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Persistent organic cationic complexes cation

Persistent Organic Cationic Complexes Structure and Reactivity... [Pg.131]

Electron-transfer oxidation in equation (3b) can be considered to consist of a series of preequilibria, in the limit where the radical cation of the organic donor and radical anion of the acceptor are both persistent species (equation 6a). The fu-st set of brackets encloses the electron donor-acceptor or EDA precursor complex, and the second set the contact ion pair or CIP successor complex that is constrained by the solvent cage. Intermolecular reactions of that lead to the oxidation products largely occur subsequent to cage escape (ki). [Pg.852]


See other pages where Persistent organic cationic complexes cation is mentioned: [Pg.142]    [Pg.1994]    [Pg.53]    [Pg.13]    [Pg.188]    [Pg.42]    [Pg.145]    [Pg.160]    [Pg.230]    [Pg.685]    [Pg.1]    [Pg.280]    [Pg.741]    [Pg.224]    [Pg.83]    [Pg.259]    [Pg.404]    [Pg.268]    [Pg.414]   
See also in sourсe #XX -- [ Pg.132 ]

See also in sourсe #XX -- [ Pg.132 ]




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