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Reactions with carbon

Displacement Reactions with Carbon, O.xygen. and Sulfur Nucleophiles... [Pg.244]

Reactions with Carbon and Oxygen Nucleophiles, and Other Reactions... [Pg.464]

The linear a olefins described m Section 14 15 are starting materials for the preparation of a variety of aldehydes by reaction with carbon monoxide The process is called hydroformylation... [Pg.711]

Uses, cx-Aminonitriles may be hydrolyzed to aminoacids, such as is done in producing ethylenediaminetetracetate (EDTA) or nittilotriacetate (NTA). In these cases, formaldehyde is utilized in place of a ketone in the synthesis. The principal use of the ketone-based aminonitriles described above is in the production of azobisnittile radical initiators (see below). AN-64 is also used as an intermediate in the synthesis of the herbicide Bladex. Aminonitriles are also excellent intermediates for the synthesis of substituted hydantoins by reaction with carbon dioxide however, this is not currently commercially practiced. [Pg.222]

In the commonly used Welland process, calcium cyanamide, made from calcium carbonate, is converted to cyanamide by reaction with carbon dioxide and water. Dicyandiamide is fused with ammonium nitrate to form guanidine nitrate. Dehydration with 96% sulfuric acid gives nitroguanidine which is precipitated by dilution. In the aqueous fusion process, calcium cyanamide is fused with ammonium nitrate ia the presence of some water. The calcium nitrate produced is removed by precipitation with ammonium carbonate or carbon dioxide. The filtrate contains the guanidine nitrate that is recovered by vacuum evaporation and converted to nitroguanidine. Both operations can be mn on a continuous basis (see Cyanamides). In the Marquerol and Loriette process, nitroguanidine is obtained directly ia about 90% yield from dicyandiamide by reaction with sulfuric acid to form guanidine sulfate followed by direct nitration with nitric acid (169—172). [Pg.16]

Reaction with Carbon Nucleophiles. Unactivated a2iddines react with the lithium salts of malonates or p-keto esters in the presence of lithium salts to yield 3-substituted pyttohdinones (56—59), where R = alkyl and aryl, and R = alkoxyl, alkyl, and aryl. [Pg.3]

DiisononylPhthalate andDiisodeeylPhthalate. These primary plasticizers are produced by esterification of 0x0 alcohols of carbon chain length nine and ten. The 0x0 alcohols are produced through the carbonylation of alkenes (olefins). The carbonylation process (eq. 3) adds a carbon unit to an alkene chain by reaction with carbon monoxide and hydrogen with heat, pressure, and catalyst. In this way a Cg alkene is carbonylated to yield a alcohol a alkene is carbonylated to produce a C q alcohol. Due to the distribution of the C=C double bond ia the alkene and the varyiag effectiveness of certain catalysts, the position of the added carbon atom can vary and an isomer distribution is generally created ia such a reaction the nature of this distribution depends on the reaction conditions. Consequendy these alcohols are termed iso-alcohols and the subsequent phthalates iso-phthalates, an unfortunate designation ia view of possible confusion with esters of isophthaUc acid. [Pg.122]

Potassium Carbonate. Except for small amounts produced by obsolete processes, eg, the leaching of wood ashes and the Engel-Precht process, potassium carbonate is produced by the carbonation, ie, via reaction with carbon dioxide, of potassium hydroxide. Potassium carbonate is available commercially as a concentrated solution containing ca 47 wt % K CO or in granular crystalline form containing 99.5 wt % K CO. Impurities are small amounts of sodium and chloride plus trace amounts (<2 ppm) of heavy metals such as lead. Heavy metals are a concern because potassium carbonate is used in the production of chocolate intended for human consumption. [Pg.532]

Geminal polyhahdes also react with organosilanes under peroxide catalysis. For example, triethylsilane affords triethylchlorosilane in good yield upon reaction with carbon tetrachloride in the presence of benzoyl peroxide (bpo) at 80°C (94,100,102). [Pg.28]

Other components in the feed gas may react with and degrade the amine solution. Many of these latter reactions can be reversed by appHcation of heat, as in a reclaimer. Some reaction products cannot be reclaimed, however. Thus to keep the concentration of these materials at an acceptable level, the solution must be purged and fresh amine added periodically. The principal sources of degradation products are the reactions with carbon dioxide, carbonyl sulfide, and carbon disulfide. In refineries, sour gas streams from vacuum distillation or from fluidized catalytic cracking (FCC) units can contain oxygen or sulfur dioxide which form heat-stable salts with the amine solution (see Fluidization Petroleum). [Pg.211]

Hydrogen sulfide and carbon react at 900°C to give a 70% yield of carbon disulfide (102,103). A process for reaction of coke and hydrogen sulfide or sulfur in an electric-resistance-heated fluidized bed has been demonstrated on a laboratory scale (104). Hydrogen sulfide also forms carbon disulfide in reactions with carbon monoxide at 600—1125°C (105) or carbon dioxide at 350—450°C in the presence of catalysts (106). [Pg.31]

The adsorbed oxygen atom on the copper surface is removed by reaction with carbon monoxide and provides a pathway for the formation of the carbon dioxide needed in the main reaction. [Pg.199]

Hydrogen cyanide is a weak acid and can readily be displaced from a solution of sodium cyanide by weak mineral acids or by reaction with carbon dioxide, eg, from the atmosphere however, the latter takes places at a slow rate. [Pg.382]

The dimer acids [61788-89-4] 9- and 10-carboxystearic acids, and C-21 dicarboxylic acids are products resulting from three different reactions of C-18 unsaturated fatty acids. These reactions are, respectively, self-condensation, reaction with carbon monoxide followed by oxidation of the resulting 9- or 10-formylstearic acid (or, alternatively, by hydrocarboxylation of the unsaturated fatty acid), and Diels-Alder reaction with acryUc acid. The starting materials for these reactions have been almost exclusively tall oil fatty acids or, to a lesser degree, oleic acid, although other unsaturated fatty acid feedstocks can be used (see Carboxylic acids. Fatty acids from tall oil Tall oil). [Pg.113]

Ca.rhoxyla.tlon, This is the process of iatroduciag a carboxyUc acid group iato a phenol or naphthol by reaction with carbon dioxide under appropriate conditions of heat and pressure. Important examples are the carboxylation of phenol and 2-naphthol to give sahcyhc acid and 2-hydroxy-3-naphthoic acid, respectively. [Pg.293]

Reactions with carbon nucleophiles, e.g. from ketones (73CR(C)(277)703, 74CR(C)(278)427), are sometimes accompanied by deacylation in situ to give alkyl derivatives, e.g. (106)... [Pg.214]

Experiments with cyclic thioethers (80JCS(P1)1693), thiourea, thiocyanate and ethyl xan-thate always led to destruction of oxaziridines (73AJC2159). Products of complicated consecutive reactions could be isolated but only with some difficulty, e.g. (92) from a reaction with carbon disulfide (74JOC957), and (93), obtained by trapping with butadiene a product of a reaction between an oxaziridine and a thiirane (80JOC1691). [Pg.209]

Carbotbermic Reactions Some apparently solid/solid reactions with carbon apparently take place through intermediate CO and CO2. The reduction of iron oxides has the mechanism... [Pg.2124]

The mfluoromethyl group activates the fluorine in position 4 ofperfluorotolu ene toward reaction with carbon nucleophiles Examples on che use of perfluoro-toluene as an arylation agent abound, and in all cases, the 4-fluonne atom is replaced predommantly or exclusively [% 87,88,89, 90 (equation 48) In perjluoromesity-lene, the aromatic fluorine atoms are activated toward Ar reaction, and a reaction... [Pg.516]

Thiohydantoin 9 was obtained from the treatment of carbonyl 1 with carbon disulfide and ammonium cyanide in aqueous methanol. The transformation could also be carried out step-wise, that is, treatment of 1 with ammonium cyanide to form aminonitrile 10 followed by reaction with carbon disulfide to produce thiohydantoin 9. Alternatively, 5,5-disubstituted 4-thiohydantoins could be prepared by the reaction of ketones with ammonium monothiocarbamate and sodium cyanide. ... [Pg.267]

The Grignard reagent from 2-thenyl chloride can be obtained by the use of the "cyclic reactor.However, rearrangement occurs in its reaction with carbon dioxide, ethyl chlorocarbonate, acetyl chloride, formaldehyde, and ethylene oxide to 3-substituted 2-methylthio-phenes, Only in the case of carbon dioxide has the normal product also been isolated. [Pg.92]

G. Reactions with Carbon Dioxide and Some Carbonic Derivatives.. ... [Pg.43]


See other pages where Reactions with carbon is mentioned: [Pg.47]    [Pg.60]    [Pg.60]    [Pg.321]    [Pg.900]    [Pg.6]    [Pg.47]    [Pg.261]    [Pg.369]    [Pg.523]    [Pg.544]    [Pg.53]    [Pg.386]    [Pg.55]    [Pg.163]    [Pg.165]    [Pg.612]    [Pg.42]    [Pg.74]   
See also in sourсe #XX -- [ Pg.60 ]




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1-Hexyne reactions with carbon dioxide

1.3- Butadiene reactions with carbon dioxide

2- Butene reaction with carbon atoms

3- Hydroxypyridine reaction with carbon dioxide

Acids reaction with carbonates

Acrylic acid , reaction with carbon-centered

Activated carbon catalytic reactions with

Activated carbon reaction with oxidants

Addition Reactions with Formation of Carbon-Oxygen Bonds

Alcohols reaction with carbon disulfide

Aliphatic carbon-centered radicals reaction with transition metal

Alkenes reactions with carbon dioxide

Alkenes reactions with carbon monoxide

Alkynes reactions with carbon monoxide

Allene reactions with carbon dioxide

Allyl alcohol reaction with carbon tetrachloride

Allyl complexes reaction with carbon dioxide

Allylsilanes reactions with electrophilic carbon

Aluminum-carbon bonds reactions with

Amidines, reaction with carbon dioxide

Amines reaction with carbon dioxide

Ammonia reaction with carbon dioxide

Antimony—carbon bonds reactions with

Aromatic amines reactions with carbonate radical

Arsenic—carbon bonds reactions with

Barium carbonate reaction with, phosgene

Benzyl methyl carbonate reactions with

Bismuth—carbon bonds reactions with

Boranes reaction with carbon

Boranes reaction with carbon dioxide

Boron—carbon bonds reactions with

Boron—carbon bonds reactions with hydrogen

Butadiene, catalyzed reactions with carbon dioxide

Calcium carbonate reaction with acid rain

Calcium carbonate reaction with hydrochloric acid

Calcium carbonate reaction with sulfur dioxide

Calcium carbonate reaction with weak acid

Calcium carbonate reaction with, phosgene

Calcium carbonate solid-state reactions with

Calcium hydroxide reaction with carbon dioxide

Calcium hydroxide reaction with lithium carbonate

Calcium hydroxide reaction with sodium carbonate

Calcium nitrate, reaction with potassium carbonate

Carbocations reaction with carbon monoxide

Carbohydrates carbon dioxide, reaction with

Carbohydrates carbon monoxide, reaction with

Carbon atom, recoil, reactions with

Carbon atomic, reactions with benzene

Carbon atoms, energetic, reactions with

Carbon atoms, energetic, reactions with organic compounds

Carbon bisulfide, reaction with ethylene

Carbon black reactions with

Carbon dioxide lithium hydroxide reaction with

Carbon dioxide palladium-catalyzed reaction with butadiene

Carbon dioxide reaction with Grignard reagents

Carbon dioxide reaction with acetyl coenzyme

Carbon dioxide reaction with graphite

Carbon dioxide reaction with lithium

Carbon dioxide reaction with magnesium

Carbon dioxide reaction with organometallic

Carbon dioxide reaction with water

Carbon dioxide reactions with acetylenes

Carbon dioxide reactions with alkoxides

Carbon dioxide reactions with amides

Carbon dioxide reactions with dienes

Carbon dioxide reactions with hydride complexes

Carbon dioxide reactions with organometallic reagents

Carbon dioxide reactions with transition metal complexes

Carbon dioxide, reaction with hydrogen

Carbon dioxide, reaction with indole

Carbon dioxide, reaction with niobium

Carbon dioxide, reaction with organolithium reagents

Carbon dioxide, reaction with organometallics

Carbon disulfide reaction with ammonia

Carbon disulfide reaction with ethylene diamine

Carbon disulfide reactions with nickel

Carbon disulfide, exchange reactions with sulfur

Carbon disulfide, reaction with hydrazines

Carbon disulfide, reaction with nucleophiles

Carbon disulfide, reaction with pyrrole

Carbon gaseous oxygen reaction with

Carbon halides reactions with

Carbon hydrides reactions with

Carbon monoxide addition reactions with clusters, metal cluster

Carbon monoxide dichlorine, reaction with

Carbon monoxide nitrous oxide, reaction with

Carbon monoxide reaction with

Carbon monoxide reaction with alcohols

Carbon monoxide reaction with boranes

Carbon monoxide reaction with copper chloride

Carbon monoxide reaction with dicobalt

Carbon monoxide reaction with ferrous iron

Carbon monoxide reaction with hematite

Carbon monoxide reaction with hydrocarbons

Carbon monoxide reaction with methanol

Carbon monoxide reaction with nitric oxide

Carbon monoxide reaction with nitriles

Carbon monoxide reaction with nitrogen

Carbon monoxide reaction with nitrogen dioxide

Carbon monoxide reaction with oxygen atoms

Carbon monoxide reaction with steam

Carbon monoxide reaction with zirconium compounds

Carbon monoxide, reaction with alcoholates

Carbon monoxide, reaction with hydroxyl radicals

Carbon monoxide, reaction with metal

Carbon monoxide, reaction with metal atoms

Carbon monoxide, reaction with organic

Carbon monoxide, reaction with organic halides

Carbon monoxide, reaction with organoborane

Carbon monoxide, reaction with organolithium compounds

Carbon monoxide, reaction with osmium complexes

Carbon monoxide, reaction with oxygen

Carbon monoxide, reaction with rhodium

Carbon monoxide, reaction with rhodium complexes

Carbon monoxide, tropospheric reaction with hydroxyl

Carbon nucleophiles synthesis reactions with

Carbon nucleophiles, reactions with aryne

Carbon oxides reactions with

Carbon reaction with aqueous ammonia

Carbon reaction with aquo complexes

Carbon reaction with cyclopropenones

Carbon reaction with electrophile

Carbon reaction with mortar

Carbon reaction with nucleophile

Carbon reaction with oxygen

Carbon reaction with, carbonyl difluoride

Carbon reactions with arynes

Carbon tetrabromide reaction with aldehydes

Carbon tetrachloride reaction with hydrogen fluoride

Carbon tetrachloride, reaction with

Carbon tetrachloride, reaction with thiophenol

Carbon, elemental reactions with

Carbon-centered alkyl radicals reaction with

Carbon-centered radical, reactions with silicon hydrides

Carbon-hydrogen bonds radical reaction with

Carbon-thallium bonds reactions with

Carbonate reactions with

Carbonate reactions with

Carbonate species reaction with

Carbonates from phosgene reaction with alcohols

Carbonates reaction with aromatic amines

Carbonates reaction with hydroxyl radical

Carbonates solid-state reactions with

Carbon—germanium bonds reactions with

Carbon—hydrogen bonds reactions with

Carbon—hydrogen reactions with

Carbon—iron bonds reactions with

Carbon—magnesium bonds reactions with

Carbon—mercury bonds reactions with

Carbon—nitrogen bonds reactions with

Carbon—oxygen bonds reactions with

Carbon—phosphorus bonds reactions with

Carbon—selenium bonds reactions with

Carbon—silicon bonds reactions with

Carbon—sulfur bonds reactions with

Carbon—tellurium bonds reactions with

Carbon—tin bonds reactions with

Carbon—transition-metal bonds reactions with

Cesium carbonate, reaction with

Chlorine, reaction, with carbon

Chlorine, reaction, with carbon monoxide

Cobalt clusters reaction with carbon monoxide

Conjugated diene complexes reactions with carbon electrophiles

Copper carbonate reaction with nitric acid

Copper clusters, reactions with carbon monoxide

Copper oxide, reaction with carbon

Copper oxide, reaction with carbon monoxide

Cross-coupling reaction with carbon nucleophiles

Cupric carbonate, reaction with

Cupric carbonate, reaction with acids

Cysteine reaction with carbon dioxide

Cytochrome reaction with carbon monoxide

Dichlorine reaction with carbonate

Diene reactions with carbon monoxide

Dienes reactions with carbon electrophiles

Diethyl carbonate, reaction with

Dinitroanilines, reaction with carbon

Disilenes, reactions with carbon

Electrophilic attack insertion reactions with carbon

Electrophilic cyclopropanes reaction with carbon nucleophiles

Elimination reactions forming carbon-oxygen double bonds with

Energetic tritium and carbon atoms reactions of,with organic

Energetic tritium and carbon atoms, reactions of, with organic compounds

Enol ethers reactions with electrophilic carbon

Ethylene carbonate, reaction with potassium thiocyanate

Ethylene oxide reaction with carbon dioxide

Ethylene reactions with carbon dioxide

Ethylenediamine reaction with carbon bisulfide

Exchange reaction with labelled carbon monoxide

From carbon monoxide reaction with Group

From carbon monoxide reaction with Group chlorides

From carbon monoxide reaction with inorganic

Furan reaction with atomic carbon

Grignard reaction with carbon dioxide

Grignard reaction with ethyl carbonate

Haemoglobin, reactions with carbon monoxide

Halogens reaction with carbon

Histidine reaction with carbon dioxide

Hydrated proton with active carbon, reaction

Hydrochloric acid reaction with sodium carbonate

Hydrochloric acid reaction with sodium hydrogen carbonate

Hydrogen reactions with carbon monoxide

Hydrogen, reaction with bromine carbon dioxide

Hydroxyl reaction with carbonate

Hydroxyl reaction with elemental carbon

Indium—carbon bonds reactions with

Indoles carbon dioxide reaction with

Insertion reactions with carbon-hydrogen bonds

Iridium clusters, reaction with carbon

Iridium complexes reaction with carbon monoxide

Iron oxide, reaction with carbon

Iron oxide, reaction with carbon monoxide

Iron reaction with carbon monoxide

Iron, tricarbonyl reactions with carbon electrophiles

Lead—carbon bonds reactions with

Lithium amides reaction with carbon monoxide

Lysine reaction with carbon dioxide

Magnesium oxide, reaction with carbon

Magnesium oxide, reaction with carbon dioxide

Metal alkoxides reaction with carbon monoxide

Metal carbonates reactions with

Metal carbonates, reaction with acids

Metal—carbon triple bonds electrophiles, reactions with

Metal—carbon triple bonds nucleophiles, reactions with

Metal—ligand bonds carbon dioxide reactions with

Methoxybutenyne reaction with diethyl carbonate

Microwave-Promoted Carbonylations Using Reaction Vessels Prepressurized with Carbon Monoxide

Molecular Simulations Applied to Adsorption on and Reaction with Carbon

Nickel complexes reactions with carbon dioxide

Nitric acid calcium carbonate, reaction with

Nitric oxide reaction with carbon monoxide over

Nitrogen dioxide reaction with carbon

Nitrogen reaction with carbonate radical

Nitrosyl complexes reaction with carbon monoxide

Nitrosyl reaction with carbon monoxide

Nucleophilic addition reactions with carbon nucleophiles

Nucleophilic reactions with electrophilic carbon moieties

Osmium reaction with carbon monoxide

Oxidation reactions with carbon monoxide

Ozone reaction with carbonates

Palladium complexes reactions with carbon dioxide

Phenol reaction with carbon dioxide

Phenylmagnesium bromide reaction with carbon dioxide

Plutonium "carbonate reaction with, phosgene

Polyenes reactions with carbon electrophiles

Potassium carbonate, reaction with calcium

Primary Reactions of the Calcite-Carbonate-Equilibrium with Atmospheric Contact in Infinitely Diluted Solutions

Propargyl amine, reaction with carbon

Propargylic Substitution Reactions with Carbon-Centered Nucleophiles

Propargylic carbonate reaction with malonate

Propylene oxide reaction with carbon dioxide

Proton with active carbon, reaction

Pyrrole anions, reaction with carbon

REACTIONS OF HALOGEN COMPOUNDS WITH NITRIC OXIDE AND CARBON MONOXIDE

REACTIONS WITH ELECTROPHILIC CARBON

Reaction XXXVI.—Condensation of Carbon Tetrachloride with Phenols and simultaneous Hydrolysis

Reaction carbon atom bonding with

Reaction of Carbon Dioxide or Urea with Glycerol

Reaction of Carbon Dioxide with Magnesium

Reaction of Carbon Nucleophiles with Carbonyl Groups

Reaction of Cyclic Ketals with Carbon Dioxide

Reaction of Lithiated Bis(methylthio)methane with Carbon Dioxide

Reaction of carbon monoxide with microperoxidase

Reaction of carbon monoxide with sulphur dioxide

Reaction of lithium carbonate with ferric oxide

Reaction of unsaturated ligands with carbon number larger than four

Reaction with Carbon Nucleophiles (and Homologs)

Reaction with ammonium hydrogen carbonate

Reaction with barium carbonate

Reaction with carbon dioxide

Reaction with carbon disulfide

Reaction with carbon suboxide

Reaction with magnesium methyl carbonates

Reactions carbon oxides with water

Reactions of Carbon Monoxide with Transition Metals

Reactions of Carbonyl Compounds with Other Carbon Nucleophiles

Reactions of Nucleophiles with sp Hybridised Carbon Centres

Reactions of Nucleophiles with sp2 Hybridised Carbon Centres

Reactions of Nucleophiles with sp3 Hybridised Carbon Centres

Reactions of barium carbonate with various oxides

Reactions with Carbon Nucleophiles

Reactions with Nucleophilic Carbon Compounds

Reactions with Other Carbon Nucleophiles

Reactions with Sulfur, Boron, Carbon, Phosphorus, Arsenic, Antimony, and Bismuth

Reactions with Sulfur, Carbon, and Silicon

Reactions with carbon compounds

Reactions with carbon electrophiles

Reactions with carbon electrophiles transition metal catalysis

Reactions with carbon sulfides

Rhodium-Catalyzed Allylic Alkylation Reaction with Stabilized Carbon Nucleophiles

Ruthenium clusters reaction with carbon monoxide

Ruthenium complexes reaction with carbon monoxide

Secondary amines, reaction with carbon

Secondary amines, reaction with carbon dioxide

Sodium carbonate reaction with

Sodium carbonate reaction with barium chloride

Sodium hydrogen carbonate reaction with acetic acid

Steam, reaction with carbon

Subject reaction with carbon dioxide

Subject reaction with carbonate radical

Succinimidyl carbonate reaction with amines

Superoxide reaction with carbonate

Surface reaction with carbon dioxide

Surface reaction with carbon monoxid

Synthesis with alpha carbon reactions

The Reaction of Carbon with Oxygen

Thiophenols reaction with carbon tetrachlorid

Titanium complexes, reaction with carbon

Titanium complexes, reaction with carbon alkyls

Titanium complexes, reaction with carbon allyl

Titanium complexes, reaction with carbon dioxide

Transition metal reaction with carbon dioxide

Transition metals carbon reaction with

Tungsten clusters, reaction with carbon

Water carbonate reaction with

Zinc—carbon bonds reactions with

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