Poly methyl acrylate

Poly(methyl acrylate) Poly(methyl methacrylate)... 

Concerning the reaction of ACPC with diols, the frequent use of poly(ethylene glycol) has to be mentioned [20-24]. Ueda et al. ([22-24]) reacted preformed poly(ethylene glycol) (Mn between 6 x 10 to 2 x 10 ) with ACPC. In this case, unlike the reaction of ACPA with diols vide ante), no additional condensation agent was needed. The ethylene glycol-based thermally labile polymers were used to produce blocks with poly(vinyl chloride) [22], poly(styrene) [23], poly(methyl acrylate), poly(vinyl acetate), and poly(acrylonitrile) [24]. 

CHCH2-) COOCH3 poly(methyl acrylate) poly [ 1 -(methoxycarbonyl) ethane-1,2-diyl]... 

J. L. Gomez Ribelles, M. Monleon Pradas, G. Gallego Ferrer, N. Peidro Torres, V. Perez Gimenez, P. Pissis, and A. Kyritsis, Poly(methyl acrylate)/poly(hydroxyethyl acrylate) sequential interpenetrating polymer networks. Miscibility and water sorption behavior, J. Poly. Sci. B 37, 1587-1599 (1999). 

Poly(methyl acrylate) Poly(methyl methacrylate) Polyacrylonitrile Polymethacrylonitrile Polybutadiene Polyisoprene Polychloroprene Poly(methylene oxide) Poly(ethylene oxide) Poly(tetramethylene oxide) Poly(propylene oxide) Poly(hexamethylene succinate) Poly(hexamethylene sebacate) Poly(ethylene terephthalate) Nylon 6 Polycarbonate... 

PB PBI PBMA PBO PBT(H) PBTP PC PCHMA PCTFE PDAP PDMS PE PEHD PELD PEMD PEC PEEK PEG PEI PEK PEN PEO PES PET PF PI PIB PMA PMMA PMI PMP POB POM PP PPE PPP PPPE PPQ PPS PPSU PS PSU PTFE PTMT PU PUR Poly(n.butylene) Poly(benzimidazole) Poly(n.butyl methacrylate) Poly(benzoxazole) Poly(benzthiazole) Poly(butylene glycol terephthalate) Polycarbonate Poly(cyclohexyl methacrylate) Poly(chloro-trifluoro ethylene) Poly(diallyl phthalate) Poly(dimethyl siloxane) Polyethylene High density polyethylene Low density polyethylene Medium density polyethylene Chlorinated polyethylene Poly-ether-ether ketone poly(ethylene glycol) Poly-ether-imide Poly-ether ketone Poly(ethylene-2,6-naphthalene dicarboxylate) Poly(ethylene oxide) Poly-ether sulfone Poly(ethylene terephthalate) Phenol formaldehyde resin Polyimide Polyisobutylene Poly(methyl acrylate) Poly(methyl methacrylate) Poly(methacryl imide) Poly(methylpentene) Poly(hydroxy-benzoate) Polyoxymethylene = polyacetal = polyformaldehyde Polypropylene Poly (2,6-dimethyl-l,4-phenylene ether) = Poly(phenylene oxide) Polyp araphenylene Poly(2,6-diphenyl-l,4-phenylene ether) Poly(phenyl quinoxaline) Polyphenylene sulfide, polysulfide Polyphenylene sulfone Polystyrene Polysulfone Poly(tetrafluoroethylene) Poly(tetramethylene terephthalate) Polyurethane Polyurethane rubber... 

Phase behavior studies with poly(ethylene-co-methyl acrylate), poly (ethylene-co-butyl acrylate), poly(ethylene-co-acrylic add), and poly(ethylene-co-methacrylic acid) were performed in the normal alkanes, their olefinic analogs, dimethyl ether, chlorodifluoromethane, and carbon dioxide up to 250 °C and 2,700 bar. The backbone architecture of the copolymers as well as the solvent quality greatly influences the solution behavior in supercritical fluids. The effect of cosolvent was also studied using dimethyl ether and ethanol as cosolvent in butane at varying concentrations of cosolvent, exhibiting that the cosolvent effect diminishes with increasing cosolvent concentrations. 

In the case of the miscibility of polyacrylates with PVC the situation is more complicated as shown in Table 2. The higher acrylates are immiscible with PVC as expected but so is poly(methyl acrylate). Poly(ethyl acrylate) is a case where miscible bloids... 

In ASA terpolymer acrylic acid brings more flexibility and the material has very good mechanical properties and weather resistance. For these reasons ASA is extensively used in automotive industry and in the fabrication of various appliances. Even more frequently than acrylic acid itself, various acrylates are used in copolymers. Among these can be mentioned the copolymers of acrylic acid esters with methacrylic acid esters such as poly(methyl methacrylate-co-methyl acrylate), poly(methyl methacrylate-co-ethyl acrylate), poly(methyl methacrylate-co-butyl acrylate), poly(ethyl methacrylate-co-ethyl acrylate), poly(acrylonitrile-co-methyl acrylate), poly(alkyl acrylate-co-methyl methacrylates), and poly(alkyl acrylate-co-hydroxyethyl methacrylates) where alkyl can be methyl, ethyl, butyl, etc. Some literature information regarding thermal decomposition of copolymers including acrylic acid and acrylic acid esters is given in Table 6.7.8 [6],... 

The reactions of composite 1 with secondary polymer of amino-terminated poly(methyl acrylate), poly(methyl methacrylate) or polystyrene were carried out in acetone or tetrahydrofuran under refluxing for 24 h. The amount of the binding polymer decreased with increasing of the molecular weight, as shown in Table 17.1. 

Synonyms EMA Ethylene/methyl acrylate Poly (ethylene-co-methyl acrylate)... 

Parent homopolymers were successfully separated from various block copolymers, for example PMMA-6-poly( -propyl methacrylate), PMMA-6-poly(n-butyl acrylate), PMMA-6-poly( -pentyl methacrylate), poly(lactic acid)-i-poly(butylene terephthalate-s /at-butylene adipate), PS-6-poly(methyl acrylate), poly(Af-virtyl pyrollidone)-6-poly(caprolactone) and others. 

Poly(ethylene glycol) Poly(methyl acrylate) Poly(methyl methacrylate) Poly-2-ethylhexyl acrylate Small angle X-ray scattering... 

To evaluate this model, an experiment with a four-component system was conducted This system was a poly(methyl acrylate)/poly(vinyl acetate) (PMA/PVAc) physical blend, or mixture, consisting of four individual blends (PMA/PVAc (80/20) + PMA/PVAc (60/40) + PMA/PVAc (40/60) - -PMA/PVAc (20/80)). PMA is miscible with PVAc. The open squares in Figure 3.49 are the experimental dCp/dT data. The difference between glass transition temperatures of PMA and PVAc is about 33°C. In the glass transition region, the four-component mixture showed an acceptable fit to the experimental data, see Figure 3.49. The solid lines shown in Figure 3.49... 

Poly(methyl acrylate)/poly(n-butyl acrylate) 4.0 0.008 [6]... 

Poly (methyl vinyl ketone), poly (isopropyl vinyl ketone), ethylene-carbon monoxide copolymers Poly(vinyl acetate), poly (methyl acrylate), poly (ethyl acrylate), poly (methyl methacrylate), poly (butyl acrylate), ethylene-vinyl acetate copolymers Poly (acrylic acid),... 

The partial molar quantities of mixing were determined for normal and branched alkanes (O5 — Cio), cyclohexane, benzene and tetrachloromethane in polyisobutylene [57]. Partial molar enthalpies of mixing were measured for normal alkenes in low and high density polyethylene, polypropylene, polybutene-1, polystyrene, poly(methyl acrylate), poly(vinyl chloride), polyCN-isopropyl-acrylamide), ethylene-vinyl acetate copolymer, ethylene-carbon oxide copolymer [88] normal, branched and cyclic alkanes, benzene, n-butylbenzene, ois- and ra s-decalin, tetraline and naphthalene in polystyrene at 183, 193 and 203°C [60] these solutes in poly (methyl acrylate) [57] n-nonane, n-dodecane and benzene in polystyrene in the range 104.8 — 165.1 C [71] O7—C, C12 normal alkanes and aromatic hydrocarbons in polystyrene at an average temperature of 204.9°C [72], C7—Cg normal alkanes in poly(ethylene oxide) at an average temperature of 66.5 "C [72] normal alkanes in ethylene oxide—propylene oxide block copolymers (Pluronics L 72, L 64 and F 68) at the same average temperature [72]. 

Poly[(vinyl chloride)/ethylene/(methyl acrylate)] Poly[(vinyl chloride)/ethylene/(methyl acrylate)] Poly[(vinyl chloride)/(methyl acrylate)]... 

FIG. 12-14. Relaxation spectra in extension (H) of poly(methyl acrylate), poly(methyl methacrylate), and three copolymers with compositions indicated, reduced to I00°C. Lines drawn with slope of — Mole percent methacrylate, left to right 0,42, 61, 75,100. (Fujino, Senshu, and Kawai. °°)... 

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