Resins properties

Blends of piperylenes and amylenes (mixed 2-methyl-1-butene and 2-methyl-2-butene) or UOP propylene dimers can be adjusted to produce softening points of 0—100°C and weight average molecular weights of <1200 (32,33). Careful control of the diolefin/branched olefin ratio is the key to consistent resin properties (34). 

The reaction is completed after 6—8 h at 95°C volatiles, water, and some free phenol are removed by vacuum stripping up to 140—170°C. For resins requiring phenol in only trace amounts, such as epoxy hardeners, steam distillation or steam stripping may be used. Both water and free phenol affect the cure and final resin properties, which are monitored in routine quaHty control testing by gc. OxaHc acid (1—2 parts per 100 parts phenol) does not require neutralization because it decomposes to CO, CO2, and water furthermore, it produces milder reactions and low color. Sulfuric and sulfonic acids are strong catalysts and require neutralization with lime 0.1 parts of sulfuric acid per 100 parts of phenol are used. A continuous process for novolak resin production has been described (31,32). An alternative process for making novolaks without acid catalysis has also been reported (33), which uses a... 

Typical resin properties Test method Value... 

Suspension Polymerization. Suspension polymerization is carried out in small droplets of monomer suspended in water. The monomer is first finely dispersed in water by vigorous agitation. Suspension stabiUzers act to minimize coalescence of droplets by forming a coating at the monomer—water interface. The hydrophobic—hydrophilic properties of the suspension stabiLizers ate key to resin properties and grain agglomeration (89). 

Table 1. Resin Properties Required for Various Fabrication Methods...

Polyester carbonate resins are made by the interfacial process described for standard PC resins. The phthalate units are introduced by reaction of the appropriate phthaloyl dichlorides concurrent with the phosgenation. At present, Bayer, GE, and Miles produce polyester carbonate resins (47) sales volume is low, probably ca 100 t/yr. Polyester carbonates are used primarily in appHcations requiring 5—25°C higher heat-deflection temperature and better hydrolytic performance than are provided by standard PC resins. Properties are given in Table 9. 

Resin property" 1-Butene copolymer 1 -Butene/4-methylpentene-1 terpolymer 4-Methylpentene-1 copolymer... 

Variation of Reaction Stages And Mole Composition Effect on Melamine-Urea-Formaldehyde (MUF) Resin Properties... 

MUF resin is widely used as an adhesive in wood industries, coating technology, paper industries and a main material in kitchenware production. In various applications, different resin properties are needed to suit its application. Important resin properties are for example higher resin solubility, low curing period with lower temperature and catalyst amount, good stability for longer shelf life, and lower free formaldehyde emission, as formaldehyde is very toxic, and can cause cancer [1]. One of the factors that affecting the MUF resin properties is the mole composition. The mole composition is a ratio of formaldehyde to amino compoimd... 

The MUF resin formulation is built up from combination of certain amount of formalin, melamine and urea (in initial and post refluxing stages) and also sorbitol. Variation on the formulation gives different resin properties. The optimum resin properties give the optimum MUF resin formulation. From the properties analysis data, the optimum formulation is determined by using Mixture Experimental Design D-optimal criterion. The selective criteria... 

The absorption of moisture critically affects other important resin properties, particularly those associated with low-dielectric and thermomechanical applications. Results of a 96-h boiling water immersion test are presented in Table 2.2. The moisture absorbed decreased substantially with fluoromethylene chain length from n = 3 to n = 6, followed by only modest decreases for n = 8 and 10. This latter behavior was somewhat unexpected and may be the effect of decreased cross-link density counteracting the increased fluorine content. These 100°C measurements are just above the glass transition and the situation may be different at room temperature. These measurements are in progress. 

Paint technologies, 18 54-55, 56 Paint viscosity, measuring, 18 69 Paired comparison test, 11 512 Paired synthesis, of phthalide and 4.4-butylbenzaldehyde, 9 680-681 PAI resins, properties of, 10 215t Pair production process, 21 313 Palatinit, 12 44... 

---