Basic processing

The basic processing of ID and 2D data requires obligatory processing steps for transforming the raw data (FID) into a readable spectrum, i.e. Fourier transformation and phase correction to produce a spectrum with absorptive lineshapes. Finally, a few additional step.s (calibration, peak picking, integration) as discussed in chapter 4 are required before the spectrum is eventually plotted. 

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Image reconstruction from projections is a basic process in computerized tomography (CT)... 

When investigating time parameters it was shown, that a storage time in Xe of spectral purity was 10 mcs, while a restoring time was 10 ms with subsequent decrease in the case of addition of small amounts of air (less than 1%). As basic processes influencing time parameters, both dissociative recombination and three-particle adhesion of electrons to oxygen molecules have been considered. 

Loeb L B 1960 Basic Processes of Gaseous Electronics 2nd edn (Berkeley, CA University of California)... 

Cohen-Tannoudji C, Dupont-Roc J and Grynberg G 1992 Atom-Photon Interactions Basic Processes and Applications (New York Wiley)... 

Taking into account the hydration shell of the NA and the possibility of the water content changing we are forced to consider the water -I- nucleic acid as an open system. In the present study a phenomenological model taking into account the interdependence of hydration and the NA conformation transition processes is offered. In accordance with the algorithm described above we consider two types of the basic processes in the system and thus two time intervals the water adsorption and the conformational transitions of the NA, times of the conformational transitions being much more greater... 

Therefore, if a large quantity of sample is introduced into the flame over a short period of time, the flame temperature will fall, thus interfering with the basic processes leading to the formation and operation of the plasma. Consequently introduction of samples into a plasma flame needs to be controlled, and there is a need for special sample-introduction techniques to deal with different kinds of samples. The major problem with introducing material other than argon into the plasma flame is that the additives can interfere with the process of electron formation, a basic factor in keeping the flame self-sustaining. If electrons are removed from the plasma by... 

This is the basic process in an inductively coupled plasma discharge (ICP). The excited ions can be examined by observing the emitted light or by mass spectrometry. Since the molecules have been broken down into their constituent atoms (as ions) including isotopes, these can be identified and quantified by mass spectrometry, as happens with isotope ratio measurements. 

There are many variations of the basic process and the patent Hterature is extensive. Several key patents describe the technology (16). The process steps are oxidation of cumene to a concentrated hydroperoxide, cleavage of the hydroperoxide, neutralization of the cleaved products, and distillation to recover acetone. 

CO, and methanol react in the first step in the presence of cobalt carbonyl catalyst and pyridine [110-86-1] to produce methyl pentenoates. A similar second step, but at lower pressure and higher temperature with rhodium catalyst, produces dimethyl adipate [627-93-0]. This is then hydrolyzed to give adipic acid and methanol (135), which is recovered for recycle. Many variations to this basic process exist. Examples are ARCO s palladium/copper-catalyzed oxycarbonylation process (136—138), and Monsanto s palladium and quinone [106-51-4] process, which uses oxygen to reoxidize the by-product... 

Fabrication technologies for ah electronic ceramic materials have the same basic process steps, regardless of the appHcation powder preparation, powder processing, green forming, and densiftcation. 

Any one of the five basic processes may be responsible for limiting the extraction rate. The rate of transfer of solvent from the bulk solution to the soHd surface and the rate into the soHd are usually rapid and are not rate-limiting steps, and the dissolution is usually so rapid that it has only a small effect on the overall rate. However, knowledge of dissolution rates is sparse and the mechanism may be different in each soHd (1). 

The earhest frothing process developed was the Dunlop process, which made use of chemical gelling agents, eg, sodium fluorosiUcate, to coagulate the mbber particles and deactivate the soaps. The Talalay process, developed later, employs freeze-coagulation of the mbber followed by deactivation of the soaps with carbon dioxide. The basic processes and a multitude of improvements are discussed extensively in Reference 3. A discussion more oriented to current use of these processes is given in Reference 115. 

Natural-gas components include water vapor, carbon dioxide (qv), sometimes hydrogen sulfide, heavier hydrocarbons (qv), methane, nitrogen, small amounts of argon, traces of neon and hydrogen, and helium. The production of pure helium from natural gas requires three basic processing steps (73). 

Most commercial processes involve copolymerization of ethylene with the acid comonomer followed by partial neutralization, using appropriate metal compounds. The copolymerization step is best carried out in a weU-stirred autoclave with continuous feeds of all ingredients and the free-radical initiator, under substantially constant environment conditions (22—24). Owing to the relatively high reactivity of the acid comonomer, it is desirable to provide rapid end-over-end mixing, and the comonomer content of the feed is much lower than that of the copolymer product. Temperatures of 150—280°C and pressures well in excess of 100 MPa (1000 atm) are maintained. Modifications on the basic process described above have been described (25,26). When specific properties such as increased stiffness are required, nonrandom copolymers may be preferred. An additional comonomer, however, may be introduced to decrease crystallinity (10,27). 

Russian Process Technology. Magnesium production ia the former Soviet Union is apparently done via molten chloride electrolysis (29,30). The basic process uses camaOite [1318-27-0], MgCl2 KCl 6H20, either from natural deposits or as a by-product of processiag natural salt deposits, as its... 

Three basic processes exist for the thermal reduction of magnesium oxide the Pidgeon process, the Magnetherm process, and the BoKano process. 

Chemical Separation. A reprocessing facility typically utilizes multiple extraction/reextraction (stripping) cycles for the recovery and purification of uranium and plutonium. For example, a co-decontamination and partitioning cycle is followed by one or more cycles of uranium and plutonium purification. The basic process is illustrated in Figure 3. 

Propylene oxide [75-56-9] (methyloxirane, 1,2-epoxypropane) is a significant organic chemical used primarily as a reaction intermediate for production of polyether polyols, propylene glycol, alkanolamines (qv), glycol ethers, and many other useful products (see Glycols). Propylene oxide was first prepared in 1861 by Oser and first polymerized by Levene and Walti in 1927 (1). Propylene oxide is manufactured by two basic processes the traditional chlorohydrin process (see Chlorohydrins) and the hydroperoxide process, where either / fZ-butanol (see Butyl alcohols) or styrene (qv) is a co-product. Research continues in an effort to develop a direct oxidation process to be used commercially. 

Many factors affect the mechanisms and kinetics of sorption and transport processes. For instance, differences in the chemical stmcture and properties, ie, ionizahility, solubiUty in water, vapor pressure, and polarity, between pesticides affect their behavior in the environment through effects on sorption and transport processes. Differences in soil properties, ie, pH and percentage of organic carbon and clay contents, and soil conditions, ie, moisture content and landscape position climatic conditions, ie, temperature, precipitation, and radiation and cultural practices, ie, crop and tillage, can all modify the behavior of the pesticide in soils. Persistence of a pesticide in soil is a consequence of a complex interaction of processes. Because the persistence of a pesticide can govern its availabiUty and efficacy for pest control, as weU as its potential for adverse environmental impacts, knowledge of the basic processes is necessary if the benefits of the pesticide ate to be maximized. 

The Claus process is the most widely used to convert hydrogen sulfide to sulfur. The process, developed by C. F. Claus in 1883, was significantly modified in the late 1930s by I. G. Farbenindustrie AG, but did not become widely used until the 1950s. Figure 5 illustrates the basic process scheme. A Claus sulfur recovery unit consists of a combustion furnace, waste heat boiler, sulfur condenser, and a series of catalytic stages each of which employs reheat, catalyst bed, and sulfur condenser. Typically, two or three catalytic stages are employed. 

Modifications and improvements to the basic process have been made to reduce the quantity of waste products (21,22) in the wet chemical process, to recover HF, and to economically process low Ta, high Nb containing raw materials (23). Several alternative extraction media have been reported in the hterature. Most, except for tributylphosphate (TBP) (24) and tri- -octylphosphine oxide (TOPO) (25), have never been used in industry. 

Instant tea is manufactured in the United States, Japan, Kenya, Chile, Sri Lanka, India, and China. Production and consumption in the United States is greater than in the rest of the world. World production capacity of instant teas depends on market demand but is in the range of 8,000 to 11,000 t/yr (3). The basic process for manufacture of instant tea as a soluble powder from dry tea leaf includes extraction, concentration, and drying. In practice, the process is considerably more compHcated because of the need to preserve the volatile aroma fraction, and produce a product which provides color yet is soluble in cold water, all of which are attributes important to iced tea products (88). 

There are a number of minerals in which thorium is found. Thus a number of basic process flow sheets exist for the recovery of thorium from ores (10). The extraction of mona ite from sands is accompHshed via the digestion of sand using hot base, which converts the oxide to the hydroxide form. The hydroxide is then dissolved in hydrochloric acid and the pH adjusted to between 5 and 6, affording the separation of thorium from the less acidic lanthanides. Thorium hydroxide is dissolved in nitric acid and extracted using methyl isobutyl ketone or tributyl phosphate in kerosene to yield Th(N02)4,... 

The basic process technology in vaccine production consists of fermentation for the production of antigen, purification of antigen, and formulation of the final vaccine. In bacterial fermentation, technology is weU estabHshed. For viral vaccines, ceU culture is the standard procedure. Different variations of ceU line and process system are in use. For most of the Hve viral vaccine and other subunit vaccines, production is by direct infection of a ceU substrate with the vims. 

Ex situ bioremediation may use various biological wastewater treatment processes, soil piles, or land appHcation. With in situ bioremediation, the basic process is the same microbes, soil, and water working together as a bioreactor. Where the in situ techniques differ are in how contaminants and microbes are brought in contact and how oxygen, nutrients, and other chemical supplements ate distributed in the soil—water—air matrix. Typical in situ bioremediation techniques include natural or intrinsic attenuation, air sparging, and bioventing. 

Modifications of the basic process are undersoftening, spHt recarbonation, and spHt treatment. In undersoftening, the pH is raised to 8.5—8.7 to remove only calcium. No recarbonation is required. SpHt recarbonation involves the use of two units in series. In the first or primary unit, the required lime and soda ash are added and the water is allowed to settie and is recarbonated just to pH 10.3, which is the minimum pH at which the carbonic species are present principally as the carbonate ion. The primary effluent then enters the second or secondary unit, where it contacts recycled sludge from the secondary unit resulting in the precipitation of almost pure calcium carbonate. The effluent setties, is recarbonated to the pH of saturation, and is filtered. The advantages over conventional treatment ate reductions in lime, soda ash, and COg requirements very low alkalinities and reduced maintenance costs because of the stabiUty of the effluent. The main disadvantages are the necessity for very careful pH control and the requirement for twice the normal plant capacity. 

The basic process usually consists of a large reaction vessel in which air is bubbled through pressuri2ed hot Hquid toluene containing a soluble cobalt catalyst as well as the reaction products, a system to recover hydrocarbons from the reactor vent gases, and a purification system for the ben2oic acid product. 

There are many variations of the basic processing loop shown in Figure 8. Processing to produce only BT is common, often in conjunction with a toluene-to-benzene dealkylation unit. If benzene and toluene ate not to be recovered. Column B may be used to remove toluene and lighter components. 

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