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Methyl acrylate reaction with phenyl radicals

Alkylation and Arylation. The 5-methylation of thioamides by diazomethane is catalysed by silica gel. 5-Phenyl derivatives of thiobenzanilides are obtained in high yield by radical arylation with nitrosoacetanilide or phenylazotriphenyl-methane. Thiols are made from alkyl (or cycloalkyl, or aralkyl) halides by their reaction with dimethylthioformamide and treatment of the imidium ester with methanol other methods of hydrolysis lead to side-reactions, giving impure products. Mono- and bi-protic thiocarboxamides condense with ethyl bromo-cyanoacetate and one equivalent of NaOEt with spontaneous separation of sulphur and the formation of ff-amino-cr-cyano-acrylates, as shown in reaction (5). The... [Pg.183]

See other pages where Methyl acrylate reaction with phenyl radicals is mentioned: [Pg.619]    [Pg.746]    [Pg.963]    [Pg.17]    [Pg.2]    [Pg.259]    [Pg.413]    [Pg.67]    [Pg.285]    [Pg.56]    [Pg.355]    [Pg.334]    [Pg.94]   
See also in sourсe #XX -- [ Pg.8 ]



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Acryl radical

Acrylate radicals

Acrylate reaction

Acrylates methyl acrylate

Acrylates reaction with radicals

Methyl acrylate, reaction

Methyl acrylate, reaction with

Methyl phenyl] acrylate

Methyl radical

Methyl radical reactions

Phenyl Reactions

Phenyl radical

Phenyl radical reactions

Radical phenylative

Radicals methyl radical

Reaction with methyl radicals

Reaction with radicals

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