Acrylates methyl acrylate

Acetyl chloride, see 1.1.1-Trichloroethane Acetyl-CoA, see Cyclohexane Acetylene, see Benzene. Ethylenimine, Hexachloroethane, TCDD Acrolein, see Acrylonitrile, Allyl alcohol, Atrazine. Acrylamide, see Acrylonitrile Acrylic acid, see Acrylamide, Ethyl acrylate. Methyl acrylate... [Pg.1518]

Acrylonitrile, 1,1-Dichloroethylene, Ethyl acrylate. Methyl acrylate. Methyl methacrylate Y-Hydroxy-y-o-hydroxyphenyl-a-oxobutyrate, see Carbaryl... [Pg.1532]

Fig. 7.8. (a) Normalized impact fracture toughness and (b) interlaminar shear strength (ILSS) of carbon fiber-epoxy matrix composites as a function of glycidyl acrylate/methyl acrylate (GA/MA) interlayer... [Pg.292]

Allyl acrylate n-Butyl acrylate Methyl acrylate Methacrylonitrile Methyl isopropenyl ketone N-Vinyl pyrrolidone 2-Vinyl pyrrolidone Vinylidene chloride... [Pg.51]

The synthesis of amphopropionates is thus similar to the amphoacetates except that, rather than sodium chloride being formed as a by-product, methanol often is. If made from methyl acrylate, there is usually about 5-7% methanol in the surfactant product. If alkylation is conducted with sodium acrylate, methyl acrylate is the more efficient alkylating agent. [Pg.176]

In the first detailed study of benzoin photoinitiated polymerization of vinyl monomers (styrene, butyl acrylate, methyl acrylate and methyl... [Pg.56]

Aqueous emulsions of styrene, methyl methacrylate, methyl acrylate, and ethyl acrylate were polymerized with y-radiation from a Co source in the presence of sodium dodecyl sulfate or sodium laurate. The continuous measurement of conversion and reaction rate was carried out dilato-metrically. The acrylates polymerized fastest and the over-all polymerization rate increased as follows styrene < methyl methacrylate < ethyl acrylate methyl acrylate. The effects of radiation dose, temperature, and original monomer and emulsifier concentrations were studied with respect to the following factors properties of polymer dispersions, number and size of polymer particles, viscometrically determined molecular weights, monomer-water ratio, and kinetic constants. [Pg.60]

AcrylatSS See Acrylic Acid Ethyl Acrylate Methyl Acrylate. [Pg.45]

Acryclic acid is obtained by the catalytic oxidation of propylene and acrylates (methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate...) by alcohol esterification of the acid. The preparation of methacrylic acid involves the acidic hydrolysis of acetone cyanohydrin and methyl methacrylate is obtained by a similar process involving the methanolysis of acetone cyanohydrin. [Pg.502]

It is very clear that if the initiator has hydroxyl groups, and if the termination takes place exclusively by recombination then a polymeric diol is obtained [2, 3], which is ideal for polyurethane. If the termination takes place by disproportionation, only monofunctional compounds are obtained, which cannot be used in PU. The vinylic and dienic monomers used in practice have various termination mechanisms. Some monomers give only recombination reactions, such as styrene, acrylates (methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethyl hexyl acrylate), acrylonitrile and butadiene. Other monomers give both mechanisms of termination, around 65-75% disproportionation and 25-35% recombination, such as methacrylates (methyl methacrylate, ethyl methacrylate, butyl methacrylate etc.), substituted styrenes and other monomers [2, 3, 4]. [Pg.296]

Acrylates Methyl acrylates, methanol, acetone, butanol... [Pg.531]

Eethal concentration Median lethal dose Eow-density polyethylene Einear low-density polyethylene Maleic anhydride Methacrylic acid Methyl acrylate Methyl acrylate Methacrylonitrile Modified atmosphere packaging Methyl butyl ketone 2-Mercaptobenzothiazole 4,4 -Methylene dianiline Medium density fibreboard Magnesium hydroxide Methylene diisocyanate Medium density PE Monoethylhexyl phthalate Methylethyl ketone Melamine-formaldehyde Methyl isoamyl ketone... [Pg.296]

D Butyl acrylate/methyl acrylate/ Rohagum P-24... [Pg.1460]

Acramin Binder 27 Acramin Binder 1900D Butyl acrylate/methyl acrylate/ methylmethacrylate copolymer. Ethyl acrylate/methyl methacrylate copolymer binder, iaminating... [Pg.1461]

Isobornyl methacrylate Isodecyl methacrylate Karaya (Sterculia urens) gum Methoxyethyl acrylate Methyl acrylate Sodium allyloxy hydroxypropyl sulfonate Sodium laureth sulfate Vinyl acetate/ethylene/vinyl chloride terpolymer Vinyl chloride/vinyl acetate copolymer coatings, tungsten base metals Tungsten hexachloride coatings, TV picture tubes Tetramethoxysilane coatings, urethane Pentaerythritol... [Pg.4979]

DL-Diepoxybutane Methacrylic acid Methyl acrylate Methyl acrylate polymer Succinaldehyde Vinyl acetate (C4H602)x... [Pg.7031]

Lacroix and coworkers reported a reverse iodine transfer pol5mierization (RITP), where elemental iodine is used as a control agent in living radical polymerization [288]. Styrene, butyl acrylate, methyl acrylate, and butyl ot-fluoroacrylate were homopolymerized, using a radical catalyst and I2 as a chain transfer agent. Methyl acrylate was also copolymerized with vinyUdene chloride using this process. [Pg.130]

A number of acrylic resins are used for bonding cloth, plastics, leather, and, in some cases, metal foils. The acryhc monomers most commonly used in adhesives are ethyl acrylate, methyl acrylate, methacryhc acid, acrylic acid, acrylamide, and acrylonitrile. The polymers or copolymers are soluble in common organic solvents and can be supplied in much the same manner as other solvent-based systems. In addition, the polymers are soluble in the monomers. When a catalyst is added, monomers polymerize, thus providing good bonding to glass and to plastic surfaces of similar composition (e.g., polymethylmethacrylate). ... [Pg.64]

Methyl acrylate Methyl acrylate-co-vinyl acetate Clear films II had 25-75 % methyl acrylate Kosai et al. (1977)... [Pg.2060]

Chem ical RasiStanCG. Acrylic polymers and copolymers are highly resistant to hydrolysis. This property differentiates acrylic polymers from poly(vinyl acetate) and vinyl acetate copolymers. When exposed to highly extremely acidic or alkaline environments, acrylic ester polymers can hydrolyze to poly(acrylic acid) and the corresponding alcohol. Resistance to hydrolysis decreases in the order butyl acrylate > ethyl acrylate > methyl acrylate. Although it is the least hydrolytically stable, methyl acrylate is still far more resistant to hydrolysis than vinyl acetate (57,58). [Pg.151]

Of the two common comonomers incorporated in textile-grade acrylics, methyl acrylate is the least active in chain transfer, whereas vinyl acetate is as active in chain transfer as DMF. Vinyl acetate is also known to participate in the chain transfer-to-polymer reaction (31). This occurs primarily at high conversion, where the concentration of polsrmer is high and monomer is scarce. [Pg.188]

The first useful acrylic PSAs were introduced in the 1950s with the incorporation of high Tg functional monomers (23), such as acrylic acid and acrylamide, used for reinforcement. This continues to be a widely used approach for acrylic PSA reinforcement. Typical acrylic PSAs contain up to 10% of these reinforcing monomers. Additional high Tg, but nonfunctional, monomers may also be added to the copolymer, with some typical examples being vinyl acetate, ethyl acrylate, methyl acrylate, and methyl methacrylate. [Pg.6717]

Ma, Q., and Wooley, K. L. (2000). The preparation of t-butyl acrylate, methyl acrylate, and styrene block copolymers by atom transfer radical polymerization precursors to amphiphilic and hydrophilic block copolymers and conversion to complex nanostructured materials. /. Polym. Sci., Part A Polym. Chem., 3 (Suppl.) 4805-4820. [Pg.929]

Allyl acrylate tert-Butyl acrylate Methyl acrylate... [Pg.122]

Iso-Butyl Acrylate Methyl Acrylate Acrolein Acrylamide Acrylonitrile Charcoal I-Dodecene Adipic Acid Dioctyl Adipate... [Pg.127]

Methylacrylate - 2,3-dibromopropyl acrylate, methyl acrylate-2,3-dibromopropyl methacrylate GC-MS [109]... [Pg.263]

The nanoparticles consist of pyrogenic colloidal SiOj (Aerosol 1380, Degussa Co., Germany) with an average particle size of 7 nm. Styrene, acrylamide, methyl methacrylate, butyl acrylate, ethyl acrylate, methyl acrylic acid, and vinyl acetate, were used as grafting monomers without further purification. [Pg.27]

The polymerization of acrylates (methyl acrylate, n-butyl acrylate, t-butyl acrylate) was also investigated by Onishi et by using a half-metallocene iron iodide complex [Fe(Cp)I(CO)2] catalyst, Al(OiPr)3 or Ti(OiPr)4 as cocatalysts, and ethyl-2-iodoisobutyrate as inidator at T= 60-80 °C in toluene (Scheme 15e). For instance, poly(methyl acrylate) polymers of Afn= 12 lOOgmoT with PDI = 1.19 were obtained with 93% monomer conversion. Methyl acrylate and iV,iV-dimethylacrylamide were also controlled by using a Fe2Cp2 (00)4/12 system for which a combinadon of metal-catalyzed. Stable radical-mediated, and DT is expected to take place. ... [Pg.169]

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