Flames temperatures

Many interferences that occur in low-temperature flames are reduced or do not occur at higher temperatures. In atomic absorption this effect is not as noticeable as in flame emission. For atomic absorption the best flame condition would be to use the lowest temperature that completely dissociates the analyte substance(s) to ground state atoms. 

If the analyte element, after dissociation, reacts with oxygen in the flame, it may form oxides, which are often very stable. A high flame temperature frequently can be used to dissociate the oxide to reform ground state atoms. Thus one method for at least partial control of stable oxide formation is to use a high-temperature flame. 

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Figure 6.28 Increasing the theoretical flame temperature by reducing excess air or combustion air preheat reduces the stack loss.

Example 6.4 The process in Fig. 6.2 is to have its hot utility supplied by a furnace. The theoretical flame temperature for combustion is 1800°C, and the acid dew point for the flue gas is 160°C. Ambient temperature is 10°C. Assume = 10°C for process-to-process heat transfer but = 30°C for flue-gas-to-process heat transfer. A high value for for flue-gas-to-process heat... 

The fuel consumption is now calculated by taking the flue gas from theoretical flame temperature to ambient temperature ... 

Flue gas recirculation. Recirculation of part of the flue gas as shown in Fig. 11.4 lowers the peak flame temperature, thus reducing formation. There is clearly a limit to how much flue gas can be recirculated without affecting the stability of the flame. 

Therefore, if a large quantity of sample is introduced into the flame over a short period of time, the flame temperature will fall, thus interfering with the basic processes leading to the formation and operation of the plasma. Consequently introduction of samples into a plasma flame needs to be controlled, and there is a need for special sample-introduction techniques to deal with different kinds of samples. The major problem with introducing material other than argon into the plasma flame is that the additives can interfere with the process of electron formation, a basic factor in keeping the flame self-sustaining. If electrons are removed from the plasma by... 

Density of argon gas (300 K) Specific heat of argon gas Flame temperature Flame dimensions (approx) Volume of 1.6 ml argon at 300K... 

Gun Propellents. Although the stresses on individual gun propellant grains are less severe because of the small size, these propellants must withstand much higher weapon pressures and accelerations. Formulation options are usually more limited for gun propellants than for rocket propellants because the products of combustion must not foul or corrode a gun, should have a low flame temperature, and should exhibit minimum flash and smoke characteristics. Gun propellants are examined microscopically for porosity, are tested for mechanical characteristics, and fired in closed bombs to determine the burning characteristics. 

Because the gaseous products ate ia thermodynamic equiUbtium at the flame temperature, quite accurate calculatioas of gas compositioa, maximum... 

Fig. 1. The postulated flame stmcture for an AP composite propellant, showing A, the primary flame, where gases are from AP decomposition and fuel pyrolysis, the temperature is presumably the propellant flame temperature, and heat transfer is three-dimensional followed by B, the final diffusion flame, where gases are O2 from the AP flame reacting with products from fuel pyrolysis, the temperature is the propellant flame temperature, and heat transfer is three-dimensional and C, the AP monopropellant flame where gases are products from the AP surface decomposition, the temperature is the adiabatic flame temperature for pure AP, and heat transfer is approximately one-dimensional. AP = ammonium perchlorate.

Oxidizers. The characteristics of the oxidizer affect the baUistic and mechanical properties of a composite propellant as well as the processibihty. Oxidizers are selected to provide the best combination of available oxygen, high density, low heat of formation, and maximum gas volume in reaction with binders. Increases in oxidizer content increase the density, the adiabatic flame temperature, and the specific impulse of a propellant up to a maximum. The most commonly used inorganic oxidizer in both composite and nitroceUulose-based rocket propellant is ammonium perchlorate. The primary combustion products of an ammonium perchlorate propellant and a polymeric binder containing C, H, and O are CO2, H2, O2, and HCl. Ammonium nitrate has been used in slow burning propellants, and where a smokeless exhaust is requited. Nitramines such as RDX and HMX have also been used where maximum energy is essential. 

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