Distributors

These places are also local businesses that can be found in the chemicals section of any big city s yellow pages except that these places have some big connections. By this Strike means that they are licensed distributors for some of the biggest chemical and scienceware companies and manufacturers. Those big companies would never sell a thing to a punk like you or Strike. Even if a punk like you or Strike was to present a fake business front or... 

Big name science houses and chemical manufacturers These include such names as Fisher, Baxter, VWR, Cole-Parmer, Alltech, Aldrich and Sigma. It is very hard to get a fledgling account with these giants, but if one can then the sky s the limit. Most chemists should be happy getting these companies products through the distributors. 

As of the year 1998, small quantities of sassafras oil are still being sold on retail shelves without any scrutiny. Usually in 1-4oz sizes. Anything larger is usually sold only through distributors and manufacturers. And as of 1998, the DEA has informed most of these distributors that they (the DEA) want lists kept or sales reported of most, if not all, sassafras oil purchases. Mind you it is not illegal to buy the oil. It s just that you will be put on a list if you do. The operative term here is Watched Substance . Solution have someone else buy it for you. 

Specialty Gases. The purity of specialty gases depends on the systems and procedures adopted by the distributors for bulk gas supply and cylinder preparation, filling, and deHvery. The distributors need to foUow strict cylinder selection, preparation, and filling procedures to ensure the quaHty of the products. Most of the precautions taken into consideration in the bulk gases deHvery system are also appHed for specialty gases to eliminate recontamination. 

Eleven large volume consumers in the United States and their products from acetone are Hsted in Table 10 (47). The largest distributors are Ashland Chemical Company, Unocal Chemicals, ChemCentral, Van Waters Rogers, andJLM Industries (47). 

The commercial appHcation of this concept (68) is portrayed ia Figure 8, which shows the adsorbent as a stationary bed. A Hquid circulating pump is provided to pump Hquid from the bottom outiet to the top inlet of the adsorbent chamber. A fluid-directing device known as a rotary valve (69,70) is provided. The rotary valve functions on the same principle as a multiport stopcock in directing each of several streams to different lines. At the right-hand face of the valve, the four streams to and from the process are continuously fed and withdrawn. At the left-hand face of the valve, a number of lines are coimected that terminate in distributors within the adsorbent bed. 

Eig. 19. CME monopolar electrolyzer a, membrane b, cathode element c, half-cathode element d, current distributor e. Teflon tube f, CI2 + depleted brine manifold g, conductor rod h, CI2 + depleted brine outlet nozzle i, base frame j, recycled NaOH manifold k, recycled NaOH inlet nozzle 1, gasket (the gasket-to-element ratio is quite small) m, tie rod n, anode element o, H2 + NaOH manifold p, end plate, q, under cell bus bar (simplifies piping... 

Fig. 25. OxyTech MGC electroly2er a, membrane b, anode assembly c, manifold spacer d, anolyte outlet e, catholyte outlet f, bulkhead g, brine inlet h, NaOH inlet i, insulating channel j, bulkhead insulator k, interface material 1, cathode assembly m, interceU bus n, tie rod o, current distributor p,...

Drop Diameter. In extraction equipment, drops are initially formed at distributor no22les in some types of plate column the drops are repeatedly formed at the perforations on each plate. Under such conditions, the diameter is determined primarily by the balance between interfacial forces and buoyancy forces at the orifice or perforation. For an ideal drop detaching as a hemisphere from a circular orifice of diameter and then becoming spherical ... 

World consumption of potassium salts presentiy exceeds 28 million t of K O equivalent per year. About 93% of that is for fertilizer use (see POTASSIUM compounds). The potash [17353-70-7] industry is essentially a mining and beneftciation industry. The two main fertilizer materials, KCl and K SO are produced by beneftciating ores at the mine sites. The upgraded salts then are shipped to distributors and manufacturers of mixed goods. 

Fig. 19. TVA-type ammoniator—granulator incorporating a pipe cross reactor. 1, ammonia sparger, located at the 4 o clock position 11.4 cm from granulation shell with holes facing the rotating stream 2, phosphoric acid sparger, located to discharge phosphoric acid onto the top and near the center of the rotating bed of materials 3, pipe cross reactor 4, scmbber Hquor distributor, located above the bed in granulator to dribble scmbber Hquor onto bed.

Calcium. Soil minerals are a main source of calcium for plants, thus nutrient deficiency of this element in plants is rare. Calcium, in the form of pulverized limestone [1317-65-3] or dolomite [17069-72-6] frequendy is appHed to acidic soils to counteract the acidity and thus improve crop growth. Such liming incidentally ensures an adequate supply of available calcium for plant nutrition. Although pH correction is important for agriculture, and liming agents often are sold by fertilizer distributors, this function is not one of fertilizer manufacture. 

Based on estimates of resin sales for film and sheet. Includes estimate of captive use for photographic film and pressure-sensitive tape. Table 7. U.S. Manufacturers or Distributors of Film and Sheet ... 

A generic multipurpose fluidized bed is illustrated in Figure 2 (1). The soHds are contained in a vessel and gas is introduced into the system via a distributor, which is typically a drilled plate at the bottom of the vessel. A plenum chamber is provided below the distributor plate. The height of the soHds level above the distributor is called the bed height, and the vertical space above the bed height is called the freeboard. A splash zone may exist as a transition between the bed and freeboard. Cyclones, located either in the freeboard or external to the vessel, are used to remove soHds from the gas stream. Diplegs can return entrained soHds directly to the bed. 

Fig. 2. Multipurpose fluidized bed where 1 represents the sheU 2, soHd particles 3, the blower 4, the gas distributor 5, the heat exchanger for fluidizing gas 6, internal heating or cooling 7, external heating or cooling 8, cyclones 9, the soHds feeder 10, soHds offtake 11, Hquid feed 12, the freeboard 13, the...

As bubbles rise through the bed, they coalesce into larger bubbles. The actual bubble size at any height above the distributor, in the bed is a function of the initial bubble size as it emerges from the gas distributor and the gas flow rate (16) ... 

Good gas distribution is necessary for the bed to operate properly, and this requites that the pressure drop over the distributor be sufficient to prevent maldistribution arising from pressure fluctuations in the bed. Because gas issues from the distributor at a high velocity, care must also be taken to minimize particle attrition. Many distributor designs are used in fluidized beds. The most common ones are perforated plates, plates with caps, and pipe distributors. 

A perforated plate can be flat, concave, convex, or double-dished. The main advantages of the perforated plate are that it is simple, inexpensive, easy to modify, and easy to clean. The disadvantages of a perforated plate are the possibiUty of soflds leaking, ie, weeping through it into the plenum lower turndown capabiUty than other distributors the requirement of a peripheral seal and a relatively high pressure drop requited for good distribution. 

Several cap-type distributors are shown in Figure 12. These minimize weeping and have good turndown, but are difficult to clean and modify, and are more expensive than perforated plates. A peripheral seal is also requited as for a perforated plate. 

Fig. 12. Cap-type gas distributors where the fluid is directed laterally.

Figure 13 shows two pipe distributors, one in a branched and one in a ring configuration. These distributors minimize weeping, have good turndown, may requite the lowest pressure drop, and avoid the need for a plenum chamber. They are also well suited to multiple-level fluid injection. The disadvantages of these distributors are that there are defluidized soHds beneath the distributor and the mechanical design is more complex. 

Fig. 13. Examples of pipe gas distributors (a) simple sparger, (b) details of the pipe, (c) wagon wheel, and (d) multilevel distributor.

Design Considerations. For a perforated plate, the pressure drop across the distributor should be at least 30% of the bed pressure drop when operating at the lowest expected gas velocity. The number of holes in the distributor should exceed 10 per square meter. The pressure drop, AP, across the distributor is given by... 

In pipe distributors, the pressure drop requited for good gas distribution is 30% of the bed pressure drop for upward facing holes, but only 10% for downward facing ones. The pressure drop calculation and the recommended hole density are the same as for a perforated plate. To maintain good gas distribution within the header system, it is recommended the relation... 

Jet Penetration. At the high gas velocities used in commercial practice, there are jets of gas issuing from distributor holes. It is essential that jets not impinge on any internals, otherwise the internals may be quickly eroded. Figure 14 is a graphical correlation used to determine the jet penetration length as a function of gas velocity and gas density. Jets from horizontal and downflow holes are considerably shorter than those that are pointed upward. 

Particle Attrition. Distributor jets are a potential source of particle attrition. Particles are swept into the jet, accelerated to a high velocity, and smash into other particles as they leave. To reduce attrition at distributors, a shroud or larger-diameter pipe is often added concentric to the jet hole, as shown in Figure 15. The required length of the concentric shroud is given by the relation... 

Fig. 14. (a) Correlation of jet penetration, P, from distributors iato fluidized beds where (—) represents upwardly directed jets and (-) downwardly and... 

Fig. 15. Schematic of a distributor grid shroud used to allow jets to expand and enter the fluid bed at lower velocity.

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