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Furnaces combustion

Use equipment for dual purposes, such as a fuel combustion furnace to serve as a pollutant incinerator. [Pg.385]

The Claus process is the most widely used to convert hydrogen sulfide to sulfur. The process, developed by C. F. Claus in 1883, was significantly modified in the late 1930s by I. G. Farbenindustrie AG, but did not become widely used until the 1950s. Figure 5 illustrates the basic process scheme. A Claus sulfur recovery unit consists of a combustion furnace, waste heat boiler, sulfur condenser, and a series of catalytic stages each of which employs reheat, catalyst bed, and sulfur condenser. Typically, two or three catalytic stages are employed. [Pg.212]

Combustion gases—CO, NO Combustion—furnace, cooking stove, space heater, etc. [Pg.385]

An Erlenmeycr or other form of Combustion Furnace.— The usual length is 80-90 cm. (31-35 in.), and it is provided with 30 to 35 burners. Flat flame burners are undesirable. [Pg.4]

Figure 10.4 shows a schematic representation of the multidimensional GC-IRMS System developed by Nitz et al. (27). The performance of this system is demonstrated with an application from the field of flavour analysis. A Siemens SiChromat 2-8 double-oven gas chromatograph equipped with two FIDs, a live-T switching device and two capillary columns was coupled on-line with a triple-collector (masses 44,45 and 46) isotope ratio mass spectrometer via a high efficiency combustion furnace. The column eluate could be directed either to FID3 or to the MS by means of a modified Deans switching system . [Pg.226]

Weliky et al. [154] described a procedure for the determination of both organic and inorganic carbon in a single sample of a marine deposit. Carbonate carbon is determined from the carbon dioxide evolved by treatment of the sample with phosphoric acid the residue is then treated with a concentrated solution of dichromate and sulfuric acid to release carbon dioxide from the organic matter. The carbon dioxide produced at the two stages of the analysis is estimated using a carb on analyser based on the thermal conductivity principle. In addition, total carbon content is determined on another subsample using the dry combustion furnace. This provides a check on the values determined by the phosphoric acid dichromate technique. [Pg.503]

Kipp apparatus, electric combustion furnace,2 4 nitrometer, nickel dish, sieve of wire gauze, weighing bottle, and mixing tube are supplied by the laboratory. [Pg.47]

Compound-specific isotope analysis (CSIA) by GC-IRMS became possible in 1978 due to work of Mathews and Hayes [634], based on earlier low-precision work of Sano et al. [635]. The key innovation was the development of a catalytic combustion furnace based on Pt with CuO as oxygen source, placed between the GC exit and the mass spectrometer. The high pressure of helium (99.999% purity or better) ensures that all gas flows are viscous. After being dried in special traps avoiding formation of HC02 (i. e., interferes with 13C02) by ion-molecule reactions in the ion source, the C02 is transmitted to a device that regulates pressure and flow and then into the ion source [604]. [Pg.82]

Now, GC-IRMS can be used to measure the nitrogen isotopic composition of individual compounds [657]. Measurement of nitrogen isotope ratios was described by Merritt and Hayes [639], who modified a GC-C-IRMS system by including a reduction reactor (Cu wire) between the combustion furnace and the IRMS, for reduction of nitrogen oxides and removal of oxygen. Preston and Slater [658] have described a less complex approach which provides useful data at lower precision. Similar approaches have been described by Brand et al. [657] and Metges et al. [659]. More recently Macko et al. [660] have described a procedure, which permits GC-IRMS determination of 15N/14N ratios in nanomole quantities of amino acid enantiomers with precision of 0.3-0.4%o. A key step was optimization of the acylation step with minimal nitrogen isotope fractionation [660]. [Pg.84]

Tobias et al. [665] have described a method in which the GC effluent is passed into a combustion furnace to convert the organic hydrogen content into water, which is then selectively reduced to hydrogen in a reduction furnace containing Ni metal. The final stream is transmitted to the IRMS via a heated Pd filter, which passes only hydrogen isotopes to the ion source. For a benzene sample a precision of < 5 %o was obtained for <52HSMOw> which approaches the performance of off-line techniques and the requirements for studies of natural variability. This already meets requirements for analysis of D-labeled compounds used in tracer studies [666,667]. [Pg.84]

Because little has been said concerning difficulties arising from derivati-zation of samples to render them suitable for GC analysis, replacement of GC by HPLC for non-volatile or thermally labile compounds is a possibility. However, the demands of reproducible solvent removal for a reliable LC-C-IRMS approach are formidable. Caimi and Brenna [685,686] have developed an instrument based on a moving wire transport system. The analytes are deposited on the wire as they elute from the HPLC column and, after solvent drying at 200 °C, are transported into an 800 °C combustion furnace loaded with CuO, where the resulting C02 is picked up by an He carrier stream and swept via a drying trap into the IRMS. [Pg.86]

In the infrared detection system, the sample is weighed into a special ceramic boat which is then placed into a combustion furnace at 1371°C (2500°F) in an oxygen atmosphere. Most of the sulfur present is converted to sulfur dioxide, which is then measured with an infrared detector after moisture and dust are removed by traps. The calibration factor is determined using standards approximating the material to be analyzed. [Pg.298]

The compositions of biomass among fuel types are considerably varied, especially with respect to inorganic constituents important to the critical problems of fouling and slagging. Alkali and alkaline earth metals, in combination with other fuel elements such as silica and sulfur, and facilitated by the presence of chlorine, are responsible for many imdesirable reactions in combustion furnaces and power boilers. [Pg.51]

The manual procedure for determination of total nitrogen by chemiluminescence involves preparing the standards from a stock solution, diluting the samples, injecting the standards into the combustion furnace for analysis, and calculation of the nitrogen content of the samples. The calculation is based on the signal from the diluted sample compared to the standard curve and the dilution factor for the sample. [Pg.184]

Higher-molecular-weight polynuclear aromatics can cause problems during processing of crude. They are known to contribute to deposit formation and fouling of refining equipment and fuel combustion furnaces. Also, some polynuclear aromatic compounds found in crude oil have been determined to be human carcinogens. [Pg.34]

As was previously mentioned, trace elements that sublime at temperatures below those attained during coal combustion (e.g., As, Se, Hg, Zn), and are associated with thermally unstable solid phases (in particular organic matter and sulphide minerals), are subject to vaporization into furnace gases. Once these gases, and fly ash particles entrained in the gases, are vented from the combustion furnace they quickly cool, leading to the condensation of volatilized elements onto the... [Pg.240]

Incomplete combustion furnace black process petrochemical oils and coal tar oils... [Pg.150]

Advancement in this research area was made possible through the development of the BCR 7-lb. combustion furnace (13, 19). In this furnace, coals can be classified quantitatively in terms of their relative combustion perform-... [Pg.581]

Hypovanadic Chloride, vanadium tetrachloride, VC14, can be prepared synthetically from the lower chloride, VC13, by heating in a stream of chlorine at 600° C. Another convenient method consists in passing dry chlorine over ferrovanadium contained in a hard glass tube heated in a combustion furnace. The reaction is expressed ... [Pg.43]

Prior to either of these steps, fourteen of the twenty burners of the combustion furnace are lighted (Note 4) and tiles are placed over the lighted burners, which finally must be adjusted to yield a maximum temperature. The first two and last four burners are unused. [Pg.39]

With an electric combustion furnace, wherein a tempera-... [Pg.41]

After combustion furnaces have come to thermal equilibrium, turn combustion cycle control to START and let it proceed normally through the cycle. Observe indicated temperature on pyrometer of both upper and lower combustion furnaces at the end of the combustion portion of cycle. [Pg.108]


See other pages where Furnaces combustion is mentioned: [Pg.478]    [Pg.13]    [Pg.354]    [Pg.477]    [Pg.237]    [Pg.169]    [Pg.289]    [Pg.343]    [Pg.343]    [Pg.362]    [Pg.175]    [Pg.38]    [Pg.82]    [Pg.82]    [Pg.545]    [Pg.85]    [Pg.193]    [Pg.226]    [Pg.227]    [Pg.26]    [Pg.68]    [Pg.104]    [Pg.588]    [Pg.57]    [Pg.482]    [Pg.46]    [Pg.764]   
See also in sourсe #XX -- [ Pg.448 ]




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