Organic cation

Phenyldiazonium chloride and other similar diazonium compounds are very soluble in water, are completely insoluble in ether and other organic solvents, and are completely dissociated in aqueous solution to organic cations and inorganic anions (e.g., chloride ions) a convenient formulation is therefore, for example, CjHjNj+CP. 

More highly conducting TCNQ salts of the form M (TCNQ)(TCNQ ) are also easily synthesized, where M can be any one of a variety of organic cations. These salts can be prepared by a number of different methods, though a general method involves mixing of a simple salt with TCNQ in solution. The precipitated salt can then be obtained by filtration. 

Bipyridiniums. The bipyridinium herbicides (Table 2), paraquat and diquat, ate nonselective contact herbicides and crop desiccants. Diquat is also used as a general aquatic herbicide (2,296). Bipyridinium herbicides are organic cations and are retained ia the soil complex via cation exchange. They are strongly sorbed to most soils and are not readily desorbed (332). Both paraquat and diquat are not readily leached (293). 

The reaction between organic cation (OC) of the alkaloids of Papaver Somnifeiaim and heteropoly anion (HPA) was studied by the... 

In this context it is important to note that the detection of this land of alkali cation impurity in ionic liquids is not easy with traditional methods for reaction monitoring in ionic liquid synthesis (such as conventional NMR spectroscopy). More specialized procedures are required to quantify the amount of alkali ions in the ionic liquid or the quantitative ratio of organic cation to anion. Quantitative ion chromatography is probably the most powerful tool for this kind of quality analysis. 

What constitutes an ionic liquid, as distinct from a molten salt It is generally accepted that ionic liquids have relatively low melting points, ideally below ambient temperature [1, 2]. The distinction is arbitrarily based on the salt exhibiting liquidity at or below a given temperature, often conveniently taken to be 100 °C. However, it is clear from observation that the principle distinction between the materials of interest today as ionic liquids (and more as specifically room-temperature ionic liquids) and conventional molten salts is that ionic liquids contain organic cations rather than inorganic ones. This allows a convenient differentiation without concern that some molten salts may have lower melting points than some ionic liquids . 

It should also be noted that terms such as high temperature and low temperature are also subjective, and depend to a great extent on experimental context. If we exclusively consider ionic liquids to incorporate an organic cation, and further limit the selection of salts to those that are liquid below 100 °C, a large range of materials are still available for consideration. 

However, ionic liquids containing other classes of organic cations are known. Room-temperature ionic liquids containing organic cations including quaternary ammonium, phosphonium, pyridinium, and - in particular - imidazolium salts are currently available in combination with a variety of anions (Figure 3.1-1 provides some common examples) and have been studied for applications in electrochemistry [7, 8] and in synthesis [9-11]. 

In some cases there is evidence of multiple solid-solid transitions, either crystal-crystal polymorphism (seen for Cl salts [20]) or, more often, formation of plastic crystal phases - indicated by solid-solid transitions that consume a large fraction of the enthalpy of melting [21], which also results in low-energy melting transitions. The overall enthalpy of the salt can be dispersed into a large number of fluxional modes (vibration and rotation) of the organic cation, rather than into enthalpy of fusion. Thus, energetically, crystallization is often not overly favored. 

The viscosities of non-haloaluminate ionic liquids are also affected by the identity of the organic cation. For ionic liquids with the same anion, the trend is that larger allcyl substituents on the imidazolium cation give rise to more viscous fluids. For instance, the non-haloaluminate ionic liquids composed of substituted imidazolium cations and the bis-trifyl imide anion exhibit increasing viscosity from [EMIM], [EEIM], [EMM(5)IM], [BEIM], [BMIM], [PMMIM], to [EMMIM] (Table 3.2-1). Were the size of the cations the sole criteria, the [BEIM] and [BMIM] cations from this series would appear to be transposed and the [EMMIM] would be expected much earlier in the series. Given the limited data set, potential problems with impurities, and experimental differences between laboratories, we are unable to propose an explanation for the observed disparities. 

Some examples of organic anionic inhibitors are sodium phosphates, thioureas and sodium MBT phosphionates (mercaptobenzothiazole). Some examples of organic cationic inhibitors are amines, amides, quaternary ammonium salts, and imidazoline. 

The introduction of another organic cation function, guanidinium group, into macrocyclic structures such as (IV)-(VI) produces ligands which also display affinity for phosphate anions58). 

This is a common problem when using elemental lithium negative electrodes in contact with electrolytes containing organic cationic groups, regardless of whether the electrolyte is an organic liquid or a polymer [4]. 

Ledwith, A. and Sherrington, D. C. Stable Organic Cation Salts Ion Pair Equilibria and Use in Cationic Polymerization. Vol. 19, pp. 1 — 56. 

Ionic contrast media are triiodobenzene derivatives carrying a negative electrical charge, water soluble only as sodium or meglumine (an organic cation similar to glucosamine) salts. 

Methly-4-phenyl-l, 2,3,6-tetrahydropytidine Organic Cation Transporters... 

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