Ceramic-reinforced polymer

Mark, J. E., Ceramic-Reinforced Polymers and Polymer-Modified Ceramics. Polym. Eng. Sci. 1996, 36,2905-2920. 

Mark JE (1996) Ceramic-reinforced polymers and polymer-modified ceramics. Polym Eng... 

Ma X-D, Qian X-F, Yin J, Xi H-A, Zhu Z-K (2002) Preparation and characterization of polyvinyl alcohol-capped CdSe nanoparticles at room temperature. J Coll Interface Sci 252(I) 77-8I Mark JE (1996) Ceramic-reinforced polymers and polymer-modified ceramics. Polym Eng Sci 36 2905-2920... 

Liquid polyalurninum chloride is acidic and corrosive to common metals. Suitable materials for constmction of storage and handling facilities include synthetic mbber-lined steel, corrosion resistant fiber glass reinforced plastics (FRP), ceramics, tetrafluoroethylene polymer (PTFE), poly(vinyhdene fluoride) (PVDF), polyethylene, polypropylene, and poly(vinyl chloride) (PVG). Suitable shipping containers include mbber-lined tank tmcks and rail cars for bulk shipment and plastic-lined or aH-plastic dmms and tote bins for smaller quantities. Except for aluminum chlorohydrates, PAG products are shipped as hazardous substances because of their acidity. 

A rapidly increasing number of publications on polysilanes documents current interest in these polymers (JJ. Polysilanes are potentially applicable in microlithography as high resolution UV-resists (2J, imageable etch barriers ), or contrast enhancement layers (4). They have been successfully used as precursors to Si-C fibers (5J and ceramic reinforcing agents ((L). Polysilanes have also initiated polymerization of vinyl monomers (J ). Doping of polysilanes have increased their conductivity to the level of semiconductors (8). Very recently polysilanes were used as photoconductors (9) and non-linear optical materials (10b... 

Dispersions of finely divided solids in non-aqueous media have been important for paints, inks, reinforced polymers and lubricating oils, but with the development of liquid toner systems and "ultra-structure" processing of ceramics as fine powders dispersed in organic media, the understanding and optimization of such systems is more important than ever. 

Much of what we need to know abont the thermodynamics of composites has been described in the previous sections. For example, if the composite matrix is composed of a metal, ceramic, or polymer, its phase stability behavior will be dictated by the free energy considerations of the preceding sections. Unary, binary, ternary, and even higher-order phase diagrams can be employed as appropriate to describe the phase behavior of both the reinforcement or matrix component of the composite system. At this level of discussion on composites, there is really only one topic that needs some further elaboration a thermodynamic description of the interphase. As we did back in Chapter 1, we will reserve the term interphase for a phase consisting of three-dimensional structure (e.g., with a characteristic thickness) and will use the term interface for a two-dimensional surface. Once this topic has been addressed, we will briefly describe how composite phase diagrams differ from those of the metal, ceramic, and polymer constituents that we have studied so far. 

Given the vast number of possible matrix-reinforcement combinations in composites and the relative inability of current theories to describe the viscosity of even the most compositionally simple suspensions and solutions, it is fruitless to attempt to describe the momentum transport properties of composite precursors in a general manner. There are, however, two topics that can be addressed here in an introductory fashion flow properties of matrix/reinforcement mixtures and flow of matrix precursor materials through the reinforcement. In both cases, we will concentrate on the flow of molten polymeric materials or precursors, since the vast majority of high-performance composites are polymer-based. Fnrthermore, the principles here are general, and they apply to the flnid-based processing of most metal-, ceramic-, and polymer-matrix composites. 

The stress-strain curves for cortical bones at various strain rates are shown in Figure 5.130. The mechanical behavior is as expected from a composite of linear elastic ceramic reinforcement (HA) and a compliant, ductile polymer matrix (collagen). In fact, the tensile modulus values for bone can be modeled to within a factor of two by a rule-of-mixtures calculation on the basis of a 0.5 volume fraction HA-reinforced... 

Commercially available non-oxide ceramic reinforcements are in three categories continuous, discontinuous, and whiskers. The great breakthrough in the ceramic fibre area has been the concept of pyrolysing polymers under controlled conditions, containing the desired species to produce high-temperature ceramic fibres. Silicon carbide fibre is a major development in the field of ceramic reinforcements. 

The manufactured 90 mm x 90 mm x 10 mm three-layered B4C/B4C-30wt%SiC tiles were tested as armor [67], The photographs of the experiment set-up of the ballistic test as well as a residual impression in the clay box that was used as one of the criteria in the ballistic performance of laminates are shown in Fig. 7.17. The ballistic penetration tests were performed to evaluate the ballistic performance of the laminates. Depth of penetration tests were used to evaluate the ballistic performance of the composite laminates. In addition, pure B4C monolithic ceramics were used as a standard for the test. Test panels were made using the three-layered B4C/B4C-SiC laminate and B4C monolithic ceramic material as the hard face. While the B4C monolithic tile had 100% of its theoretical density, the three-layered B4C/B4C-30wt%SiC laminates had about 3-4% of porosity. A commonly used Spectra fiber-reinforced polymer composite was used as backing plates. The targets were mounted on clay and the projectile was shot at the target at a specific velocity. 

Subclass B2 is formed by the so-called structural composites, in which an outspoken mechanical reinforcement is given to the polymer. Subgroup B21 consists of blends of polymers with compatible anti-plasticizers subgroups B22 are the most important the fibre-reinforced polymer systems. The two components, the polymer matrix and the reinforcing fibbers or filaments (glass, ceramic, steel, textile, etc.) perform different functions the fibrous material carries the load, while the matrix distributes the load the fibbers act as crack stoppers, the matrix as impact-energy absorber and reinforcement connector. Interfacial bonding is the crucial problem. 

Janes, Neumann and Sethna ° reviewed the general subject of solid lubricant composites in polymers and metals. They pointed out that the reduction in mechanical properties with higher concentrations of solid lubricant can be offset by the use of fibre reinforcement. Glass fibre is probably the most commonly used reinforcing fibre, with carbon fibre as a second choice. Metal and ceramic fibres have been used experimentally to reinforce polymers, but have not apparently been used commercially. To some extent powders such as bronze, lead, silica, alumina, titanium oxide or calcium carbonate can be used to improve compressive modulus, hardness and wear rate. 

The fibers or the yarn or rovings made therefrom can be processed to fleeces or mats (non-oriented semi-finished product) and textiles, lattices or meshes (oriented semifinished products) and can be utilized as such e.g. for thermal insulation or as filter materials, or in composites with other materials e.g. for fiber-reinforced polymers, metals or ceramics. Fibers are generally marketed after surface treatment (chemical modification, annealing, smoothing) to optimize their application and processing properties. 

Ceramic reinforcing fibers are utilized both in a continuous form (endless fibers) and in a discontinuous form (e.g. whiskers, short fibers). Most of the continuous fibers are utilized in the manufacture of composites with polymer matrices (PMC), where they are in competition with other high performance fibers (boron, carbon fibers), mainly for military or aerospace applications. Discontinuous fibers are generally used for the manufacture of metal matrix (MMC) and ceramic matrix (CMC) composites. 

Whiskers can be easily mixed with powders and processed as such. Composites are formed with metal (utilization in automobile construction e.g. pi.stons of whisker-reinforced aluminum), ceramic or polymer matrices for frictional applications (e.g. brake and clutch linings). Small quantities command prices of 1500 to 2000 DM/kg. For larger quantities prices of 100 to 150 DM/kg are expected. 

Ceramics are also being used in conjunction with resins. Ceramic papers have been developed in Japan, and ceramic fibre reinforced polymers in the USA. 

Another way to improve the mechanical properties of osseoconductive coatings is to add reinforcing ceramic or polymer materials. In the context of this treatise, only ceramic additive such as titania or zirconia will be briefly discussed. Hence, hydroxyapatite/polymer composite coatings will be excluded from discussion. 

Conventional potassium hydroxide electrolytic cells are made from carbon steel. Areas with high corrosion potential are frequently clad with nickel, plastic, or ceramic material. The cathode is constructed of steel coated with a catalyst. The anodes and cathodes of bipolar cells are usually made from nickel or nickel-coated steel. Diaphragms were originally made from asbestos reinforced with nickel nets. Because of the health hazards associated with the use of asbestos, ceramics and polymers are being considered as substitute materials. 

Traditional fibres used as reinforcement in polymer composites are generally either polymers or ceramics the polymer aramids, glass, carbon, boron, aluminium oxide and silicon carbide. Carbon is a high-performance fibre material that is the most commonly used reinforcement in advanced polymer-matrix composites. Glass fibre is readily available and may be fabricated into a glass-reinforced plastic economically using a wide variety of composite-manufacturing techniques. 

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