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Esters of fatty acids

The term fat is applied to solid esters of fatty acids with glycerol (glycerides) if the fat is liquid at the ordinary temperature, it is conventionally called a fatty oil, vegetable oil or animal oil. The acids which occur most abundantly are palmitic ticid CH3(CHj),4COOH, stearic acid CH3(CH2)isCOOH and oleic acid CH3(CH2),CH=CH(CH2),C00H. Upon hydrolysis, fats yield glycerol and the alkali salts of these acids (soaps) ... [Pg.444]

The free acids are obtained upon acidification. Fata usually consist of mixtures of glycerides. The term wax is usually applied to esters of fatty acids with other alcohols such as cetyl alcohol CH3(CH2),4CHjOH and oleyl alcohol CH3(CHj),CH=CH(CHj),CH30H. [Pg.445]

Waxes are mixtures of substances that usually contain esters of fatty acids and long chain alcohols... [Pg.1102]

Fats and oils are one of the oldest classes of chemical compounds used by humans. Animal fats were prized for edibiUty, candles, lamp oils, and conversion to soap. Fats and oils are composed primarily of triglycerides (1), esters of glycerol and fatty acids. However, some oils such as sperm whale (1), jojoba (2), and orange roughy (3) are largely composed of wax esters (2). Waxes (qv) are esters of fatty acids with long-chain aUphatic alcohols, sterols, tocopherols, or similar materials. [Pg.122]

Chemical bleaching is never used on oils intended for edible use because it oxidizes unsaturated fatty acids to cause off-flavors. However, it does find wide usage for specialty linseed oil, for the paint industry, and fatty chemicals such as sorbitan esters of fatty acids and sodium stearoyl lactylate. Residual peroxide is destroyed by heating above its decomposition temperature. [Pg.125]

The primary products used are fatty acids with 12—18 carboa atoms and fatty alcohols, or esters of fatty acids such as the glycerides of rapeseed and lard oil (18). Eatty acid amines and amides are used ia metal working, particularly ia emulsions (18). [Pg.242]

Olestra is prepared by a solvenfless transesterification process in which sucrose is treated with methyl ester of fatty acids in the presence of sodium methoxide between 100—180°C for 14 hours (68). The manufacturing process involves removal of the unreacted fatty acid esters by enzymic hydrolysis... [Pg.33]

Sulfated Acids, Amides, and Esters. Reaction with sulfuric acid may be carried out on fatty acids, alkanolamides, and short-chain esters of fatty acids. The disodium salt of sulfated oleic acid is a textile additive and an effective lime soap dispersant. A typical sulfated alkanolamide stmcture is CiiH23C0NHCH2CH20S03Na. Others include the sulfates of mono and diethanolamides of fatty acids in the detergent range. The presence of... [Pg.244]

Polyoxyethylene Esters. This series of surfactants consists of polyoxyethylene (polyethylene glycol) esters of fatty acids and aUphatic carboxyhc acids related to abietic acid (see Resins, natural). They differ markedly from mono- and diglycerides in properties and uses. [Pg.249]

Synthetic Conjugated Oils. Tung oil dries rapidly, but is expensive, and its films discolor rapidly due to the presence of three double bonds. These defects led to efforts to synthesi2e conjugated oils, especially those containing esters of fatty acids with two conjugated double bonds. [Pg.261]

Transesterification has a number of important commercial uses. Methyl esters of fatty acids are produced from fats and oils. Transesterification is also the basis of recycling technology to break up poly(ethylene terephthalate) [25038-59-9] to monomer for reuse (29) (see Recycling, plastics). Because vinyl alcohol does not exist, poly(vinyl alcohol) [9002-89-5] is produced commercially by base-cataly2ed alcoholysis of poly(vinyl acetate) [9003-20-7] (see Vinyl polymers). An industrial example of acidolysis is the reaction of poly(vinyl acetate) with butyric acid to form poly(vinyl butyrate) [24991-31-9]. [Pg.388]

Rhodamine 6G long-chain hydrocarbons [169] squalene, a-amyrin [170] methyl esters of fatty acids [171] glycerides [91] sterols [172, 173] isoprenoids, quinones [HI] lipoproteins [174] glycosphingolipids [175] phenolic lipids [176] phosphonolipids [177] increasing the sensitivity after exposure to iodine vapor [178,179]... [Pg.44]

Esters of fatty acids [18, 19] monohydrate phoric acid... [Pg.242]

The chromatograms are freed from mobile phase (5 min in a stream of warm air), immersed in the dipping solution for 4 s or sprayed evenly with it and then heated to 110 C for 20 min (the methyl esters of fatty acids are heated to 140°C for 10 min [6]). [Pg.300]

Natural fats are glycerol esters of fatty acids known as triglycerides. Unsaturated fats are generally liquids (oils) at room temperature, while triglycerides rich in saturated fatty acids are generally solids. View tristearin and triolein. Which one of these is saturated and which is unsaturated Are die double bonds in the unsaturated fat cis or transl... [Pg.157]

Similarly, esters of fatty acids and polyethylene glycols are produced by the reaction of long-chain fatty acids and ethylene oxide ... [Pg.196]

Higher molecular primary unbranched or low-branched alcohols are used not only for the synthesis of nonionic but also of anionic surfactants, like fatty alcohol sulfates or ether sulfates. These alcohols are produced by catalytic high-pressure hydrogenation of the methyl esters of fatty acids, obtained by a transesterification reaction of fats or fatty oils with methanol or by different procedures, like hydroformylation or the Alfol process, starting from petroleum chemical raw materials. [Pg.20]

Sorbitan esters of fatty acids are well known. Similar products can be made from ether carboxylic acids and sorbitol without an acid catalyst with a good color [39]. The advantage of these products is that the hydrophilicity can be adjusted by the polyethylene glycol content in the ether carboxylic acid. [Pg.320]

Part of the diet consists of fats, which are triglycerol esters of fatty acids (FAs). The FAs from digestion of ingested fats can be metabolized in a variety of pathways. Fragments of the original FAs are preserved in these processes and can be utilized in the biosynthesis of other molecules. It is important to note that, during metabolism, almost all FAs are broken down into two-carbon units. The only exceptions are FAs with odd numbers of carbon atoms these are relatively rare in the diet. It ean be shown further that there is a partial barrier to the incorporation of FA-derived carbon into the amino acids which constitute collagen. [Pg.193]

Simple lipids Esters of fatty acids with various alcohols. [Pg.111]

Complex lipids Esters of fatty acids containing groups in addition to an alcohol and a fatty acid. [Pg.111]

FIGURE 9.1 GC/MS of total methyl esters of fatty acids standards and single fractions after PLC. Abbreviations first number (18 or 20) = number of carbon atoms in the chain second number (0 to 5) = number of double bounds n = normal chain i =isoacid ai = anteisoacid m-br =multi-branched acid. (From Rezanka, T., J. Chromatogr. A, 727, 147-152, 1996. With permission.)... [Pg.201]


See other pages where Esters of fatty acids is mentioned: [Pg.172]    [Pg.1008]    [Pg.136]    [Pg.99]    [Pg.220]    [Pg.21]    [Pg.249]    [Pg.252]    [Pg.304]    [Pg.291]    [Pg.450]    [Pg.339]    [Pg.439]    [Pg.259]    [Pg.260]    [Pg.243]    [Pg.299]    [Pg.581]    [Pg.840]    [Pg.637]    [Pg.113]    [Pg.624]    [Pg.652]    [Pg.111]    [Pg.111]   
See also in sourсe #XX -- [ Pg.11 ]




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Butyl ester of fatty acid

Chromatography of fatty acid methyl esters

Fatty acid esters of sorbitan

Fatty acids and esters of monohydric alcohols

Fatty acids esters

Glycerol Esters of Condensed Castor Oil Fatty Acids

Glyceryl esters of fatty acids

Glyceryl-Lacto Esters of Fatty Acids

Lactylated Fatty Acid Esters of Glycerol

Lactylated Fatty Acid Esters of Glycerol and Propylene Glycol

Lactylic Esters of Fatty Acids

Lipase-catalyzed synthesis of saccharide-fatty acid esters

Of fatty acid methyl esters

Of fatty acids and their esters

Oxyethylation of fatty acid methyl esters

Polyethylene glycol ester of fatty acid

Polyglycerol Esters of Fatty Acids

Polyglyceryl esters of fatty acids

Polyoxethylene esters of fatty acids

Polyoxyethylene esters of fatty acids

Properties of Fatty Acid Methyl and Ethyl Esters Related to Biofuels

Properties of Fatty Acids and their Methyl Esters

Propylene glycol esters of fatty acids

Starch Esters of Higher Fatty Acids

Sucrose esters, of fatty acids

The Biosynthesis of Fatty Acids and their Esters

Transformation of fatty acid esters into saturated hydrocarbon mixtures

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