Cellulose Chlorinated copolymers

Paraloid B72 is an ethyl methacrylate (EMA) copolymer, Tg 40°C, 50% nvc in toluene. It has low reactivity with sensitive phosphorescent and luminescent pigments, and produces stable, durable non-yellowing coatings. It is compatible with vinyls, cellulosics, chlorinated rubbers and silicones, and is used in clear, metallic and solid colour formulations. [Pg.191]

Oil-base (including oil-modified alkyd resin) paint films should not be used in alkaline environments as the paint will deteriorate owing to saponification alkali-resistant coatings are provided by some cellulose ethers, e.g. ethyl cellulose, certain polyurethane, chlorinated rubber, epoxy, p.v.c./ p.v.a. copolymer, or acrylic-resin-based paints. In particular, aluminium and its alloys should be protected by alkali-resistant coatings owing to the detrimental effects of alkali on these metals. [Pg.612]

Zone 2 acetal, ABS, chlorinated polyether, ethyl cellulose, ethylene-vinyl acetate copolymer, furan, ionomer, phe-... [Pg.319]

The principal kinds of thermoplastic resins include (1) acrylonitrile-butadiene-styrene (ABS) resins (2) acetals (3) acrylics (4) cellulosics (5) chlorinated polyelliers (6) fluorocarbons, sucli as polytelra-fluorclliy lene (TFE), polychlorotrifluoroethylene (CTFE), and fluorinated ethylene propylene (FEP) (7) nylons (polyamides) (8) polycarbonates (9) poly elliylenes (including copolymers) (10) polypropylene (including copolymers) ( ll) polystyrenes and (12) vinyls (polyvinyl chloride). The principal kinds of thermosetting resins include (1) alkyds (2) allylics (3) die aminos (melamine and urea) (4) epoxies (5) phenolics (6) polyesters (7) silicones and (8) urethanes,... [Pg.1316]

ABA ABS ABS-PC ABS-PVC ACM ACS AES AMMA AN APET APP ASA BR BS CA CAB CAP CN CP CPE CPET CPP CPVC CR CTA DAM DAP DMT ECTFE EEA EMA EMAA EMAC EMPP EnBA EP EPM ESI EVA(C) EVOH FEP HDI HDPE HIPS HMDI IPI LDPE LLDPE MBS Acrylonitrile-butadiene-acrylate Acrylonitrile-butadiene-styrene copolymer Acrylonitrile-butadiene-styrene-polycarbonate alloy Acrylonitrile-butadiene-styrene-poly(vinyl chloride) alloy Acrylic acid ester rubber Acrylonitrile-chlorinated pe-styrene Acrylonitrile-ethylene-propylene-styrene Acrylonitrile-methyl methacrylate Acrylonitrile Amorphous polyethylene terephthalate Atactic polypropylene Acrylic-styrene-acrylonitrile Butadiene rubber Butadiene styrene rubber Cellulose acetate Cellulose acetate-butyrate Cellulose acetate-propionate Cellulose nitrate Cellulose propionate Chlorinated polyethylene Crystalline polyethylene terephthalate Cast polypropylene Chlorinated polyvinyl chloride Chloroprene rubber Cellulose triacetate Diallyl maleate Diallyl phthalate Terephthalic acid, dimethyl ester Ethylene-chlorotrifluoroethylene copolymer Ethylene-ethyl acrylate Ethylene-methyl acrylate Ethylene methacrylic acid Ethylene-methyl acrylate copolymer Elastomer modified polypropylene Ethylene normal butyl acrylate Epoxy resin, also ethylene-propylene Ethylene-propylene rubber Ethylene-styrene copolymers Polyethylene-vinyl acetate Polyethylene-vinyl alcohol copolymers Fluorinated ethylene-propylene copolymers Hexamethylene diisocyanate High-density polyethylene High-impact polystyrene Diisocyanato dicyclohexylmethane Isophorone diisocyanate Low-density polyethylene Linear low-density polyethylene Methacrylate-butadiene-styrene... [Pg.958]

MC MDI MEKP MF MMA MPEG MPF NBR NDI NR OPET OPP OSA PA PAEK PAI PAN PB PBAN PBI PBN PBS PBT PC PCD PCT PCTFE PE PEC PEG PEI PEK PEN PES PET PF PFA PI PIBI PMDI PMMA PMP PO PP PPA PPC PPO PPS PPSU Methyl cellulose Methylene diphenylene diisocyanate Methyl ethyl ketone peroxide Melamine formaldehyde Methyl methacrylate Polyethylene glycol monomethyl ether Melamine-phenol-formaldehyde Nitrile butyl rubber Naphthalene diisocyanate Natural rubber Oriented polyethylene terephthalate Oriented polypropylene Olefin-modified styrene-acrylonitrile Polyamide Poly(aryl ether-ketone) Poly(amide-imide) Polyacrylonitrile Polybutylene Poly(butadiene-acrylonitrile) Polybenzimidazole Polybutylene naphthalate Poly(butadiene-styrene) Poly(butylene terephthalate) Polycarbonate Polycarbodiimide Poly(cyclohexylene-dimethylene terephthalate) Polychlorotrifluoroethylene Polyethylene Chlorinated polyethylene Poly(ethylene glycol) Poly(ether-imide) Poly(ether-ketone) Polyethylene naphthalate Polyether sulfone Polyethylene terephthalate Phenol-formaldehyde copolymer Perfluoroalkoxy resin Polyimide Poly(isobutylene), Butyl rubber Polymeric methylene diphenylene diisocyanate Poly(methyl methacrylate) Poly(methylpentene) Polyolefins Polypropylene Polyphthalamide Chlorinated polypropylene Poly(phenylene oxide) Poly(phenylene sulfide) Poly(phenylene sulfone)... [Pg.959]

There continues to be extensive interest in latexes and micellar systems. The structure of acrylic latex particles has been investigated by non-radiative energy transfer by labelling the co-monomers with fluorescent acceptor-donor systems. Phase separations could also be measured in this way. Excimer fluorescence has been used to measure the critical micelle temperature in diblock copolymers of polystyrene with ethylene-propylene and the results agree well with dynamic light scattering measurements. Fluorescence anisotropy has been used to measure adsorption isotherms of labelled polymers to silica as well as segmental relaxation processes in solutions of acrylic polymers. In the latter case unusual interactions were indicated between the polymers and chlorinated hydrocarbon solvents. Fluorescence analysis of hydrophobically modifled cellulose have shown the operation of slow dynamic processes while fluorescence... [Pg.367]

Estaflex ATC. [Akzo] Acetyl tributyl citrate primary plasticizer for plastics incl. PP, PS, PVAc, PVB, PVC, vinyl acetate copolymers, chlorinated rubber, ethyl cellulose, nitrocellulose suitable fcM coatings in contact with foodstuffs. [Pg.135]

Solvents used for paint removal are able to dissolve or considerably swell physically drying binders (e.g., vinyl chloride copolymers, cellulose nitrate, polyacrylates) and chemically cross-linked coatings (e.g., oil-based paints, dried alkyd resins, cross-linked polyester-melamine resins, cross-linked epoxy and isocyanate coatings) [14.237]. A combination of dichloromethane with low-boiling ketones or esters is particularly suitable. Small amounts of high-boiling solvents with a low volatility (e.g., tetrahydronaphthalene, solvent naphtha, methyl benzyl alcohol, or benzyl alcohol) are added to these mixtures to retard evaporation and increase the solvency. Modern paint removers do not contain chlorinated hydrocarbons, they are formulated on the basis of high boilers (e.g., dimethylformamide, dimethyl sulfoxide, propylene carbonate, and yV-methylpyrrolidone) in combination with alcohols and aromatics, or consist of aqueous, frequently alkaline or acidic systems. [Pg.322]

Toluene [108-88-3] is mainly used in cellulose nitrate lacquers in heat-curing paints based on urea-, melamine-, or phenol - formaldehyde resins in alkyd resin paints and in paints based on chlorinated rubber, polystyrene, polyacrylates, or poly(vinyl acetate). Mixtures of toluene with esters are used to dissolve vinyl chloride copolymers and postchlorinated poly(vinyl chloride) [14.265]. [Pg.351]

Dichloromethane [75-09-2] (methylene chloride) is a colorless, highly volatile, neutral liquid with a characteristic odor. It is insoluble in water but miscible with organic solvents. It has a very good solvency for many organic substances, such as fats, oils, waxes, and resins. Bitumen, rubber, chlorinated rubber, polystyrene, postchlorinated poly(vinyl chloride), vinyl chloride copolymers, polyacrylates, and cellulose esters are also soluble. The solubility spectrum can be expanded by adding other solvents. A mixture of methanol or ethanol and dichloromethane is a good solvent for cellulose ethers and acetyl cellulose. Cellulose nitrate is, however, insoluble. [Pg.352]

Butanol [ 71-36-3] (1 -butanol) is a colorless neutral liquid that has a limited miscibility with water and a characteristic odor. It is miscible with organic solvents. Butanol has a high solvency for most known natural and synthetic resins, fats, oils, linseed oil, saturated polyesters, and poly(vinyl acetate). It considerably increases the dilutability of cellulose nitrate solutions with non-solvents. Cellulose esters, cellulose ethers, chlorinated rubber, poly(vinyl chloride), vinyl chloride copolymers, and polystyrene are not dissolved by butanol. [Pg.355]

Diacetone alcohol [123-42-2] (4-hydroxy-4-methyl-2-pentanone) is an almost odorless ketone alcohol that is weakly acidic as a result of rearrangement to the enol form. It is miscible with water and organic solvents except aliphatic hydrocarbons. It acts as a good solvent for cellulose esters and ethers, alcohol-soluble resins, castor oil, and plasticizers. Poly(vinyl acetate) and chlorinated rubber are partially dissolved or swollen. Polystyrene, poly(vinyl chloride), vinyl chloride copolymers, dam-ar resins, resin esters, rubber, bitumen, mineral oils, ketone resins, and maleate resins are insoluble. Diacetone alcohol is used as a high boiler in stoving enamels to improve flow and gloss. [Pg.358]

Cyclohexanone [108-94-1] (Hexanone) is insoluble in water, miscible with organic solvents. It is a high boiler with very good solvency for cellulose nitrate, cellulose ethers and esters, colophony, shellac, alkyd resins, natural and synthetic resins, chlorinated rubber, rubber, vinyl polymers and copolymers, polystyrene, ketone and ketone-formaldehyde resins, fats, oils, waxes, blown oils, and bitumen. [14.268],... [Pg.361]

Trimethylcyclohe.xanone [873-94-9] (TMC-one, 3,3,5-trimethylcyclohexanone) is a saturated cyclic ketone. It is a colorless high boiler with an aromatic odor reminiscent of menthol. Trimethylcyclohexanone is only moderately miscible with water, but is miscible in all proportions with all organic solvents. It is chemically closely related to isophorone. Trimethylcyclohexanone dissolves cellulose nitrate, low molecular mass PVC grades, poly(vinyl acetate), vinyl chloride-vinylacetate copolymers, chlorinated rubber, alkyd resins, unsaturated polyester resins, epoxy resins, acrylic resins, etc. [Pg.361]

Isophorone [14.268], [14.269] is an unsaturated cyclic ketone. It consists of a-isophorone [78-59-1] (3,5,5-trimethyl-2-cyclohexen-l-one), which contains about 1-3% of the isomer P-isophorone [471-01-2] (3,5,5-trimethyl-3-cyclohexen-l-one). Isophorone is a stable, water-white liquid with a mild odor that is miscible in all proportions with organic solvents. It dissolves many natural and synthetic resins and polymers, such as poly(vinyl chloride) and vinyl chloride copolymers, poly(vinyI acetate), polyacrylates, polymethacrylates, polystyrene, chlorinated rubber, alkyd resins, saturated and unsaturated polyesters, epoxy resins, cellulose nitrate, cellulose ethers and esters, damar resin (dewaxed), kauri, waxes, fats, oils, phenol-, melamine-, and urea-formaldehyde resins, as well as plant protection agents. However, isophorone does not dissolve polyethylene, polypropylene, polyamides. [Pg.361]

Ethyl acetate [79-20-9] is a colorless, neutral liquid that is partially miscible with water and has a pleasant, fruity odor. It has a good solvency for cellulose nitrate, cellulose ethers, chlorinated rubber, poly(vinyl acetate), vinyl chloride copolymers, polyacrylates, polystyrene, fats, oils, and many natural and synthetic resins (alkyd resins, saturated polyesters, ketone resins). Cellulose acetate is, however, dissolved only in the presence of small amounts of ethanol. Poly(vinyl chloride) is insoluble. [Pg.363]

Isobutyl acetate [110-19-0] is a colorless, neutral liquid with a pleasant, fruity odor. It is miscible with organic solvents, but immiscible with water. Isobutyl acetate has a high solvency for cellulose nitrate, colophony, damar resin, ketone and ketone-formaldehyde resins, maleate resins, urea and melamine resins, and phenolic and alkyd resins. Polymers such as polystyrene, poly(vinyl ethers), poly(vinyl acetate), polyacrylates, chlorinated rubber and vinyl chloride copolymers, as well as fats, greases, and oils are readily dissolved. Postchlorinated poly(vinyl chloride) is less soluble. Polyisobutene, cellulose ethers, polymethacrylates, poly(vinyl butyrals), natural rubber, and manila copal are swollen. Shellac, cellulose acetate, cellulose acetobutyrate, poly(vinyl chloride), and poly(vinyl formal) are insoluble. [Pg.363]

Ethyl triglycol [112-50-5] [2-(2-ethoxyethoxy)ethoxy]ethanol, triethylene glycol monoethyl ether] is an almost colorless, neutral, mild-smelling liquid with a low hygroscopicity. It is soluble in water and most organic solvents, but is only partially miscible with aromatic and aliphatic hydrocarbons. Ethyl triglycol dissolves cellulose nitrate, shellac, colophony, ketone resins, maleate resins, chlorinated rubber, alkyd resins, and many other paint resins. It does not dissolve cellulose acetate, poly(vinyl chloride), vinyl chloride copolymers, fats, oils, and rubber. [Pg.369]

Dimethylacetal [534-15-6] (acetaldehyde dimethyl acetal, 1,1-dimethoxyethane) is a neutral liquid that is miscible with water and organic solvents. It dissolves cellulose nitrate, cellulose ethers, poly(vinyl acetate), polyacrylates, polymethacrylates, poly(vinyl ethers), some vinyl chloride copolymers, and synthetic and natural resins. It does not dissolve poly(vinyl chloride), polystyrene, chlorinated rubber, and cellulose acetate. It is used in the production of paints, adhesives, and shoe-cap stiffeners. [Pg.372]

N.N-Dimethylformamide [68-12-2] (DMF) [14.276] is miscible with water and organic solvents except aliphatic hydrocarbons. It is a good high-boiling solvent for cellulose esters, cellulose ethers, poly(vinyl chloride), vinyl chloride copolymers, poly(vinyl acetate), polyacrylonitrile, polystyrene, chlorinated rubber, polyacrylates, ketone resins, and phenolic resins. Alkyd resins and resin esters are partially soluble. Dimethylformamide does not dissolve polyethylene, polypropylene, urea-formaldehyde resins, rubber, and polyamides. It is used as a solvent in printing inks, for polyacrylonitrile spinning solutions [14.277], and as a solvent in the synthesis of acetylene. [Pg.372]

Methyl methacrylate/butyl methacrylate copolymer binder, printing inks Calcium resinate C5 hydrocarbon resin, aliphatic Ethylcellulose Ethyl hydroxyethyl cellulose Methyl methacrylate/butyl methacrylate copolymer PEG-4 Polyacrylamide Rosin, polymerized Rubber, chlorinated Styrene/MA copolymer Terpene resin Urea-formaldehyde resin, butylated Urethane-acrylate resin Zinc rosinate... [Pg.4902]

Acrylamides copolymer film-former, printing inks Rubber, chlorinated film-former, protective coatings Ethyl hydroxyethyl cellulose film-former, protective skin care Diisostearyl trimethylolpropane siloxy silicate film-former, protective skin creams/lotions Myristoyl hydrolyzed collagen film-former, protective cosmetics Hydrolyzed almond protein film-former, protective skin care C20-40 alcohols film-former, pump hair sprays Acrylates/octylacrylamide copolymer film-former, PVA emulsions 3-Methoxybutanol... [Pg.5253]

Tetrabromobisphenol A di-2-hydroxyethyl ether Tetradecabromodiphenoxybenzene Tetrakis (2-chloroethyl) ethylene diphosphate Tris (2,3-dichloropropyl) phosphate flame retardant, EPS Tribromophenyl allyl ether flame retardant, ethyl cellulose Diphenyl octyl phosphate flame retardant, ethylene copolymers Ethylenebis (tetrabromophthalimide) flame retardant, expandable PS Dibromoethyidibromocyclohexane Tetrabromobisphenol A bis (allyl ether) Tetrabromocyclooctane flame retardant, extruded PS Tetrabromocyclooctane flame retardant, fabrics Antimony pentoxide Methylphosphonic acid, (5-ethyl-2-methyl-2-oxido-1,3,2-dioxaphosphorinan-5-yl) methyl methyl ester flame retardant, fibers Antimony pentoxide Tetrabromoethane flame retardant, filament winding Epoxy resin, brominated flame retardant, film Tetrabromobis (2-ethylhexyl) phthalate flame retardant, fire-retardant material Chlorinated paraffins (C12, 60% chlorine) Chlorinated paraffins (C23, 43% chlorine) flame retardant, flexible PU foam bedding Tetrakis (2-chloroethyl) ethylene diphosphate flame retardant, flexible PU foam furniture Tetrakis (2-chloroethyl) ethylene diphosphate flame retardant, flexible PU foam transportation Tetrakis (2-chloroethyl) ethylene diphosphate flame retardant, flexible PU foams furniture, automobile seating... [Pg.5263]

Cellulose acetate butyrate lonomer resin Polyethylene, chlorosulfonated Polyethylene elastomer, chlorinated Polyvinyl chloride Styrene-ethylene/butylene-styrene block copolymer Tetrafluoroethylene/propylene copolymer tubing, chemicals Polymethyl methacrylate tubing, flexible... [Pg.5832]

Cellulose propionate, or chlorinated polyethylene, also CPE Alternating copolymer from vinyl ether and maleic acid Copolymer from acrylic acid and maleic acid Chlorinated polyethylene... [Pg.2157]

It is often desirable to perform some kind of chemical modification to polymers once they have formed. Acetylation of cellulose, for example, represents the chemical modification of a naturally occurring polymer (see chapter 3) to give the technologically useful cellulose diacetate and triacetate polymers. Poly(vinyl alcohol) (PVA) is a well-known example of a polymer that can only be formed by chemical modification since vinyl alcohol monomer does not exist (except as its keto form, acetaldehyde). Instead, PVA is formed by hydrolysis of poly(vinyl acetate) (PVAc). Partly hydrolysed PVAc is, of course, simply a copolymer of VA and VAc. As another example, ethylene/vinyl chloride copolymers can be prepared by reductive elimination of chlorine from poly (vinyl chloride) (PVC). The driving force here is that, although ethylene and vinyl chloride can be copolymerised directly, the normal routes to these polymers give insufficient control over composition and sequence distribution. [Pg.75]

Acrylate styrene acrylonitrile Acrylate modified styrene acrylonitrile Acrylic acid ester rubber Acrylonitrile butadiene rubber or nitrile butadiene rubber Acrylonitrile butadiene styrene Acrylonitrile styrene/chlorinated polyethylene Acrylonitrile methyl methacrylate Acrylonitrile styrene/EPR rubber or, acrylonitrile ethylene propylene styrene Alpha methyl styrene Atactic polypropylene Butadiene rubber or, cis-1,4-polybutadiene rubber or, polybutadiene rubber Butadiene styrene block copolymer Butyl rubber Bulk molding compound Casein formaldehyde Cellulose acetate Cellulose acetate butyrate Cellulose acetate propionate Cellulose nitrate Chlorinated polyethylene Chlorinated polyvinyl chloride Chloro-polyethylene or, chlorinated polyethylene. [Pg.135]