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Tungsten clusters, reaction with carbon

Bimetallic clusters 15 and 16 have been isolated from reaction between Fe4(ti3-CO)4(ri -C5H4PPh2)Cp3 and W(CO)4(NCMe)2 at room temperature. Complex 15 is the major product (90%) and contains an unusual p4-ri -CO ligand coordinated across one Fes face of the cluster through the carbon atom, and to the tungsten atom via the oxygen. The complexes display different electrochemical behaviour, with 15 showing one, and 16 two, reversible oxidation processes. ... [Pg.93]

See other pages where Tungsten clusters, reaction with carbon is mentioned: [Pg.273] [Pg.44] [Pg.299] [Pg.297] [Pg.69] [Pg.206] [Pg.10] [Pg.297] [Pg.118] [Pg.135] [Pg.2930] [Pg.143] [Pg.297] [Pg.665] [Pg.2929] [Pg.578] [Pg.767] [Pg.108] [Pg.802] [Pg.190] [Pg.34]

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Carbon clusters

Carbonate reactions with

Clustering reaction

Reaction with carbon

Tungsten carbon

Tungsten with