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Experimental work

So far the results of 12 experimental measurements of the polarization correlation in the two-photon decay of atoms have been published. All but two of these have been carried out in order to test the BCHSH inequality in one form or another. [Pg.489]

In its simplest form the exciting system will consist of a source, illumination optics, filter and polariser, and the intensity-measuring system will consist of an analyser, collection optics, filter and detector. The source of ultraviolet light is usually a mercury or xenon arc and the filter on the source side of the specimen selects from its output a narrow band of wavelengths near the peak of the absorption spectrum of the particular fluorescent molecule in use. The illumination optics should transmit the light as a fairly parallel beam to the specimen, so that it can be given a [Pg.198]

At its simplest, the collection optics will contain no lenses but will simply define an approximately parallel beam by means of apertures. If small areas of the sample are to be investigated a microscope system may be used, but in that case consideration must be given to the effect of the large collection angle on the polarisation of the detected light. The detection system will usually be a photomultiplier and amplifier whose output is observed either on an electrometer or a chart recorder, although an oscilloscope has been used for dynamic recording.  [Pg.199]

It must be noted when considering the geometrical form of the specimen and the directions of the incident and fluorescent light beams that it is the direction of polarisation inside the specimen which is important. The use of certain geometries may necessitate corrections for refraction effects. It is also important for any type of system to correct for any sensitivity of the illuminating or detection systems to the polarisation vectors. [Pg.199]

The choice of fluorescent probe depends on a variety of factors. It has already been pointed out that what is determined directly is information which characterises the distribution of orientations of the fluorescent molecules. The ideal experiment would be one in which the polymer molecules themselves contained fluorescent groups. Stein has considered the theory of the fluorescence method specifically for a uniaxially oriented fluorescent rubber but no experiments to study orientation have been reported for such a system. Nishijima et al have, however, made some qualitative observations on the polarisation of the fluorescent light from polyvinylchloride films which had been first stretched and then irradiated with light of wavelength 185 nm to produce fluorescent polyene segments. [Pg.199]

It has usually been asserted that the fluorescent molecules are located only in the non-crystalline regions of crystalline polymers, although no clear evidence for this statement is given. If this is so, it seems reasonable to expect that, where no strong specific alignment forces exist between the polymer molecules and the fluorescent molecules, long thin fluorescent molecules will tend to align themselves parallel to the polymer chains. If, in addition, the absorption and emission axes of the fluorescent molecule [Pg.199]

For calculation of chain propagation rate constant initial parts of kinetic curves were used, when temperature of reaction mixture did not markedly differ from initial. So, received values of piperylene oligomerization rates constants in first approximation may be referred to temperature interval 298-310 K. Relative method s error was 15-20%. [Pg.35]

At equal conditions of polymerization [Ti A1 piperylene = 1 1,25 2 mole (piperylene was introduced as modifier into catalytic complex solution at the moment of its preliminary ageing), ageing of catalytic system for 30 min at 273K, polymerization temperature 298K, toluene as a solvent, Cti = 6 mmoleA, Cm = 1.5 mole/1] way of process carrying out was changed. Namely  [Pg.35]

Variant 2. Solutions of TiCU and Al(i-C4Hs)3 from reservoirs 1 and 2 accordingly through apparatus 3 entered into vessel 4 where resulting catalytic complex was aged for 30 min at 273K (catalytic system preparation in turbulent regime). [Pg.35]

Variant 3. Solutions of preliminary aged ternary catalytic complex and monomer from reservoirs 1 and 2 accordingly were mixed in apparatus 3 with following introduction of reaction mixture into apparatus 4 (reaction mixture formation in turbulent regime). Traditional conditions for isoprene polymerization were created in tank apparatus (vessel) 4 at low mixing by magnetic stirrer (100 rpm) and tubular turbulent apparatus in this case functioned as prereactor (Fig. 2.1). [Pg.35]

For each of noted variants blank experiment modelling traditional process scheme was simultaneously carried out (initial reagents without preliminary mixing in prereactor 3 were introduced directly into reaction volume 4). Conversion curves of isoprene polymerization were received by gravimetric method. [Pg.35]

Chemicals were used as received. Acyclovir [CA (chem. Abstracts) 59277-89-3], and dimethyltin dichloride (CA 753-73-1) were purchased from die Aldrich Chemical Company, Milwaukee, WS. Diethyltin dichloride (CA 866-55-7) and [Pg.82]


At this stage, how great the excess of chlorine should be for Fig. 4.7c to be feasible cannot be specified. Experimental work on the reaction chemistry would be required in order to establish this. However, the size of the excess does not change the basic structure. [Pg.104]

The authors are grateful to Dr. Placid Rodriguez, Director IGCAR for his keen encouragement and support. Authors are also thankful to S/Shri S.Saravanan, V.Manoharan, P.Balaraman and Shri P.Sukumar for all their help in experimental work. [Pg.446]

Evaluation and calibration. A piece of tube was rotated around its own axis during four channel wall thickness mea.surements (Figure 7). The four traces are not identical A rotation apart as should be expected. The calibrations of the four equipment s from the manufacture was not the same. Especially one of the traces has less dynamic than the other three. Based on these observations a dynamic calibration system was suggested using a tube, which could be rotated around its own axis in the measuring system. The values should be verified using traditional mechanical measurement around the tube circumference. The prototype system was permanently installed in the workshop at the production hall. Experimental work was more difficult under such circumstances so our participation in the development work stopped. [Pg.901]

As is made evident in the next section, there is no sharp dividing line between these two types of adsorption, although the extremes are easily distinguishable. It is true that most of the experimental work has tended to cluster at these extremes, but this is more a reflection of practical interests and of human nature than of anything else. At any rate, although this chapter is ostensibly devoted to physical adsorption, much of the material can be applied to chemisorption as well. For the moment, we do assume that the adsorption process is reversible in the sense that equilibrium is reached and that on desorption the adsorbate is recovered unchanged. [Pg.601]

Figure Al.3.20. Real part of the dielectric function for silicon. The experimental work is from [31]. The theoretical work is from an empirical pseudopotential calculation [25]. Figure Al.3.20. Real part of the dielectric function for silicon. The experimental work is from [31]. The theoretical work is from an empirical pseudopotential calculation [25].
The atoms on the outennost surface of a solid are not necessarily static, particularly as the surface temperature is raised. There has been much theoretical [12, 13] and experimental work (described below) undertaken to investigate surface self-diffiision. These studies have shown that surfaces actually have dynamic, changing stmetures. For example, atoms can diflfiise along a terrace to or from step edges. When atoms diflfiise across a surface, they may move by hopping from one surface site to the next, or by exchanging places with second layer atoms. [Pg.292]

In experimental work it is usually most convenient to regard temperature and pressure as die independent variables, and for this reason the tenn partial molar quantity (denoted by a bar above the quantity) is always restricted to the derivative with respect to Uj holding T, p, and all the other n.j constant. (Thus iX = [right-hand side of equation (A2.1.44) it is apparent that the chemical potential... [Pg.350]

Covalent immobilization of proteins on nricrostmctured gold surfaces was studied in [226]. On Arese substrates, which were prepared by pCP aird etching. Are immobilization sites of proteins could be spatially controlled using air amino-reactive SAM. The whole process, i.e. production of Are micropattemed substrate including SAM exchairge aird protein immobilization, took a reasonably small amount of time ( 24 h), providing some flexibility in the experimental work. [Pg.2628]

Unfortunately, in most cases not all the available information on a reaction is given in the reaction equation in a publication, and even less so in reaction databases. To obtain a fuller picture of the reaction that was performed, the text describing the experimental procedure in the publication or a lab journal) would have to be consulted. Reaction products that are considered as trivial, such as water, alcohol, ammonia, nitrogen, etc., are generally not included in the reaction equation or mentioned in the text describing the experimental work. This poses serious problems for the automatic identification of the reaction center. It is highly desirable to have the full stoichiometry of a reaction specified in the equation. [Pg.171]

Ac Che limic of Knudsen screaming Che flux relacions (5.25) determine Che fluxes explicitly in terms of partial pressure gradients, but the general flux relacions (5.4) are implicic in Che fluxes and cheir solution does not have an algebraically simple explicit form for an arbitrary number of components. It is therefore important to identify the few cases in which reasonably compact explicit solutions can be obtained. For a binary mixture, simultaneous solution of the two flux equations (5.4) is straightforward, and the result is important because most experimental work on flow and diffusion in porous media has been confined to pure substances or binary mixtures. The flux vectors are found to be given by... [Pg.42]

In general, tests have tended to concentrate attention on the ability of a flux model to interpolate through the intermediate pressure range between Knudsen diffusion control and bulk diffusion control. What is also important, but seldom known at present, is whether a model predicts a composition dependence consistent with experiment for the matrix elements in equation (10.2). In multicomponent mixtures an enormous amount of experimental work would be needed to investigate this thoroughly, but it should be possible to supplement a systematic investigation of a flux model applied to binary systems with some limited experiments on particular multicomponent mixtures, as in the work of Hesse and Koder, and Remick and Geankoplia. Interpretation of such tests would be simplest and most direct if they were to be carried out with only small differences in composition between the two sides of the porous medium. Diffusion would then occur in a system of essentially uniform composition, so that flux measurements would provide values for the matrix elements in (10.2) at well-defined compositions. [Pg.101]

The student should read Sections 1,10 to 1,16 carefully before commencing any experimental work. A supply of melting point capillaries is prepared as described in Section 11,10 (compare Fig. 77, R , I). The apparatus illustrated in Fig. 77. 10, 2, a is assembled with concentrated sulphuric acid as the bath liquid the thermometer selected should have a small bulb. The melting points of pure samples of the following compounds are determined in the manner detailed in Section 11,10 —... [Pg.229]

Chapters V-X deal respectively with Heterocyclic and Alicyclic Compounds Miscellaneous Reactions Organic Reagents in Inorganic and Organic Chemistry Dyestuffs, Indicators and Related Compounds Some Physiologically-Active Compounds and Synthetic Polymers. Many of these preparations are of course intended for advanced students, but a mere perusal of the experimental details of selected preparations by those whose time for experimental work is limited may assist to impress them on the memory. Attention is particularly directed to the chapter... [Pg.1193]

This chapter introduces the experimental work described in the following chapters. Some mechanistic aspects of the Diels-Alder reaction and Lewis-acid catalysis thereof are discussed. This chapter presents a critical survey of the literature on solvent ejfects on Diels-Alder reactions, with particular emphasis on the intriguing properties of water in connection with their effect on rate and selectivity. Similarly, the ejfects of water on Lewis acid - Lewis base interactions are discussed. Finally the aims of this thesis are outlined. [Pg.1]

Now that all the experimental work has been presented in the preceding chapters, the opportunity arises to survey what has been accomplished. In the next section we will evaluate whether or not the goals as formulated at the end of Chapter 1 have been reached. [Pg.161]

The facilities for experimental work were poor, with inadequate wet laboratory space. In our discussions, I mentioned to Kaprielian my interest in significantly extending my previous work into the area of hydrocarbon chemistry. I felt that by establishing a strong program of basic research and graduate education in hydrocarbon chemistry, USC could become a leader in this important field. Because the memory of the first Arab oil embargo was still fresh, this struck a chord with Kaprielian, who felt that he could sell my research interest to the trustees and establish a Hydrocarbon Research Institute at USC that could accommodate me, as well as other chemistry faculty members whose interests could fit into its framework. [Pg.111]

There is a fundamental difference between such scientific controversies and what simply can be called scientific fraud, i.e., deliberate falsification or fudging of data. Sloppy experimental work or data keeping can also lead to questionable or incorrect conclusions, and, although these violate established scientific standards and must be corrected (as they will), they do not necessarily represent deliberate fraud. In all this, the professor has a strict personal responsibility. As he/she is getting most of the recognition for the accomplishment of the research, it is only natural that he/she must also shoulder the responsibility for any mistakes, errors, or even falsifications. It is not accepta-... [Pg.249]

Among the authors whose contribution has been important in the past, either by their experimental work or by their theoretical approach, the names of Koenig. Hamer, Fischer. Brooker, Kiprianov, Sklar, Schwarzen-bach, Eistert, Dimroth, and Platt are well familiar to scientists having an interest in the field of methine dyes, as well as more recently those of Kuhn, Wizinger, Scheibe, Hiinig, Van Dormael, Dahne, and Fabian. [Pg.68]

Each of the elements has a number of isotopes (2,4), all radioactive and some of which can be obtained in isotopicaHy pure form. More than 200 in number and mosdy synthetic in origin, they are produced by neutron or charged-particle induced transmutations (2,4). The known radioactive isotopes are distributed among the 15 elements approximately as follows actinium and thorium, 25 each protactinium, 20 uranium, neptunium, plutonium, americium, curium, californium, einsteinium, and fermium, 15 each herkelium, mendelevium, nobehum, and lawrencium, 10 each. There is frequently a need for values to be assigned for the atomic weights of the actinide elements. Any precise experimental work would require a value for the isotope or isotopic mixture being used, but where there is a purely formal demand for atomic weights, mass numbers that are chosen on the basis of half-life and availabiUty have customarily been used. A Hst of these is provided in Table 1. [Pg.212]

A great deal of experimental work has also been done to identify and quantify the ha2ards of explosive operations (30—40). The vulnerabiUty of stmctures and people to shock waves and fragment impact has been well estabUshed. This effort has also led to the design of protective stmctures superior to the conventional barricades which permit considerable reduction ia allowable safety distances. In addition, a variety of techniques have been developed to mitigate catastrophic detonations of explosives exposed to fire. [Pg.7]

Developments Outside Germany. In the late 1930s experimental work in England (29—31) led to the erection of large pilot faciHties for Fischer-Tropsch studies (32). In France, a commercial faciHty near Calais produced ca 150 m (940 bbl) of Hquid hydrocarbons per day. In Japan, two fijH-scale plants were also operated under Ruhrchemie Hcense. Combined capacity was ca 400 m (2500 bbl) of Hquids pet day. [Pg.80]

Dimethipin. 2,3-Dihydro-5,6-dimethyl-l,4-dithiin-l,l,4,4-tetraoxide [55290-64-7] (dimethipin, oxidimetbiin, UBI-N252, Harvard) (25) is used as a cotton defoHant and has been used as an experimental desiccant in potato vines. In addition, it defoHates nursery stock, grapes, dry beans, and natural mbber and is used as a desiccant for seed of canola, flax (l lnum usitatlssimum), rice, and sunflower (He/lanthus annuus) (10). The product has been available since the mid-1970s and the experimental work was first reported in 1974 (44). [Pg.424]

In veterinary medicine, the Hst of inhalation anesthetics generally includes only two agents, halothane [151 -67-7] and methoxyflurane [76-38-0]. Although ether (ethyl ether) is used extensively in experimental work with laboratory animals, the risks associated with its use and the advantages of halothane and methoxyflurane have removed ether from general use by the practitioner. [Pg.405]


See other pages where Experimental work is mentioned: [Pg.362]    [Pg.77]    [Pg.879]    [Pg.887]    [Pg.913]    [Pg.2837]    [Pg.2846]    [Pg.168]    [Pg.260]    [Pg.516]    [Pg.532]    [Pg.21]    [Pg.591]    [Pg.56]    [Pg.68]    [Pg.68]    [Pg.9]    [Pg.280]    [Pg.1289]    [Pg.230]    [Pg.552]    [Pg.106]    [Pg.34]    [Pg.5]    [Pg.129]    [Pg.30]    [Pg.202]   
See also in sourсe #XX -- [ Pg.783 ]

See also in sourсe #XX -- [ Pg.347 ]




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