Scheduling hazards

For a scheduled hazardous operation, such as sample collecting (see Hgure 12-3). In this case protective gloves, splash shield and other PPE might be required... 

Economic Considerations. The principal economic consideration is, of course, total installed system cost, including the initial cost of the flow primary, flow secondary, and related ancillary equipment as well as material and labor required for installation. Other typical considerations are operating costs and the requirements for scheduled maintenance. An economic factor of increasing importance is the cost of disposal at the end of normal flow meter service life. This may involve meter decontamination if hazardous fluids have been measured. 

The selection of materials to be used in design dictates a basic understanding of the behavior of materials and the principles that govern such behavior. If proper design of suitable materials of construction is incorporated, the eqiiipment should deteriorate at a uniform and anticipated gradual rate, which will allow scheduled maintenance or replacement at regular inteivals. If localized forms of corrosion are characteristic of the combination of materials and environment, the materials engineer should still be able to predict the probable life of equipment, or devise an appropriate inspection schedule to preclude unexpected failures. The concepts of predictive, or at least preventive, maintenance are minimum requirements to proper materials selection. This approach to maintenance is certainly intended to minimize the possibility of unscheduled production shutdowns because of corrosion failures, with their attendant possible financial losses, hazard to personnel and equipment, and resultant environmental pollution. 

In order to overcome apprehension regarding erosion of turbine blades during service and the hazards attending such failure, provision is made for visual inspection by a strobe light and camera while in operation. Scheduled inspection by a camera (borescope) permits... 

List of Pollutants and Source Categories The law lists 189 hazardous air pollutants. One year after enactment EPA lists source categories (industries) which emit one or more of the 189 pollutants. In two years, EPA must publish a schedule for regulation of the listed source categories. 

Table 14.6 Classification of and hazard warning signs for substances dangerous for conveyance (Schedule 2 Part I)...

Extra duties are imposed on the producers of Special Waste , i.e. a waste that is on the European Hazardous Waste list reproduced in Table 17.6 and if it has one or more of the hazardous properties listed in Table 17.7 (reproduced from Part 2 of Schedule 2 of the Special Waste Regulations, 1996). Also Special Waste is any Controlled Waste which has one of the listed properties. Extra requirements are detailed for the safe transfer and management of such waste. 

Identifies hazardous material training program requirements and stores training information and schedules ... 

Reducing and eliminating hazards and their associated risks is the second major objective. Applying inherent safety principles early in the product/process development effort provides the greatest opportunity to achieve the objectives of the inherent safety review process for the project at hand. If these principles are applied late in the effort the results may have to be applied to the project after next as the schedule may not permit implementation of the results. 

The HASP should describe how potential health and safety hazards at the work site are located, identified, and measured. A written schedule including inspections and walk-throughs conducted by designated individuals should be specified. 

The employer establishes a system to promptly address the team s results, timely resolve recommendations, schedule completion, and communicate the activities to affected personnel, livery five years after the completion of the initial process hazard analysis, it is equivalently updated and revalidated. Employers retain the required process hazards analyses for the life of the nmei-v -.. 

Equipment used to process, store, or handle highly hazardous chemicals must be designed constructed, installed and maintained to minimize the risk of release. A systematic, scheduled, test and maintenance program is preferred over "breakdown" maintenance " that could compromise safety. Elements of a mechanical integrity program include 1) identification and categorization of equipment and instrumentation, 2) documentation of manufacturer data on mean time to failure, 3 ) test and inspection frequencies, 4) maintenance procedures, 5) training of maintenance personnel, 6) test criteria, and 7) documentation of test and inspection results. 

Air cleaning (dust collection) can be cost effective for LVHV systems handling valuable dusts. Care must be taken when handling potentially toxic dusts from air cleaners. Regular, routine reconditioning of fabric filters (e.g., by automatic shaking or pneumatic pulsing) is impottant. This can be accomplished on a set maintenance schedule or as a function of pressure drop across the fabric filter. It is not recommended to recirculate airflow back to the workplace because of the low air volume and potential hazards in the event of filter failures. 

GHB has been used both for legitimate clinical and chnical research purposes and for a range of iUicit purposes. It was marketed legally in the United States until 1990, when the U.S. Food and Drug Administration (FDA) banned its sale to consumers. Except for the one indication described later in this section, GHB is a Schedule I controlled substance without other FDA-approved indications. The FDA has also declared y-butyrolactone (GBL) as a List I chemical and 1,4-butanediol (1,4-BD) as a Class I health hazard, practically designating these GHB precursors, which are also industrial solvents, as illicit and unapproved new drugs (National Institute on Drug Abuse 2000). 

Requirements for labelling of containers for supply may differ from those for conveyance. Key features of a supply label are to identify the substance (the chemical name in most cases) and any hazards and safety precuations. In Europe the classification, packaging and labelling of dangerous substances is covered by Directive 67/548/EEC as amended. This requires labels to identify appropriate risk and safety phrases (Tables 12.2 and 12.3) depending upon product properties. A substance is considered dangerous if in Part lA of an approved list or if it exhibits hazardous properties as defined in Schedule 1 for supply, or Schedule 2 for conveyance as shown in Tables 12.4 and 12.5. Substances not tested should be labelled Caution — substance not yet fully tested . Criteria for risk phrases are provided, e.g. as in Table 12.6 for toxic compounds. 

Among the hazardous chemical weapons scheduled class 1-3, methyl isocyanate becoming more and more important as a precursor [83]. This is just one among a number of substances which could be made via micro-reactor synthesis. Especially in the case of so-called binary weapons, where two relatively harmless substances are mixed to give a weapon, on-site mixing is demanded this can be accomplished with high performance by micro reactors. Pocket-sized miniature plants can neither be monitored nor detected. 

Highly toxic perfluoroisobutylene (PFIB) poses a serious health hazard to the human respiratory tract. PFIB is a thermal decomposition of polytetrafluo-roethylene (PTFE), e.g., Teflon. PFIB is approximately lOx as toxic as phosgene. Inhalation of this gas can cause pulmonary edema, which can lead to death. PFIB is included in Schedule 2 of the Chemical Weapons Convention (CWC), the aim of the inclusion of chemicals such as PFIB was to cover those chemicals, which would pose a high risk to the CWC. 

Have all hazards associated with the use of process materials been identified, for example, identifying a schedule of risks Identify a risk category on a hazard-by-hazard basis. 

Are all emissions and discharges documented in an inventory, for example, process effluent domestic wastewater, cooling water, stack emissions, hazardous wastes, nonhazardous wastes Provide a schedule of emissions. Identify the risk category. 

A high hazard process unit ha explosion classification under petrochemical schedule ol W or E-5. 

C. High hazard tanks are ctoss "O" under the above schedule. Closs E" require special fMiiusrotiv. 

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