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Compounding process basic principles

J. W. Crary, Ethylene/Mery lie Elastomer—Basic Principles of Compounding and Processing, Bulletin EA-030.0482, Du Pont Polymers, Stow, Ohio, Apr. 1982. [Pg.501]

The story of the ozone hole illustrates how important it is to learn the molecular details of chemical reactions. Some chemists use information about how reactions occur to design and synthesize useful new compounds. Others explore how to modify reaction conditions to minimize the cost of producing industrial chemicals. This chapter explores how chemical reactions occur at the molecular level. We show how to describe a reaction from the molecular perspective, introduce the basic principles that govern these processes, and describe some experimental methods used to study chemical reactions. [Pg.1047]

Abstract The basic principles of the oxidative carbonylation reaction together with its synthetic applications are reviewed. In the first section, an overview of oxidative carbonylation is presented, and the general mechanisms followed by different substrates (alkenes, dienes, allenes, alkynes, ketones, ketenes, aromatic hydrocarbons, aliphatic hydrocarbons, alcohols, phenols, amines) leading to a variety of carbonyl compounds are discussed. The second section is focused on processes catalyzed by Pdl2-based systems, and on their ability to promote different kind of oxidative carbonylations under mild conditions to afford important carbonyl derivatives with high selectivity and efficiency. In particular, the recent developments towards the one-step synthesis of new heterocyclic derivatives are described. [Pg.244]

Much attention has been focused on free-radical polymerization in the presence of transfer agents such processes yield -functional precursors that can in turn be reacted with unsaturated compounds carrying an antagonist function. This is the basic principle of what was referred to as a two-step macromonomer synthesis. [Pg.49]

All compounding processes share several basic scientific principles and parameters ... [Pg.269]

The basic principles of the Vinyloop process, a mechanical recycling process using an organic solvent to separate PVC compounds from other materials and provide a precipitated PVC compound with a formula similar to that of the original material, are outlined. The characteristics and target applications of the precipitated PVC compound are indicated as are the best suited raw materials for the process. The impact of a facility for the Vinyloop process on the environment and the profitability of the process are discussed and the future for the Vinyloop process is briefly considered. [Pg.77]

One of the most time-consuming steps in synthesis on solid supports is the adaptation and optimization of reaction conditions. Furthermore, the optimization process is difficult to monitor on the solid support. Magic-angle spinning NMR (MAS) or FT-IR can be used, but these are technically very demanding. A possible solution is the concept of dual linkers involving an analytical unit [200]. These can be employed not only to optimize chemical reactions on a support, but also for quality control of the compound libraries. The basic principle is outlined in Fig. 15. [Pg.101]


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