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Monofunctional compounds

An example of using one predicted property to predict another is predicting the adsorption of chemicals in soil. This is usually done by first predicting an octanol water partition coelficient and then using an equation that relates this to soil adsorption. This type of property-property relationship is most reliable for monofunctional compounds. Structure-property relationships, and to a lesser extent group additivity methods, are more reliable for multifunctional compounds than this type of relationship. [Pg.121]

As noted in the text, chemists overwhelmingly use the nomenclature system devised and maintained by the International Union of Pure and Applied Chemistry, or IUPAC. Rules for naming monofunctional compounds were given throughout the text as each new functional group was introduced, and a list of where these rules can be found is given in Table A.l. [Pg.1225]

As explained earfier step polymerisations generally occur by condensation reactions between functionally substituted monomers. In order to obtain high molar mass products bifuncfional reactants are used monofunctional compounds are used to control the reaction while trifunctional species may be included in order to give branched or crosslinked polymers. A number of types of reaction may be involved, as described briefly in the following paragraphs. [Pg.35]

Relationship between Volume 9 and Previous Volumes. Compendium of Organic Synthetic Methods, Voiume 9 presents about 1200 examples of published reactions for the preparation of monofunctional compounds, updating the 10650 in Volumes 1-8. Volume 9 contains about 800 examples of reactions which prepare of difunctional compounds with various functional groups. Reviews have long been a feature of this series and Volume 9 adds almost 90 pertinent reviews in the various sections. Volume 9 contains approximately 1000 fewer entries than Volume 8 for an identical three-year period, primarily for difunctional compunds. Interestingly, there are about 500 fewer citations from the most cited journal (Tetrahedron Letters) than in the previous edition. Whether this represents a trend in the literature or an inadvertent selectivity on my part is unknown, but there has been a clear increase in biochemicai and total synthesis papers which may account for this. [Pg.15]

How to Use the Book to Locate Examples of the Preparation of Protection of Monofunctional Compounds. Examples of the preparation of one functional group from another are found in the monofunctional index on p. x, which lists the corresponding section and page. Sections that contain examples of the reactions of a functional group are found in the horizontal rows of this index. Section 1 gives examples of the reactions of alkynes that form new alkynes Section 16 gives reactions of alkynes that form carboxylic acids and Section 31 gives reactions of alkynes that form alcohols. [Pg.16]

Some preparations of alkene and acetylenic compounds from alkene and acetylenic starting materials can, in principle, be classified in either the monofunctional or difunctional sections for example, the transformation RCH=CHBr — RCH=CHCOOH could be considered as preparing carboxylic acids from halides (Section 25, monofunctional compounds) or preparing a carboxylic acid-alkene (Section 322, difunctional compounds). The choice usually depends on the focus of the particular paper where this reaction was found. In such cases both sections should be consulted. [Pg.18]

Many literature preparations of difunctional compounds are extensions of the methods applicable to monofunctional compounds. As an example, the reaction RCI — ROH might be used for the preparation of diols from an appropriate dichloro compund. Such methods are difficult to categorize and may be found in either the monofunctional or difunctional sections, depending on the focus of the original paper. [Pg.18]

The main differences between these oxidations and those of monofunctional compounds are (i) the greater number of possible sites of attack, (i7) the more frequent modification of kinetics by complex formation and in) the almost inevitable greater reactivity. [Pg.387]

These oxidants are generally too feeble to attack monofunctional compounds except thiols, carbonyl- and nitro-compounds in their enolic forms, phenols and aromatic amines. However, ferric rWj-o-phenanthroline readily oxidises cyclohexanone. [Pg.423]

Amidon, G. L, Yalkowski, S. H., Anik, S. T., Valvani, S. C. Solubility of nonelectrolytes in polar solvents V. Estimation of the solubility of aliphatic monofunctional compounds in water... [Pg.123]

Unknown 18. Figure 5.22 represents the mass spectra of three monofunctional compounds with a similar array of fragment ions. Molecular ion peaks are absent in two cases. Try to refer the substances to widespread classes of organic compounds. Take into account that the intensities of the peaks of some homologous series may be very low. [Pg.170]

Unknown 19. Figure 5.23 represents the spectra of three monofunctional compounds. Could you refer them to certain classes of organic compounds ... [Pg.170]

Figure 5.22. Mass spectra of monofunctional compounds referring to three different classes. Figure 5.22. Mass spectra of monofunctional compounds referring to three different classes.
Valvani, S. C. "Solubility of Nonelectrolytes in Polar Solvents. V. Estimation of the Solubility of Aliphatic Monofunctional Compounds in Water Using a Molecular Surface Approach" J. Phys. Chem., 1975, 79, 2239. [Pg.494]

In order to determine the electronic interaction between the amino and the alkene functionalities, the n and tt orbital energies of 32 and the two analogous monofunctional compounds l-azabicyclo[4.4.4]tetradecane (34) and bicyclo[4.4.4]tetradec-l-ene (35) should be known. n and JZ( =c of 32 and 34 have been determined by PES, while 7r =c of the unknown alkene 35 has been estimated. The data are depicted in Figure 9. [Pg.181]

Also, the transannular interactions between amino and carbonyl groups in aminoke-tones, like 40-44, were studied by PES48. Pronounced stabilization of the n orbital and destabilization of the no orbital was established by comparison of the relevant ionization potentials with those of the corresponding monofunctional compounds. The shift of the no orbital was noticed as the best indicator of transannular n /jiQ=Q interaction and the maximum value was again found for the system with an eight-membered ring (41). [Pg.182]

Many different approaches have been developed for peptide synthesis, and it is not the intention to cover more than the basic principles here, with a suitable example. The philosophy to convert two amino acids into a dipeptide is to transform each difunctional amino acid into a monofunctional compound, one of which has the amino group protected, whilst the other has the carboxyl group protected. This allows... [Pg.540]

It is important to note that the rate constant k for reactions of similar monofunctional compounds is essentially the same as for the difunctional compounds used in the formation of polycondensation polymers. Likewise, as in the case of reactions of small molecules, the rate constant k increases with temperature in accordance with the Arrhenius equation ... [Pg.92]


See other pages where Monofunctional compounds is mentioned: [Pg.283]    [Pg.299]    [Pg.486]    [Pg.65]    [Pg.1226]    [Pg.240]    [Pg.3]    [Pg.13]    [Pg.41]    [Pg.4]    [Pg.316]    [Pg.260]    [Pg.278]    [Pg.67]    [Pg.68]    [Pg.391]    [Pg.156]    [Pg.252]    [Pg.90]    [Pg.98]    [Pg.104]    [Pg.1114]    [Pg.3]    [Pg.53]    [Pg.70]    [Pg.266]   
See also in sourсe #XX -- [ Pg.640 ]




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