Concentrations critical

Problems are usually encountered when pressure systems designed to operate at reasonable levels of particulate concentration are fed with dilute suspensions at the start of filtration. Low concentrations of sohds prevent the bridging effect which ensues when concentrated swarms of sohds are directed towards the pores in the filter medium. This effect is discussed quantitatively elsewhere in this Chapter. Failure to bridge the cloth pores will lead to deposition of particles inside the fabric. 

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Provided this equaHty is satisfied and the dissolved oxygen concentration in the weU-mixed Hquid is greater than the critical concentration throughout the bioreactor, then the maximum oxygen demand of the species should be met satisfactorily. Design of the bioreactor must ensure that the above requirements are achieved economically and without damaging the biological species. 

The separation of Hquid crystals as the concentration of ceUulose increases above a critical value (30%) is mosdy because of the higher combinatorial entropy of mixing of the conformationaHy extended ceUulosic chains in the ordered phase. The critical concentration depends on solvent and temperature, and has been estimated from the polymer chain conformation using lattice and virial theories of nematic ordering (102—107). The side-chain substituents govern solubiHty, and if sufficiently bulky and flexible can yield a thermotropic mesophase in an accessible temperature range. AcetoxypropylceUulose [96420-45-8], prepared by acetylating HPC, was the first reported thermotropic ceUulosic (108), and numerous other heavily substituted esters and ethers of hydroxyalkyl ceUuloses also form equUibrium chiral nematic phases, even at ambient temperatures. 

The passivating action of an aqueous solution within porous concrete can be changed by various factors (see Section 5.3.2). The passive film can be destroyed by penetration of chloride ions to the reinforcing steel if a critical concentration of ions is reached. In damp concrete, local corrosion can occur even in the presence of the alkaline water absorbed in the porous concrete (see Section 2.3.2). The Cl content is limited to 0.4% of the cement mass in steel-concrete structures [6] and to 0.2% in prestressed concrete structures [7]. 

Density. Most fillers added in rubber base formulation have a density between 2 and 2.7 g/cm-, except barium sulphate (4-4.9 g/cm- ) and zinc oxide (5.6 g/cm ). Addition of filler increases the free volume of the polymer and, in general, there is a critical concentration of filler at which the density of the formulation increases. The method of incorporation of filler in the adhesive formulation is important because air voids may appear when a poor dispersion is produced. 

Figure 49. Extrapolation of sedimentation data to estimate time for critical concentration.

For this safety criterion, we consider the fact that as the velocity decreases with increasing distance from the surface of the tank, it will reach some critical velocity, at which the induced movement of air will be insufficient to overcome the effects of crossdrafts or the buoyancy velocity At this point, we must ensure that the concentration is at, or below, some critical allowable concentration, Qfj,. The values of the critical concentration and velocity will depend (tn particular circumstances, but it is worth noting that must be at least equal to I g in order to overcome the effects of buoyancy, and the appropriate value will depend on the crossdrafts, which typically vary between 0.05 m to 0.5 in s F For the sake of providing examples, we have chosen to be the maximum of the buoyancy velocity and the typical cross-draft velocity. For the critical concentration we have chosen two values, C = 0.05 and C = 0.10. The actual value used by a designer would depend on the toxicity of the contaminant in question. 

FIGURE 10.75 Required initial kinematic momentum, f/p, as a function of the length of the tank, L, and the buoyancy velocity, v, when the critical contour criterion is applied with the critical concentration, C ,j, equal to 5% and the cross-drafts equal to 0.05 m s". ... 

X 10 M), and an equivalent amount of OH (its usual concentration in plasma) would swamp the buffer system, causing a dangerous rise in the plasma pH. How, then, can this bicarbonate system function effectively The bicarbonate buffer system works well because the critical concentration of H2CO3 is maintained relatively constant through equilibrium with dissolved CO2 produced in the tissues and available as a gaseous CO2 reservoir in the lungs. ... 

One of the most important characteristics of the emulsifier is its CMC, which is defined as the critical concentration value below which no micelle formation occurs. The critical micelle concentration of an emulsifier is determined by the structure and the number of hydrophilic and hydrophobic groups included in the emulsifier molecule. The hydrophile-lipophile balance (HLB) number is a good criterion for the selection of proper emulsifier. The HLB scale was developed by W. C. Griffin [46,47]. Based on his approach, the HLB number of an emulsifier can be calculated by dividing... 

In eq. (1) the ETT order parameter z = s(p-Pc) measures, in a convenient direction, the chemical potential from that corresponding to the ETT. From the values given in Table I for the above s and q, we readily see that the occurrence of the ETTs discussed in this paper always implies an increase of the alloy free energy. Thus, CuPt random alloys, that just below and above the equiatomic concentration present both the relevant ETT s, are less stable than CuPd or AgPd and, thus more likely to be destabilised. Moreover, the proximity to both the critical concentrations implies large contributions to the BSE from the X and L points. Now, the concentration wave susceptibility, Xcc(q). as observed by Gyorffy and Stocks, is proportional to... 

An increase followed by a decrease in corrosion rate at a certain critical concentration is a commonly observed phenomenon for many metals and alloys. If the anion concentration at which the decrease takes place is high, then the anion species is deemed to be aggressive, but if low the anion is referred to as inhibitive. A considerable amount of experimental work in... 

Amorphous Fe-3Cr-13P-7C alloys containing 2 at% molybdenum, tungsten or other metallic elements are passivated by anodic polarisation in 1 N HCl at ambient temperature". Chromium addition is also effective in improving the corrosion resistance of amorphous cobalt-metalloid and nickel-metalloid alloys (Fig. 3.67). The combined addition of chromium and molybdenum is further effective. Some amorphous Fe-Cr-Mo-metalloid alloys passivate spontaneously even in 12 N HCl at 60° C. Critical concentrations of chromium and molybdenum necessary for spontaneous passivation of amorphous Fe-Cr-Mo-13P-7C and Fe-Cr-Mo-18C alloys in hydrochloric acids of various concentrations and different temperatures are shown in Fig. 3.68 ... 

Fig. 3.68 Critical concentrations of chromium and molybdenum necessary for spontaneous passivation of amorphous Fe-Cr-Mo-13P-7C and Fe-Cr-Mo-18C alloys in hydrochloric acid of various concentrations and temperatures ...

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