacing is less than half... [Pg.402]

S. R Chenakin, Sputtering of organic molecular Monolayers self-assembled onto Ag(l 11) and Au(l 11) surfaces, Vacuum, 66, 157-166 (2002). [Pg.98]

Some the structural state of dendritic macromolecules at air - water (Langmuir monolayers) and air - solid (adsorbed monolayers, self - assembled films, and cast films) interfaces has been discussed by V. V. Tsukruk [106] and Frechet [107],... [Pg.229]

Realization of two-terminal microsensors like that represented in Scheme I depends on the discovery of viable reference and indicator molecules that can be confined to electrode surfaces. Described herein are three different microelectrochemical sensing systems. The first is a three-terminal microelectrochemical sensing system for CO based upon an indicator molecule, ferrocenyl ferraazetine, that selectively reacts with CO (2). The second microelectrochemical system is based upon a disulfide functionalized ferrocenyl ferraazetine that can be adsorbed onto Au or Pt via monolayer self-assembly techniques. Efforts to make a two-terminal CO sensor based upon the... [Pg.224]

A CO Sensor Based Upon Self-assembled Ferrocenyl Ferraazetine. Having demonstrated the CO dependent solid-state electrochemistry of ferrocenyl ferraazetine, we synthesized a ferrocenyl ferraazetine molecule with disulfide functionality (Id). Scheme III. The specific aim was to design a CO sensitive molecule that could be confined to the working electrode of a two-terminal device via monolayer self-assembly techniques. Disulfides have been shown to irreversibly adsorb to Au and Pt surfaces (3-10). NMR and mass spectrometry are consistent with the proposed structure for compound Id. The FTIR spectrum of Id in THF exhibits metal carbonyl bands at 2067,2024,1989,1985 cm similar to the spectra for other ferraazetine derivatives la-c (2,5-6). Like derivatives la-c. Id reacts with CO (1 atm) at 298 K in CH2C12 to form a ferrapyrrolinone complex 2d, equation (3). [Pg.229]

Monolayers, self-assembled 997 on gold surfaces 1421 Monte Carlo simulation 107 Montmorillonite catalysis 613-617, 627, 632 MOPAC program 954 Morphine 237... [Pg.1495]

Sowerby, S.J., and Petersen, G.B. (1997) Scanning tunneling microscopy of uracil monolayers self-assembled at the solid/ liquid interface. Journal of... [Pg.133]

As distinct from sohd supports such as gold or silver, mercury imparts lateral mobihty to hpid monolayers directly self-assembled on its surface, because of its liquid state. This is demonstrated by rapid spontaneous phase separation, with microdomain formation, in a hpid mixture monolayer self-assembled on top of a DPTL thiolipid monolayer tethered to a mercury microelectrode [30]. The presence of microdomains was directly verified from the images of the distal hpid monolayer obtained using two-photon fluorescence lifetime imaging microscopy. [Pg.201]

Kalyuzhny G, Vaskevick A, Ashkenasy G, Shanzer A (2000) UV/Vis spectroscopy of metalloporphyrin and metallophthalocyanine monolayers self-assembled on ultrathin gold films. J Phys Chem B 104 8238-8344... [Pg.103]

Time dependencies measured in Ref. 26 showed that the adsorption of lipid at the ITIES is fully reversible. The lipid adsorption on and desorption from the ITIES occur at about the same time scale. The monolayer self-assembled at the ITIES is in dynamic equilibrium with dissolved lipid molecules that allows any pinhole defects to be healed. In contrast, self-assembly on the solid/liquid interface often involves irreversible adsorption and requires high purity of chemicals, complex pretreatment, and preparation protocols to obtain a low-defect-density molecular monolayer (32). [Pg.317]

Li J, Liang KS, Scoles G, Ulman A (1995) Counterion overlayers at the interface between an electrolyte and an w-functionalized monolayer self-assembled on gold. An X-ray reflectivity study. Langmuir 11 4418-4427... [Pg.216]


See other pages where Self-assembling monolayer is mentioned: [Pg.1722]    [Pg.392]    [Pg.432]    [Pg.42]    [Pg.77]    [Pg.684]    [Pg.191]    [Pg.222]    [Pg.96]    [Pg.209]    [Pg.490]    [Pg.191]    [Pg.3054]    [Pg.191]    [Pg.121]    [Pg.1722]   
See also in sourсe #XX -- [ Pg.194 ]

See also in sourсe #XX -- [ Pg.194 ]

See also in sourсe #XX -- [ Pg.194 ]




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Adhesion Self-assembled monolayers

Alkanethiol self-assembled monolayers

Alkanethiols, self-assembled monolayers

Assembled monolayers

Biomaterial self-assembled monolayers

Contact angle self-assembled monolayers

Design using self-assembled monolayers

Disulfides, self-assembled monolayers

Electroactive monolayers/multilayers self-assembly

Electroactive self-assembled monolayers, with

Electrochemical sensors self-assembled monolayers

Electrochemistry and Self-Assembled Monolayers

Electrochemistry on Self-assembled Monolayers

Fluorinated self-assembled monolayer

Fluorinated self-assembled monolayer SAM) film

Formation of Self-Assembled Monolayers

Gate self-assembled monolayer

General Factors Affecting the Behavior of Metals Deposited onto Self-Assembled Monolayers

Gold nanoparticles self-assembled monolayers

Gold surfaces, chromophores self-assembled monolayers

Grafting-from methods self-assembled monolayer

High-density self-assembled monolayers

Hydroxy-terminated self-assembled monolayers

Immunoassays and immunosensors, recent self-assembled monolayers

Interfacial reactions self-assembled monolayers

Langmuir—Blodgett deposition self-assembled monolayers

Low-density self-assembled monolayers

Macroscopic self-assembled monolayers

Mercaptoundecanoic acid, self-assembled monolayer

Microcontact Printing of Self-Assembled Monolayers

Molecular Recognition at LB Films and Self-Assembled Monolayers

Molecular self-assembled monolayer

Monolayer assembly

Monolayer self-assembled

Monolayers, self-assembled, nucleation

N-Alkanoic acid self-assembled monolayers

Nanoparticle-based corrosion inhibitors and self-assembled monolayers

Nanoparticles and self-assembled monolayers

Nanopores in Self-Assembled Monolayers

Organic reactions, self-assembled monolayers

Patterned Self-assembled Monolayers

Patterned self-assembling monolayers

Polymer brushes self-assembled monolayers

Polymers patterned self-assembling monolayers

Preparation of Self-Assembled Monolayers

SAM = self-assembled monolayer

Selectivity self-assembled” monolayers

Self assembled monolayers chemical transformations

Self assembled monolayers computational studies

Self assembled monolayers definition

Self assembled monolayers formation, mechanism

Self assembled monolayers synthesis

Self assembled monolayers systems

Self assembly of monolayers

Self-Assembled Monolayer Gate Dielectrics

Self-Assembled Monolayers and Multilayers

Self-Assembled Monolayers and Multilayers Derived from Organosilicon Derivatives

Self-Assembled Monolayers characterisation

Self-Assembled Monolayers with Hydroquinone Incorporation

Self-Assembled Monolayers, Biological Membranes, and Biosensors

Self-Assembled Monolayers—Lipids in Materials Science and Bioengineering

Self-Assembly Monolayer Formation

Self-Assembly Monolayers (SAMs)

Self-assembled Alkanethiol Monolayer on Mercury

Self-assembled DNA monolayers

Self-assembled Monolayers as Tailored Functional Surfaces in Two and Three Dimensions

Self-assembled Monolayers for Surface Engineering

Self-assembled Monolayers of Rigid Mercaptobiphenyls

Self-assembled monolayer alkylthiol

Self-assembled monolayer antibody immobilization

Self-assembled monolayer chemistry

Self-assembled monolayer derivatization

Self-assembled monolayer desorption

Self-assembled monolayer electron-transfer kinetics

Self-assembled monolayer hydrophobic

Self-assembled monolayer monolayers)

Self-assembled monolayer monolayers)

Self-assembled monolayer noble metals

Self-assembled monolayer on gold

Self-assembled monolayer preparation

Self-assembled monolayer response times

Self-assembled monolayer semiconductors

Self-assembled monolayer technique

Self-assembled monolayers

Self-assembled monolayers

Self-assembled monolayers , label-free

Self-assembled monolayers , scanning

Self-assembled monolayers , scanning electrochemical microscopy

Self-assembled monolayers , scanning electron transfer

Self-assembled monolayers SAMs)

Self-assembled monolayers and

Self-assembled monolayers applications

Self-assembled monolayers characterization

Self-assembled monolayers chemical reactions

Self-assembled monolayers chemistry

Self-assembled monolayers copper surfaces

Self-assembled monolayers corrosion inhibitors

Self-assembled monolayers cyclodextrins

Self-assembled monolayers development

Self-assembled monolayers electrochemical behavior

Self-assembled monolayers electrochemical studies

Self-assembled monolayers electrochemistry

Self-assembled monolayers electron transfer

Self-assembled monolayers electrostatic binding

Self-assembled monolayers energy transfer

Self-assembled monolayers enhancing stability

Self-assembled monolayers enzymatic surface-initiated

Self-assembled monolayers fluorescent

Self-assembled monolayers formation

Self-assembled monolayers future applications

Self-assembled monolayers hydroxyl terminated

Self-assembled monolayers hyperbranched

Self-assembled monolayers laboratory experiments

Self-assembled monolayers mechanism

Self-assembled monolayers micro-contact printing

Self-assembled monolayers modified electrodes

Self-assembled monolayers molecular conductance

Self-assembled monolayers molecular recognition

Self-assembled monolayers multilayering

Self-assembled monolayers nanotechnology

Self-assembled monolayers new approaches

Self-assembled monolayers of alkanethiols

Self-assembled monolayers of n-alkanoic

Self-assembled monolayers of n-alkanoic acids

Self-assembled monolayers of silanes

Self-assembled monolayers overview

Self-assembled monolayers oxidation

Self-assembled monolayers patterning

Self-assembled monolayers photoactive

Self-assembled monolayers photochemistry

Self-assembled monolayers pinholes

Self-assembled monolayers polymeric

Self-assembled monolayers polymerization

Self-assembled monolayers preparation

Self-assembled monolayers reactions

Self-assembled monolayers reduction

Self-assembled monolayers solution-phase deposition

Self-assembled monolayers solutions

Self-assembled monolayers stability

Self-assembled monolayers structure

Self-assembled monolayers surface characterization

Self-assembled monolayers surface modification

Self-assembled monolayers terminal groups

Self-assembled monolayers test solution

Self-assembled monolayers thiol

Self-assembled monolayers thiol-based

Self-assembled monolayers through, chains

Self-assembled monolayers transformations

Self-assembled monolayers tunneling microscopy

Self-assembled monolayers, of DNA

Self-assembled monolayers, reactive

Self-assembled monolayers, reactive surfaces

Self-assembled thiourea monolayer

Self-assembled, generally monolayers

Self-assembling monolayers

Self-assembling monolayers

Self-assembling monolayers, SAMs

Self-assembly monolayer

Self-assembly monolayer

Self-assembly monolayer imprinted

Self-assembly monolayers

Self-assembly monolayers

Self-assembly process, polymer monolayer

Self-assembly, organized assemblies monolayers

Silanes, self-assembled monolayers

Silicon surfaces, self-assembled monolayers

Stability self-assembled monolayer

Surface Self-Assembled Monolayers

The Self-assembled Monolayer Approach

Thiols, self-assembled monolayers

Use of self-assembly monolayers

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