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Esters containing

Only esters containing two a-hydrogen atoms (ethyl acetate, propionate, n-butyrate, etc.) can be condensed with the aid of sodium alkoxides. For esters with one a-hydrogen atom, such as ethyl tsobutyrate, the more powerful base sodium triphenylmethide PhaC Na leads to condensation with the formation of ethyl a-tsobutyrylisobutyrate ... [Pg.477]

It may be pointed out that dehydration of p hydroxy esters with fused potassium hydrogen sulphate, acetic anhydride, phosphoric oxide or with tliionyl chloride in benzeue solution leads to ap unsiiturated esters containing some PY-unsaturated ester the proportion of the latter depends not only upon the structure of the ester but also upon the dehydrating agent used. Elehydration occasionally occurs during the reaction itself or upon attempted distillation. [Pg.874]

Commercial polyoxyethylene fatty acid esters contain varying proportions of monoesters,... [Pg.249]

Titanoxanes can also be prepared by reaction of a tetraalkyl titanate and carboxyUc acids (25). If the ratio of carboxyUc acid to tetraalkyl titanate is 1 1, a simple polymeric titanate ester is formed. If two or more moles of acid are used per mole of tetraalkyl titanate, the resulting polymeric titanate ester contains ester carboxylate groups. [Pg.141]

Mixed cellulose esters containing the dicarboxylate moiety, eg, cellulose acetate phthalate, have commercially useful properties such as alkaline solubihty and excellent film-forming characteristics. These esters can be prepared by the reaction of hydrolyzed cellulose acetate with a dicarboxyhc anhydride in a pyridine or, preferably, an acetic acid solvent with sodium acetate catalyst. Cellulose acetate phthalate [9004-38-0] for pharmaceutical and photographic uses is produced commercially via the acetic acid—sodium acetate method. [Pg.249]

Mixed esters containing the dicarboxylate moiety, eg, cellulose acetate phthalate, are usually prepared from the partially hydroly2ed lower aUphatic acid ester of cellulose in acetic acid solvent by using the corresponding dicarboxyhc acid anhydride and a basic catalyst such as sodium acetate (41,42). Cellulose acetate succinate and cellulose acetate butyrate succinate are manufactured by similar methods as described in reference 43. [Pg.252]

Other mixed esters, eg, cellulose acetate valerate [55962-79-3] cellulose propionate valerate [67351-41-17, and cellulose butyrate valerate [53568-56-2] have been prepared by the conventional anhydride sulfuric acid methods (25). Cellulose acetate isobutyrate [67351-38-6] (44) and cellulose propionate isobutyrate [67351-40-0] (45) have been prepared with a 2inc chloride catalyst. Large amounts of catalyst and anhydride are required to provide a soluble product, and special methods of delayed anhydride addition are necessary to produce mixed esters containing the acetate moiety. Mixtures of sulfuric acid and perchloric acid are claimed to be effective catalysts for the preparation of cellulose acetate propionate in dichi oromethane solution at relatively low temperatures (46) however, such acid mixtures are considered too corrosive for large-scale productions. [Pg.252]

Low viscosity cellulose propionate butyrate esters containing 3—5% butyryl, 40—50% propionyl, and 2—3% hydroxyl groups have excellent compatibihty with oil-modified alkyd resins (qv) and are used in wood furniture coatings (155). Acetate butyrate esters have been used in such varied apphcations as hot-melt adhesive formulations (156), electrostatically spray-coated powders for fusible, non-cratering coatings on metal surfaces (157—159), contact lenses (qv) with improved oxygen permeabiUty and excellent wear characteristics (160—162), and as reverse-osmosis membranes for desalination of water (163). [Pg.260]

Macrocyclic amides and esters containing the 2,6-dipicolinate subunit. . 241... [Pg.226]

Table 5.11. Macrocyclic esters containing the 3,5-dipicolinate subunit... Table 5.11. Macrocyclic esters containing the 3,5-dipicolinate subunit...
This mechanism is supported by the finding, that esters containing just one a-hydrogen do not undergo that reaction, unless much stronger bases are used, since the condensation product 9 cannot be stabilized under the usual reaction conditions and the equilibrium lies to the left ... [Pg.56]

The application to a mixture of two different esters, each with a-hydrogens, is seldom of preparative value, since a mixture of the four possible condensation products will be obtained. If however only one of the starting esters contains a-hydrogens, the crossed Claisen condensation often proceeds in moderate to good yields. [Pg.56]

The esterification reaction is also used to prepare epoxy esters from epoxy resins having an n value of 4 and vegetable oil fatty acids. They may be used in the same way as alkyds where better chemical resistance and adhesion are required. Unlike the alkyds, the epoxy esters contain virtually no acid groups. [Pg.679]

The reaction between an alcohol and a carboxylic acid forms an ester, containing the functional group... [Pg.595]

For the determination of the enantiomeric excess. 23 mg of the mi-hydroxy ester (containing 2 5% //-product) and 9 mg of tris[3-(heptafluoropropylhydroxymethylene)-a-camphorato]europium are dissolved in 0.5 mL of CDC13. The ec is calculated from the peak heights and areas of the resolved doublets, due to the methyl groups attached to C-2. of the minor (f) 1.74) and major (<5 1.98) enantiomers. [Pg.611]

Only a few building blocks are available for the synthesis of ester-containing rigid mesogenic units, namely dihydroxy-, dicarboxy-, or (hydroxy, carboxy)-l,4-phenylenes, 4,4,-biphenylenes, and 2,6-, 1,4-, or 1,5-naphthylenes (Table 2.15). [Pg.49]

Keywords acrylate esters containing F or CF3 groups, Diels-Alder reactions... [Pg.317]

An electrochemical method for amination has been reported by Shono et al. Derivatives of malonic esters containing an N-tosyl group were cyclized in high... [Pg.925]

Besides ordinary esters (containing an a hydrogen), the reaction can also be carried out with lactones and, as in 16-38, with the y position of a,p-unsaturated esters (vinylogy). There are also cases, where the enolate anion of an amide was condensed with an aldehyde. ... [Pg.1224]

Even though poly(ortho esters) contain hydrolytically labile Linkages, they are highly hydrophobic materiads and for this reason are very stable and can be stored without careful exclusion of moisture. However, the ortho ester linkage in the polymer is inherently thermally unstable and at elevated temperatures is believed to dissociate into an alcohol and a ketene acetal (33). A possible mechanism for the thermal degradation is shown below. This thermal degradation is similar to that observed with polyurethanes (34). [Pg.150]

How to Use the Book to Locate Examples of the Preparation of Difunctional Compounds. The difunctional index on p. xi gives the section and page corresponding to each difunctional product. Thus Section 327 (Alcohol, Thiol-Ester) contains examples of the preparation of hydroxyesters Section 323 (Alcohol, Thiol-Alcohol, Thiol) contains examples of the preparation of diols. [Pg.18]

In previous studies in the author s laboratory it has become clear that, in most diolefin derivatives, replacement of the oxygen atom of an ester moiety by a sulfur atom is possible without changing the photopolymerizable molecular arrangement, and that all of the thioester derivatives and even mixed crystals of the ester containing a small amount of thioester derivatives of 1,4-phenylene diacrylate (PDA) are photostable (Hasegawa et al., unpublished data). [Pg.133]

McKervey and Ye have developed chiral sulfur-containing dirhodium car-boxylates that have been subsequently employed as catalysts for asymmetric intramolecular C-H insertion reactions of y-alkoxy-ot-diazo-p-keto esters. These reactions produced the corresponding ci -2,5-disubstituted-3(2H)-furanones with diastereoselectivities of up to 47% de. Moreover, when a chiral y-alkoxy-a-diazo-p-keto ester containing the menthyl group as a chiral auxiliary was combined with rhodium(II) benzenesulfoneprolinate catalyst, a considerable diastereoselectivity enhancement was achieved with the de value being more than 60% (Scheme 10.74). [Pg.352]


See other pages where Esters containing is mentioned: [Pg.166]    [Pg.490]    [Pg.36]    [Pg.138]    [Pg.50]    [Pg.215]    [Pg.249]    [Pg.251]    [Pg.527]    [Pg.386]    [Pg.52]    [Pg.45]    [Pg.226]    [Pg.424]    [Pg.175]    [Pg.313]    [Pg.397]    [Pg.18]    [Pg.89]    [Pg.325]    [Pg.570]    [Pg.202]    [Pg.43]    [Pg.259]   
See also in sourсe #XX -- [ Pg.172 ]




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Acetylenecarboxylic esters, reactions with nitrogen-containing heterocycles

Acetylenecarboxylic esters, reactions with nitrogen-containing heterocycles through nucleophilic additions

Alkylation by means of phosphorus-containing esters

Containing metal-oxygen bonds esters

Cyclic esters containing sulfur

Diorganotin Salts or Esters Containing Tin-Heteroatom Bonds

Ester An organic compound that contains

Ester Containing N Acylhydrazones

Ester, Epoxy, and Phenolic Resins Containing POSS

Ester-containing linker

Ester-containing macrocycles

Esters containing Negative Groups

Ethylene oxide use in synthesizing esters containing phosphorus

Fluorine -containing cellulose ester

Fluoroelastomers Containing Copolymerized Units of Vinyl Esters

Ketones, Aldehydes, Amides, Carboxylic Acids, and Esters All Contain a Carbonyl Croup

Metalation ester-containing polymers

Nitrogen-containing esters, formation

Nomenclature of esters containing phosphorus

Phosphorodithioates containing carboxylic acid ester and amide groups

Phosphorus-containing cyclic ester

Polyimides containing ester

Pyridine-containing esters

Silicon Containing Esters with Different Types of Bioactivity

Sulfate ester-containing compounds

Synthetic containing ester bond

Synthetic polymers containing ester bonds

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