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Iron, tricarbonyl reactions with carbon electrophiles

As a Carbon Nucleophile in Uncatalyzed Reactions. Some electrophiles do not need Lewis acids, being already cationic and electrophilic enough to react with allyltrimethylsilane. Examples are the dithianyl cation (eq 20), the tricarbonyl(cyclohexadienyl) iron cation (eq 21), ( r-allyl) tetracarbonyliron cations, and chlorosulfonyl isocyanate (CSI). Other reagents react directly by cycloaddition, but need further steps to achieve an overall electrophilic substitution, as in the reactions with nitrones (eq 22). [Pg.16]

See other pages where Iron, tricarbonyl reactions with carbon electrophiles is mentioned: [Pg.192]    [Pg.111]    [Pg.768]    [Pg.319]    [Pg.428]    [Pg.625]    [Pg.654]    [Pg.599]   
See also in sourсe #XX -- [ Pg.697 , Pg.698 , Pg.699 , Pg.700 , Pg.701 ]



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Carbon electrophile

Carbon electrophiles

Carbon reaction with electrophile

Carbonate reactions with

Iron carbonate

Iron reaction

Iron tricarbonyl, reaction with

Iron-carbon

Reaction with carbon

Reaction with iron

Reactions with carbon electrophiles

Reactions with electrophiles

With Electrophiles

With iron tricarbonyls

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