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Structure states

Before entering the detailed discussion of physical and chemical adsorption in the next two chapters, it is worthwhile to consider briefly and in relatively general terms what type of information can be obtained about the chemical and structural state of the solid-adsorbate complex. The term complex is used to avoid the common practice of discussing adsorption as though it occurred on an inert surface. Three types of effects are actually involved (1) the effect of the adsorbent on the molecular structure of the adsorbate, (2) the effect of the adsorbate on the structure of the adsorbent, and (3) the character of the direct bond or local interaction between an adsorption site and the adsorbate. [Pg.582]

Elastic scattering involves no pemianent changes in the internal structures (states a and P) of A and B. Both the energy rel and angular momentum L (AB) of relative motion are tiierefore all conserved. [Pg.2006]

The most important equilibrium pliase relationship is diat between liquid and vapor. Raoult s mid Henry s laws theoretically describe liquid-vapor behavior mid, mider certain conditions, are applicable in practice. Raoult s law, sometimes useful for mi.vtures of components of similar structure, states diat die partial pressure of any component in die vapor is equal to die product of the vapor pressure of the pure component and die mole fracdon of tliat component in die liquid. It may be written in die following maimer... [Pg.127]

The maturation of proteins into their final structural state often involves the cleavage or formation (or both) of covalent bonds, a process termed posttranslational modification. Many polypeptides are initially synthesized as larger precursors, called proproteins. The extra polypeptide segments in these proproteins often serve as leader sequences that target a polypeptide... [Pg.37]

Figure 22. Shown in panel (a) is the relation between the bare energy difference e between frozen-in structural states in a glass and the effective splitting e that is smaller due the level repulsion in the tunnehng center. Panel (b) depicts schematically the derivative of e with respect to e, which is used to compute the new effective distribution P(e) of the transition energies. Figure 22. Shown in panel (a) is the relation between the bare energy difference e between frozen-in structural states in a glass and the effective splitting e that is smaller due the level repulsion in the tunnehng center. Panel (b) depicts schematically the derivative of e with respect to e, which is used to compute the new effective distribution P(e) of the transition energies.
The branching ratios for the fine structure states of the 0(3Pj) were measured by placing a 2-inch diameter active area photomultiplier tube... [Pg.287]

Let us assume that system 0 can be transformed to system 1 through the continuous change of some parameter A defined such that Ao and Ai correspond to systems 0 and 1, respectively. This parameter could be a macroscopic variable - viz. the temperature, a parameter that transforms J o to -A j, or a generalized coordinate (e.g., a torsional angle or an intermolecular distance) that allows the different structural states of the system to be distinguished. It follows that ... [Pg.21]

Alves, I. D. Cowell, S. M. Salamon, Z. Devanathan, S. Tollin, G. Hruby, V. J., Different structural states of the proteolipid membrane are produced by ligand binding to the human 8 opioid receptor as shown by plasmon waveguide resonance spectroscopy, Mol. Pharmacol. 2004, 65, 1248 1257... [Pg.444]

The structural state of dendritic macromolecules at air-water (Langmuir mono-layers) and air-solid (adsorbed monolayers, self-assembled films and cast films) interfaces have been reviewed by Tsukruk [17]. Although this work summarizes various characterization techniques for dendritic films by AFM techniques, in this chapter, we will present recent progress on the characterization of the dendritic film surface morphologies. [Pg.288]

The most intense alteration of the structural state of DNA in the presence of photoexcited fullerene C60 was observed in EAC cells. As one may see from Fig. 6.4c, during 5 h the increase in the content of DNA degradation products was observed ... [Pg.132]

These observations, together with those on supercoiled DNAs relaxed by intercalating dyes and by topoisomerase I, indicate that complete conversion from the prevalent secondary structures in supercoiled DNAs to the normal B-helix must be severely hindered kinetically. It is also clear that the free energies per base pair of the secondary structure states a and b must be nearly identical in order for these states to be interconverted by such a small environmental perturbation. [Pg.207]

A. S. Benight, J. Langowski, B. S. Fujimoto, and J. M. Schurr, unpublished results). It appears that the transition is not induced in samples with higher than normal superhelix densities. This suggests that the equilibrium between the secondary structure states a and b might be rather sensitive to superhelical stress. This question is addressed immediately below. [Pg.208]


See other pages where Structure states is mentioned: [Pg.113]    [Pg.391]    [Pg.409]    [Pg.462]    [Pg.457]    [Pg.13]    [Pg.13]    [Pg.10]    [Pg.181]    [Pg.108]    [Pg.110]    [Pg.125]    [Pg.126]    [Pg.131]    [Pg.132]    [Pg.143]    [Pg.165]    [Pg.169]    [Pg.172]    [Pg.172]    [Pg.173]    [Pg.173]    [Pg.35]    [Pg.81]    [Pg.336]    [Pg.85]    [Pg.29]    [Pg.409]    [Pg.534]    [Pg.183]    [Pg.34]    [Pg.223]    [Pg.75]    [Pg.131]    [Pg.131]    [Pg.133]    [Pg.48]    [Pg.139]    [Pg.231]   
See also in sourсe #XX -- [ Pg.241 , Pg.242 , Pg.244 ]




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Acetic acid solid state structure

Addition reactions transition-state structures

Aggregation states cross-linked structures

Ambivalent Lewis structures the transition-state limit

Aminomethylation solid state structure

Anhydro- hydroxides solid state structure

Application of linear free energy relationships to elucidate E2 transition state structure

Approximating H for solid-state structures

Assembled structures crystal states

Assembled structures pillar arenes - crystal states

Asymmetric induction crystal structure-solid state

Atomic structure, quantum mechanics spectroscopic states

Aziridines transition state structure

Band analysis, excited-state structure

Cadmium solid state structure

Calculated vs. Experimental Isotope Effects and Transition State Structure

Catenanes solid state structure

Chain structure solid state self-assembly

Characterization of Solid State Molecular and Supermolecular Structure

Chiral Structures and States

Claisen rearrangements transition state structures

Cluster compounds state intermetallic structures

Coherent states radiation phase structure

Coherent states structural physical effects

Complex solid state, structures

Complexed lithium amides solid-state structures

Composition and Solid-state Structure

Conformation crystal structure-solid state

Controlled solid state structures

Creatine kinase transition state structure

Cross-interaction constants and transition-state structure in solution

Crystal structure multi-state

Crystal structure-solid state reactivity

Crystal structure-solid state reactivity relationships

Crystalline state chemical structure effect

Crystalline state crystal structure determination

Crystalline state hierarchical structure

Crystalline structures impurity states

Crystallographic approaches to transition state structures

Cycle-State Structure from Global Eigenvalue Spectrum

Cyclic ethers transition state structures

Cyclic transition-state structures

Denatured state structure

Deuterium kinetic isotope effects, secondary, and transition state structure

Diels-Alder reaction transition state structure

Diimine solid state structures

Dissipative structure states

Dissipative structures uniform states

EM and transition state structure

Effective charge and transition-state structure in solution

Electrode band structure and interface states

Electronic Band Structure and Surface States

Electronic Configuration, Oxidation States, Structures

Electronic Structure of Transition States

Electronic excited states molecular structure

Electronic structure Bloch states

Electronic structure calculations transition state theory

Electronic structure excited state configurations

Electronic structure ground state configurations

Electronic structure ground state properties

Electronic structure methods for excited states

Electronic structure oxidation states

Electronic structures chemical bond state

Enolate anions solid state structures

Enthalpies of Transition State Structures

Entropies and Heat Capacities of Transition State Structures

Enzyme Active Sites Are Most Complementary to the Transition State Structure

Enzyme-catalyzed reactions transition state structures

Equilibrium states between structure elements in solids

Excited State Electronic Structure Theory

Excited state structure/dynamics

Excited state structures

Excited states and soliton structures

Excited states electronic structure

Excited states structural dynamics

Experimental examination of transition-state structure

Exploring the potential-energy surface for solid-state structures

Fine-structure states

Fluids with State-Dependent Electronic Structure

Formic acid solid state structure

Formulae solid state structures

Geometric structure excited states

Glassy state structural components

Grignard reactions transition-state structures

Ground State Electronic Structure Theory

Ground State Molecular Structures

Ground State Structure of Buckminsterfullerene

Ground state structures

Ground states electronic structures

Ground states subshell electronic structure

Ground-state calculations isotopomer structures

Ground-state optimized geometry structures

Group solid state structures

High-resolution solid-state NMR studies of polymer chemical and physical structures

Hydrogen atom crystal structure-solid state

Hydrogen fluoride solid state structure

Imido complexes solid state structure

Invariant structures phase-space transition states

KIEs as Probes of Transition State Structure

Ketal transition-state structure

Kinetic isotope effects transition state structures

Layered structures, solid-state

Layered structures, solid-state butadienes

Layered structures, solid-state polymerization

Lewis structure state

Ligand transition-state structure

Liphophilic character solid state structure

Lipid layer structures, solid-state

Liquid crystalline polymers (LCPs solid state structures

Liquid crystalline polymers solid state structures

Liquid, state structure

Lithium amides solid-state structures

Lithium halides solid state structures

Lowest excited states structure

Metal Electrodes Influence of Surface State and Structure

Metallic elements, solid state structures

Modeling solid-state structures

Molecular conformation, crystal structure-solid state

Molecular dynamics multiple states electronic structure

Molecular structures near-threshold states

Muonium ground state hyperfine structure

Nature of Organic Ion-Radicals and Their Ground-State Electronic Structure

One-state structural solutions

Optimized structures of transition state

Order in the Liquid State and Structure

Ordered solid-state structure

Ordered solid-state structure recognition-directed self-assembly

Organic semiconductors solid-state structure

Organometallic complexes transition state structure

Oxiranes transition-state structures

Palladium compounds, electronic structure transition state

Partially crystalline state stack structure

Peroxo complexes solid state structures

Phase-space transition states structure

Poly ground state structure

Polyacetylene ground state structure

Polymer structural state

Polyoxoanions solid state structure

Pore structure in the dry state

Pore structure in the swollen state

Potential Energy Surface Molecular Structure, Transition States, and Reaction Paths

Potential-energy surfaces solid-state structures

Proton transfer, transition state structure

Pseudorotaxanes solid-state structures

Quantum mechanics multiple states electronic structure

Radiation phase states structural analysis

Ray and other Techniques for Structural Characterization in the Solid State

Reaction between structure elements in the solid state

Residue types, structural states

Residue types, structural states adopted

Resonance structure excited state

Reversible Spin-State Switching Involving a Structural Change

STEADY-STATE CALCULATIONS FOR CONTROL STRUCTURE SELECTION

Saccharides solid-state structures

Secondary a-deuterium kinetic isotope effect and the structure of ferrocenylmethyl carbocation type transition state

Self-assembly mechanism solid state structures

Silylated dimers, solid-state structure

Sodium amide solid state structure, 261-2

Sodium chloride solid state structure, 148-9

Solid State Structural Studies

Solid State Structures of Cadmium Complexes with Relevance for Biological Systems

Solid state chromium structures

Solid state dynamic structures

Solid state intermetallic structures

Solid state metal borides structures

Solid state structure, theory

Solid state structures

Solid state structures borides

Solid state structures carboxylic acids

Solid state structures group 2 compounds

Solid state structures halogens

Solid state structures hydrogen bonding

Solid state, polyoxoanion structure

Solid-State Structures and Conformations

Solid-State Structures of the Binary

Solid-state chemistry crystal structures

Solid-state structure calculations

Solid-state structures 7 -gallium

Solid-state structures atomic-molecular crystals

Solid-state structures covalent network crystals

Solid-state structures defects

Solid-state structures ionic crystals

Solid-state structures metallic crystals

Solid-state structures spinels

Solid-state structures, highly soluble

Solution-state NMR determination of polymer end-groups, substituents and minor structures

Space of Structure States

Spectroscopic Studies of Gap States and Laser-Induced Structural Transformations in Se-Based As-Free Amorphous Semiconductors

Spin states structural properties

State bulk heterojunction structures

Steady state structure

Steady-states structuring fields 84

Stibine solid state structure

Stilbene ground state structure

Structural Complementarity to Transition State

Structural Data in the Solid State

Structural Solid State Chemistry

Structurally stable equilibrium state

Structure State Density (SSD)

Structure and Aggregation State of Enolate Anions

Structure and Dynamics of Triplet States

Structure and properties of polymers in the pure amorphous liquid state

Structure chitin, solid state

Structure chitosan, solid state

Structure in the solid state

Structure of the Starting State

Structure of the transition state

Structure solid state NMR

Structure, three-dimensional molten globule state

Structures and Bonding in the Solid State

Structures of Organomagnesium Compounds in the Solid State

Sulfur solid state structure

Supramolecular synthons solid-state structure

Swollen state chain structure

Symmetry Selection Rules for Transition State Structures

Syndiospecific Transition State Structure and Syndio-Insertion Catalytic Cycle

The Crystalline State and Partially Ordered Structures

The Intercommunication of Structures in Diluted Solution and Polymers Condensed State

The Solid State Structure, Properties, and Bonding

The solid state structure of tellurium tetrachloride

Theoretical methods solid-state structures

Thioether solid state structure

Transition State Geometric Structure in the Adiabatic PT Picture

Transition State Structure Calculations

Transition metal complexes, excited state structural dynamic

Transition state drawing structure

Transition state ensemble structures

Transition state structure

Transition state structure isomerization

Transition state structure, crystallographic

Transition state structure, determination

Transition state structure, in solution

Transition state structure, secondary

Transition state structure, secondary deuterium isotope effects and

Transition state structures cyclic ether reactions

Transition state structures structural effects

Transition state structures theoretical calculations

Transition state structures, crystallographic approaches

Transition state theory electronic structure

Transition state, charge separation structures

Transition state/structure Zimmerman-Traxler

Transition state/structure chelated

Transition state/structure cyclohexanone with

Transition state/structure staggered

Transition states electronic structure

Transition states structural effects

Transition-state structure, degenerate reactions

Transition-state structure, lysozyme

Transition-state structures Subject

Transition-state structures rationalization

Transition-state structures, Grignard reagent

Transitions of regular structures two-state models

Triplet ground state structural comparisons

Two-state structure

Uranyl oxalate solid state structure

Uranyl peroxide solid state structure

Vinylidene solid state structure

Water Structure and Protonation State

Water solid-state structure

Water state structure

Water structural states

XANES structures states

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