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Methyl alcohol isobutyl ketone

A yield of about 95% of theoretical is achieved using this process (1.09 units of isopropyl alcohol per unit of acetone produced). Depending on the process technology and catalyst system, such coproducts as methyl isobutyl ketone and diisobutyl ketone can be produced with acetone (30). [Pg.96]

Reduction. Most ketones are readily reduced to the corresponding secondary alcohol by a variety of hydrogenation processes. The most commonly used catalysts are palladium, platinum, and nickel For example, 4-methyl-2-pentanol (methyl isobutyl carbinol) is commercially produced by the catalytic reduction of 4-methyl-2-pentanone (methyl isobutyl ketone) over nickel. [Pg.487]

DIBK can be produced by the hydrogenation of phorone which, in turn, is produced by the acid-catalyzed aldol condensation of acetone. It is also a by-product in the manufacture of methyl isobutyl ketone. Diisobutyl ketone ( 1.37/kg, October 1994) is produced in the United States by Union Carbide (Institute, West Virginia) and Eastman (Kingsport, Teimessee) (47), and is mainly used as a coating solvent. Catalytic hydrogenation of diisobutyl ketone produces the alcohol 2,6-dimethyl-4-heptanol [108-82-7]. [Pg.493]

Chemical. The use of isopropyl alcohol as a feedstock for the production of acetone is expected to remain stable, as the dominant process for acetone is cumene oxidation. Isopropyl alcohol is also consumed in the production of other chemicals such as methyl isobutyl ketone, methyl isobutyl carbinol [108-11-2] isopropjlamine, and isopropyl acetate. The use of diisopropyl ether as a fuel ether may become a significant oudet for isopropyl alcohol. [Pg.113]

Acetaldehyde, acetone, tetrahydrofuran (THF), ethyl acetate, isopropyl alcohol, ethyl alcohol, 4-methyl-l,3-dioxolane, n-pro-pyl acetate, methyl isobutyl ketone, -propyl alcohol, toluene, n-butyl alcohol, 2-ethoxyethanol, and cyclohexane... [Pg.230]

Similarly to quantitative determination of high surfactant concentrations, many alternative methods have been proposed for the quantitative determination of low surfactant concentrations. Tsuji et al. [270] developed a potentio-metric method for the microdetermination of anionic surfactants that was applied to the analysis of 5-100 ppm of sodium dodecyl sulfate and 1-10 ppm of sodium dodecyl ether (2.9 EO) sulfate. This method is based on the inhibitory effect of anionic surfactants on the enzyme system cholinesterase-butyryl-thiocholine iodide. A constant current is applied across two platinum plate electrodes immersed in a solution containing butyrylthiocholine and surfactant. Since cholinesterase produces enzymatic hydrolysis of the substrate, the decrease in the initial velocity of the hydrolysis caused by the surfactant corresponds to its concentration. Amounts up to 60 pg of alcohol sulfate can be spectrometrically determined with acridine orange by extraction of the ion pair with a mixture 3 1 (v/v) of benzene/methyl isobutyl ketone [271]. [Pg.282]

Detectability may be a significant problem with homologous series of unsaturated compounds, particularly //-alkanes. For these compounds, refractive index detection or evaporative light-scattering, both of which are described elsewhere in the book, may be of use. Indirect photometry is a useful detection scheme for compounds that do not absorb in the UV. Acetone, methylethyl ketone, methyl propyl ketone, methyl isopropyl ketone, methyl isobutyl ketone, and acetophenone are added to an acetonitrile/water mobile phase, generating a negative vacancy peak when the nonchro-mophoric analyte emerges and a positive peak if the ketone is adsorbed and displaced.70 Dodecyl, tetradecyl, cetyl, and stearyl alcohols also have been derivatized with 2-(4-carboxyphenyl)-5,6-dimethylbenzimidazole and the derivatives separated on Zorbax ODS in a mobile phase of methanol and 2-propanol.71... [Pg.161]

The solid base catalysed aldol condensation of acetone was performed over a CsOH/Si02 catalyst using a H2 carrier gas. The products observed were diacetone alcohol, mesityl oxide, phorone, iso-phorone and the hydrogenated product, methyl isobutyl ketone. Deuterium tracer experiments were performed to gain an insight into the reaction mechanism. A mechanism is proposed. [Pg.363]

The aldol condensation of acetone to diacetone alcohol is the first step in a three-step process in the traditional method for the production of methyl isobutyl ketone (MIBK). This reaction is catalysed by aqueous NaOH in the liquid phase. (3) The second step involves the acid catalysed dehydration of diacetone alcohol (DAA) to mesityl oxide (MO) by H2S04 at 373 K. Finally the MO is hydrogenated to MIBK using Cu or Ni catalysts at 288 - 473 K and 3- 10 bar (3). [Pg.363]

Methyl amyl alcohol, see Methyl isobutyl carbinol Methyl n-amyl ketone (2-heptanone) 8.6... [Pg.240]

Methyl isobutyl ketone was reduced with (- )-menthol-LAH in ether to give the (+ )-(S)-carbinol (53) in low optical yield. Methyl neopentyl ketone was similarly reduced to the (-I- )-carbinol, although pinacolone was reduced to only racemic alcohol. Maximum stereoselectivity in the reduction of both ketones and alkenynols was obtained with a 2 1 (-)-menthol-LAH reagent. The observed low stereoselectivity was attributed mainly to insufficient interaction of the remote isopropyl substituent on the menthyl group with the substituents on... [Pg.243]

METHYL ISOBUTYL KETONE n-PENTYL FORMATE n-BUTYL ACETATE sec-BUTYL ACETATE tert-BUTYL ACETATE ETHYL n-BUTYRATE ETHYL ISOBUTYRATE ISOBUTYL ACETATE n-PROPYL PROPIONATE CYCLOHEXYL PEROXIDE DIACETONE ALCOHOL 2-ETHYL BUTYRIC ACID n-HEXANOIC ACID 2-ETHOXYETHYL ACETATE HYDROXYCAPROIC ACID PARALDEHYDE... [Pg.13]

Indenopyrene, see Indeno[l,2,3-crf pyrene l//-Indole, see Indole Indolene, see Indoline Inexit, see Lindane Inhibisol, see 1,1,1-Trichloroethane Insecticide 497, see Dieldrin Insecticide 4049, see Malathion Insectophene, see a-Endosulfan, p-Endosulfan Intox 8, see Chlordane Inverton 245, see 2,4,5-T lodomethane, see Methyl iodide IP, see Indeno[l,2,3-crf pyrene IP3, see Isoamyl alcohol Ipaner, see 2,4-D IPE, see Isopropyl ether IPH, see Phenol Ipersan, see Trifluralin Iphanon, see Camphor Isceon 11, see Trichlorofluoromethane Isceon 122, see Dichlorodifluoromethane Iscobrome, see Methyl bromide Iscobrome D, see Ethylene dibromide Isoacetophorone, see Isophorone a-Isoamylene, see 3-Methyl-l-butene Isoamyl ethanoate, see Isoamyl acetate Isoamylhydride, see 2-Methylbutane Isoamylol, see Isoamyl alcohol Isobac, see 2,4-Dichlorophenol Isobenzofuran-l,3-dione, see Phthalic anhydride 1,3-Isobenzofurandione, see Phthalic anhydride IsoBuAc, see Isobutyl acetate IsoBuBz, see Isobutylbenzene Isobutane, see 2-Methylpropane Isobutanol, see Isobutyl alcohol Isobutene, see 2-Methylpropene Isobutenyl methyl ketone, see Mesityl oxide Isobutyl carbinol, see Isoamyl alcohol Isobutylene, see 2-Methylpropene Isobutylethylene, see 4-Methyl-l-pentene Isobutyl ketone, see Diisobutyl ketone Isobutyl methyl ketone, see 4-Methyl-2-pentanone Isobutyltrimethylmethane, see 2,2,4-Trimethylpentane Isocumene, see Propylbenzene Isocyanatomethane, see Methyl isocyanate Isocyanic acid, methyl ester, see Methyl isocyanate Isocyanic acid, methylphenylene ester, see 2,4-Toluene-diisocyanate... [Pg.1492]

One of the most thoroughly investigated aldol condensations is the selfcondensation of acetone. This is an important industrial reaction for the production of diacetone alcohol (DA) (Scheme 11), which is valuable as a chloride-free solvent and an intermediate in the synthesis of industrially important products such as mesityl oxide (MO), isophorone, methyl isobutyl ketone, and 3,5-xylenol. The reaction is exothermic, with the yield of DA decreasing with increasing reaction temperature it is usually performed with NaOH or KOH as a basic catalyst 118). [Pg.256]

Colorless gas pungent suffocating odor gas density 2.927 g/L at 20°C heavier than air, vapor density 2.263 (air=l) condenses to a colorless liquid at -10°C density of liquid SO2 1.434 g/mL freezes at -72.7°C critical temperature 157.65°C critical pressure 77.78 atm critical volume 122 cc/g dielectric constant 17.27 at -16.5°C dissolves in water forming sulfurous acid, solubility 22.97 g and 11.58 g/lOOmL water at 0° and 20°C, respectively, under atmospheric pressure very soluble in acetone, methyl isobutyl ketone, acetic acid, and alcohol soluble in sulfuric acid liquid SO2 slightly miscible in water. [Pg.895]

Methyl Isobutyl Carbinol Methyl Amyl Alcohol Methyl Isobutyl Ketone Methyl Amyl Alcohol Iso-Butyraldehyde Isobutyric Acid Iso-Butyraldehyde Isobutyronitrile... [Pg.57]

Methyl alcohol (6) Methylene chloride (5) Methyl ethyl ketone (8) Methyl ethyl ketone (8) Methyl isobutyl ketone (8) Vinyl acetate (inhibited) (14) Caustic soda solution (3) Caustic soda solution (3) Furfural (7) Caustic soda solution (3)... [Pg.278]

The largest offtake of acetone is its conversion into solvents, used mainly in lacquers and other synthetic resin applications. These solvents include diacetone alcohol, methyl isobutyl ketone, methyl isobutyl carbinol (methyl amyl alcohol), and methyl amyl acetate. The following equations (22), in each of which the raw material is the product of the previous reaction, show a possible procedure by which these solvents may be made ... [Pg.294]

An interesting case of interproduct competition is that of the four original lacquer solvents—ethyl alcohol, butyl alcohol, ethyl acetate, and butyl acetate. These were once produced mainly by fermentation processes, but today all are also produced by synthesis from petroleum hydrocarbons. Moreover, in the past 30 years solvents have been developed from petroleum sources which are competing successfully with these materials even though the new compounds are not identical in all properties isopropyl alcohol competes with ethyl alcohol methyl isobutyl carbinol and n-propyl alcohol can replace butyl alcohol methyl ethyl ketone to a large extent supplants ethyl acetate and methyl isobutyl ketone can be substituted for butyl acetate. Thus, petroleum aliphatic chemicals have served both by displacement of source and replacement of end product to supplement and to compete with the fermentation solvents. [Pg.299]

Chemicals and Standard Solutions. Cyclohexanone, cyclohexanol, 1,3,5-trichlorobenzene, 1,2,4-trichlorobenzene, phenol, 4-methylphenol, 4-chloro-phenol, 1,2,3,4-tetrahydroisoquinoline, 1-chlorohexane, 1-chlorododecane, and 1-chlorooctadecane were obtained from Aldrich. Acetone, tetrahydrofuran, ethyl acetate, toluene, dimethyl sulfoxide, and methanol were obtained from J. T. Baker. Distilled-in-glass isooctane, methylene chloride, ethyl ether, and pentane were obtained from Burdick and Jackson. Analytical standard kits from Analabs provided methyl ethyl ketone, isopropyl alcohol, ethanol, methyl isobutyl ketone, tetrachloroethylene, dodecane, dimethylformamide, 1,2-dichlorobenzene, 1-octanol, nitrobenzene, 2,4-dichlorophenol, and 2,5-dichlorophenol. All chemicals obtained from the vendors were of the highest purity available and were used without further purification. High-purity water... [Pg.356]

About 69% of the total 1988 U.S. consumption of isobutyraldehyde, went into the production of isobutyl alcohol and isobutyraldehyde condensation and esterification products. The other principal isobutyraldehyde derivative markets (as a percentage of total 1988 U.S. isobutyraldehyde consumption) are neopentyl glycol (15%) isobutyl acetate (6%) isobutyric acid (5%) is obutylidene diurea (2.5%) and methyl iso amyl ketone (1.7%). [Pg.380]

Riggio, R., et al., Viscosities, Densities, and Refractive Indexes of Mixtures of Methyl Isobutyl Ketone-Isobutyl Alcohol. J. Chem. Eng. Data, 1984 29, 11-13. [Pg.75]

RWE-DEA (former Deutsche Texaco AG) is one of the leading companies in the development and conmercial application of processes using ion excnange resins as acidic catalysts. Our expertise comprises production of bulk chemicals, sucn as MTBE (refs. 2-3), isopropyl alcohol (refs. 2, 4-5) and sec-butyl alcohol (refs. 2, 6-7) as well as manufacture of low-volume chemicals sold at higner prices, sucn as methyl isobutyl ketone, methyl isopropenyl Ketone and methyl isopropyl ketone (refs. 8, 9-10) ... [Pg.487]

Major markets as solvents and intermediates have made the ketones important commercial products lor many years. Acetone and mcthylethyl ketone have had the most impact on the chemical industry Acetone Is used s an intermediate In methyl isobutyl ketone, methyl methacrylate, diucelonc alcohol. ketone. hisphenol-A. phiwnc. and mesityl oxide Acetone is largely produced by dehydration of isopropyl alcohol In the production of phenol from cumene, acetone is produced as a by-product This mute to acetone has tended to control its price. [Pg.35]


See other pages where Methyl alcohol isobutyl ketone is mentioned: [Pg.329]    [Pg.92]    [Pg.94]    [Pg.99]    [Pg.104]    [Pg.263]    [Pg.7]    [Pg.512]    [Pg.368]    [Pg.279]    [Pg.101]    [Pg.247]    [Pg.179]    [Pg.67]    [Pg.210]    [Pg.67]    [Pg.365]    [Pg.400]    [Pg.402]    [Pg.11]    [Pg.395]    [Pg.147]    [Pg.356]    [Pg.611]   
See also in sourсe #XX -- [ Pg.47 , Pg.114 ]




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Alcohol Methylic

Alcohols isobutyl alcohol

Alcohols methylation

Isobutyl

Isobutyl ketone

Ketones alcohols

Methyl alcohol—

Methyl isobutyl ketone

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