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Structure atomic

This simple method of deducing the structure of molecules is called Valence Shell Electron Pair Repulsion Theory (VSEPRT). It says that all electron pairs, both bonding and nonbonding, in the outer or valence shell of an atom repel each other. This simple approach predicts (more or less) the correct structures for methane, ammonia, and water with four electron pairs arranged Lctrahedrally in each case. [Pg.83]

VSEPRT seems to work for simple structures but surely there must be more to it than this Indeed there is. If we really want to understand why molecules adopt the shapes they do, we must look at the atoms that make up the molecules and how they combine. By the end of this chapter, you should be able to predict or at least understand the shapes of simple molecules. For example, why are the bond angles in ammonia 107°, while in hydrides of the other elements in the same group as nitrogen, PH3, AsH3, and SbH3 they are all aronnd 90° Simple VSEPRT would suggest tetrahedral arrangements for each. [Pg.83]

You know already what makes up an atom—protons, neutrons, and electrons. The protons and neutrons make up the central core of an atom—the nucleus-—while the electrons form some sort of cloud around it. As chemists, we are concerned with the electrons in atoms and more importantly with the electrons in molecules chemists need to know how many electrons there are in a system, where they are, and what energy they have. Before we can understand the behaviour of electrons in molecules, we need to look closely at the electronic structure of an atom. Evidence first, theory later. [Pg.83]

If enough energy is supplied to a hydrogen atom, or any other energy 0 [Pg.83]

In the case of hydrogen a single proton is left. This is, of course, the h atom proton electron [Pg.83]

In order to understand atomic structure, some results from quantum mechanics have to be recalled. For simplicity, it is sufficient to consider the non-relativistic case however, the existence of the electron spin must be taken into account. The Hamiltonian H for an atom with Z electrons is given by (using atomic units which are defined in Section 6.1) [Pg.3]

The electronic structure of the ground state follows from the properties of the ground state wavefunction F which is the solution of the stationary Schrodinger equation [Pg.3]

Approximating the Coulomb interaction between the electrons by a mean spherical potential V(r), it follows that [Pg.4]

Second, one solves the approximate Hamiltonian H° for the Z-electron problem [Pg.4]

The wavefunction F° then follows as an antisymmetrized product built from the single-particle functions q i(r, ms) for the Z electrons (Slater determinantal wave-function, see below and Section 7.2), where r is the spatial vector and ms the spin magnetic quantum number. [Pg.4]

The theories of atomic and molecular structure depend on quantum mechanics to describe atoms and molecules in mathematical terms. Although the details of quantum mechanics require considerable mathematical sophistication, it is possible to understand the principles involved with only a moderate amount of mathematics. This chapter presents the fundamentals needed to explain atomic and molecular structures in qualitative or semiquantitative terms. [Pg.15]

Although the Greek philosophers Democritus (460-370 Bc) and Epicurus (341-270 Bc) presented views of nature that included atoms, many hundreds of years passed before experimental studies could establish the quantitative relationships needed for a coherent atomic theory. In 1808, John Dalton published A New System of Chemical Philosophy in which he proposed that [Pg.15]

When two measures of hydrogen and one of oxygen gas are mixed, and fired by the electric spark, the whole is converted into steam, and if the pressure be great, this steam becomes water. It is most probable then that there is the same number of particles in two measures of hydrogen as in one of oxygen.  [Pg.16]

In fact, he then changed his mind about the number of molecules in equal volumes of different gases  [Pg.16]

At the time I formed the theory of mixed gases, I had a confused idea, as many have, I suppose, at this time, that the particles of elastic fluids are all of the same size that a given volume of oxygenous gas contains just as many particles as the same volume of hydrogenous  [Pg.16]

An important reason to have an understanding of interatomic bonding in solids is that in some instances, the type of bond allows us to explain a material s properties. For example, consider carbon, which may exist as both graphite and diamond. Whereas graphite is relatively soft and has a greasy feel to it, diamond is one of the hardest known materials in nature. In [Pg.20]

After studying this chapter, you should be able to do the following  [Pg.20]

Name the two atomic models cited, and note the differences between them. [Pg.20]

Describe the important quantummechanical prin ciple that relates to electron energies. [Pg.20]

(a) Briefly describe ionic, covalent, metallic, hydrogen, and van der Waals bonds. [Pg.20]

In this Section we apply freeon theory to atomic structure. In Section 10.2 we give the freeon Gel fand structures of the second row of the periodic table and in Section 10.3 Gel fand diagrams are used to describe the splitting of d-electron configurations in an octahedral field. [Pg.54]

The initial incentive for the invention of quantum mechanics was the observed, discrete spectra of atoms and molecules which could not be predicted by classical mechanics. The Schrodinger differential equation is constructed from the classical energy and its physically-significant solutions were restricted to those which satisfied certain physically-significant boundary-conditions. This quantized the energy and supplied quantum numbers which identified the quantized states. In the Section 10.4 we take a different view of quantization. It is used, in the following Sections, to analyze atomic spectra. [Pg.54]

One of the early great triumphs of atomic theory was the aufbau principle which explained the periodic table. In it the atomic orbital energies were assigned the following order Is 2s 2p 3s . ..The occupation number of freeon orbitals was limited to no more than two as was discussed in Section 1. Further Hund s rule was imposed i. e. states of highest spin lie the lowest. The Gel fand state reconstruction of the aufbau for the second row of the periodic table (with mi = +1 or zero) is shown in Fig. 10.1 where 2p+ = + 1,2po = 0 and 2p.i = -1  [Pg.54]

The weak-field case like the free ion obeys Hund s rule while in the strong-field case Hund s rule is overcome by the increased relative stability of the t-type relative to the e-type orbitals [Pg.55]

This model Hamiltonian is diagonal in an IRS of U(M) which has been symmetry adapted to the above chain with eigenvalues denoted [Pg.58]

In this chapter a brief description of the energy-level structure of atomic systems will be given. This will not include a rigorous quantum-mechanical treatment, but will deal with more qualitative aspects. The atomic structures that are explored with the spectroscopic techniques discussed in this text will be described. For a more complete treatment the reader is referred to standard textbooks on atomic physics and quantum mechanics [2.1-18]. [Pg.4]

Before we begin our study of the compounds of carbon we need to review some basic but familiar ideas about the chemical elements and their structure. [Pg.2]

0079 Name (lUPAC) Atomic mass Carbon Chemical Abstracts Service group notation 4.0026 [Pg.3]

Lithium Beryllimi Boron Carbon Nitrogen Oxygen Fluorine Neon [Pg.3]

Sodium Magnesium Aluminum Silicon Phosphorus Sulfur Chlorine Argon [Pg.3]

Potassium Caicium Scandium Titanium Vanadium Chromium Manganese iron Cobalt Nickei Copper Zinc Gaiiium Germanium Arsenic Selenium Bromine Krypton [Pg.3]

The mass of an atom is concentrated in its minute, positiveiy charged nucleus. The eiectron configuration of an atom can be deduced from its atomic number. [Pg.52]

Understanding the structure of the atom has been a fundamental challenge for centuries. It is possible to gain a practical understanding of atomic and molecular structure using only a moderate amount of mathematics rather than the mathematical sophistication of quantum mechanics. This chapter introduces the fundamentals needed to explain atomic structure in qualitative and semiquantitative terms. [Pg.9]

Because Dalton was not aware of the diatomic nature of the molecules H2 and O2, which he assumed to be monatomic H and 0, he did not find the correct formula of water, and therefore his surmise about the relative numbers of particles in measures of the gases is inconsistent with the modem concept of the mole and the chemical equation 2H2 + 02 2H2O. [Pg.9]

During the 50 years after the periodic tables of Mendeleev and Meyer were proposed, experimental advances came rapidly. Some of these discoveries are listed in Table 2.1. [Pg.11]

The short range order and long range disorder lead to the model of the continuous random network, introduced by Zachariasen (1932) to describe glasses such as silica. The periodic crystalline structure is replaced by a random network in which each atom has a specific number of bonds to its immediate neighbors (the coordination). Fig. [Pg.5]

A real crystal contains defects such as vacancies, interstitials and dislocations. The continuous random network may also contain defects, but the definition of a defect has to be modified. Any atom [Pg.5]

The intrinsic disorder of the continuous network is less easily classified in terms of defects. The network has many different configurations, but provided the atomic coordination is the same, all these structures are equivalent and represent the natural variability of the material. Since there is no correct position of an atom, one cannot say whether a specific structure is a defect or not. Instead the long range disorder is intrinsic to the amorphous material and is described by a randomly varying disorder potential, whose effect on the electronic structure is summarized in Section 1.2.5. [Pg.7]

A knowledge of the structure of atoms provides the basis for understanding how they combine and the types of bonds that are formed. In this section, we review early work in this area, and variations in atomic properties will be related to the periodic table. [Pg.17]

The basic processes in optical atomic spectrometry involve the outer electrons of the atomic species and therefore its possibilities and limitations can be well understood from the theory of atomic structure itself. On the other hand, the availability of optical spectra was decisive in the development of the theory of atomic structure and even for the discovery of a series of elements. With the study of the relationship between the wavelengths of the chemical elements in the mid-19th century a fundament was obtained for the relationship between the atomic structure and the optical line emission spectra of the elements. [Pg.4]

In 1885 Balmer published that for a series of atomic lines of hydrogen a relationship between the wavelengths could be found and described as  [Pg.4]

Ti and T2 are the Bohr energy levels and the complexity of the emission spectra can be related to the complexity of the structure of the atomic energy levels. [Pg.5]

For an atom with a nucleus charge Z and one valence electron, the energy of this electron is given by  [Pg.5]

The elliptical orbits can take on different orientations with respect to an external electric or magnetic field and the projections on the direction of the field also are quantitized and given by  [Pg.5]

The wavenumbers of all so-called series in the spectrum of hydrogen are given by  [Pg.4]

Materials science is concerned with the structure of materials, the binding forces that hold materials together, and the relation between structure, properties, and behavior. Two types of structure may be distinguished—atomic structure and microscopic structure. [Pg.177]

All materials are composed of atoms, which in turn consist of a nucleus and a number of shells of planetary electrons. Electrons are negatively charged particles that are extremely small and essentially weightless. An atom consists mostly of empty space. This aspect of atomic structure was anticipated by Galileo. An atom is electrically neutral and for each planetary electron there is a positively charged particle (proton) in the nucleus. The protons have about 2,000 times the mass of an electron. The weight of the atom is due primarily to the protons and neutrons in the nucleus. A neutron is an uncharged proton (or proton + electron). [Pg.177]

The simplest representations of atoms are known as Bohr models. Such models are somewhat oversimplified and are incapable of explaining all atomic characteristics. However, the simplicity of the Bohr approach and the fact that it explains the main characteristics of the atom of interest to engineers makes it a very useful tool. [Pg.178]

A periodic table of the elements siunmarizes a number of important characteristics of neutral atoms. The iron atom (Fig. 8.1) has 26 planetary electrons in 4 shells and 26 protons plus 26 neutrons in the nucleus. This electrically neutral particle is about 0.01 microinches (pin.) in diameter. The outermost planetary electrons (valence electrons) are special. They determine the chemical properties of the element. Metals have few valence electrons but the nonmetals have several. When a metal loses its valence electrons, it becomes an ion. A positively charged ion is called a cation. When a nonmetal takes on valence electrons to bring the total munber to eight, it too becomes an ion (in this case a negative particle called m anion). Cations (positively charged particles) are considerably smaller than neutral atoms, while anions are relatively larger than neutral atoms. [Pg.178]

Radicals are combinations of atoms that are particularly stable and which are involved in chemical reactions without being decomposed into their constituent elements. They carry a negative charge as anions do. Relative sizes of a few anions, cations, and radicals are shown in Fig. 8.2. The diameters of ions in a metal structure are all about the same size (= 1- 4 Angstrom imits [A], 1 A = 10 i m = 0.1 nm = 0.004 pin.) [Pg.178]

The first ideas about electronic arrangement in atoms were primarily figured out from atomic emission spectra. In various experiments, atoms were made to be thermally or electrically excited, and this resulted in different kinds of bands or lines on photographic plates. Our understanding of atomic structure is based on these types of experiments. All elements have their characteristic line spectra with which they can be analyzed and identified. [Pg.39]

From 50 to 100 years after Dalton proposed his theory, various discoveries were made that show that the atom is not indivisible, but really is composed of parts. Natural radioactivity and the interaction of electricity with matter are two different types of evidence for this subatomic structure. The most important subatomic particles are listed in Table 3-1, along with their most important properties. The protons and neutrons are found in a very tiny nucleus (plural, nuclei). The electrons are found outside the nucleus. The information in Table 3-1 must be memorized, but only the whole number part of the masses (1 amu, 1 amu, 0 amu) must be remembered. [Pg.40]

EXAMPLE 3.4. Using the data of Table 3-1, find the charge on a nucleus that contains (a) 8 protons and 8 neutrons and (b) 8 protons and 10 neutrons. [Pg.40]

Both nuclei have the same charge. Although the nuclei have different numbers of neutrons, the neutrons have no charges, so they do not affect the charge on the nucleus. [Pg.40]

EXAMPLE 3.5. To the nearest integer, calculate the mass (in amu) of a nucleus that contains (a) 17 protons and 18 neutrons and (b) 17 protons and 20 neutrons. [Pg.40]

EXAMPLE 3.6. Refer to Table 3-1 and deduce which two of the types of subatomic particles in an uncombined atom occur in equal numbers. [Pg.41]

Just as the atom is the building block from which all materials are made, this chapter must be the building block upon which the rest of the book is made. The remaining chapters of this book are devoted to topics directly related to the behavior that can only be understood by first learning atomic structure. The information in this chapter will provide you with a solid foundation of knowledge upon which to build the remainder of your review. The AP exam has a few multiple-choice questions on the topics covered in this chapter and will periodically have one essay question as well. You will have a much easier time on the other sections of this book and the AP test if you can develop a firm understanding of atomic structure and its impact. [Pg.61]

The earliest known descriptions of atoms date back to between 460 and 370 B. C. E., when the Greek philosopher Democritus first proposed the idea that matter was composed of indivisible particles. He used the term atomos (indivisible) to describe these. Other philosophers, including Plato and Aristotle opposed Democritus s ideas, believing that matter was infinitely divisible—views that were widely held until the nineteenth century. [Pg.61]

During the period between 1803 and 1807, John Dalton proposed a theory of the atomic nature of matter. Dalton s basic postulates stated that  [Pg.61]

All matter is composed of extremely small particles called atoms. [Pg.61]

Atoms of like elements are identical, while elements of different elements are different. [Pg.61]

A clearer picture of the atom began to emerge toward the end of the first decade of the twentieth century. This picture was [Pg.38]

Thomson proposed the atom consisted of negative electrons embedded in a positive pool, like raisins in plum pudding. [Pg.38]

Roentgen s discovery of x-rays stimulated great interest in this new form of radiation worldwide. Antoine Henri Becquerel (1852-1908) accidentally discovered the process of radioactivity while he was studying x-rays. Radioactivity involves the spontaneous disintegration of unstable atomic nuclei. Becquerel had stored uranium salts on top of photographic plates in a dark drawer. When Becquerel retrieved the plates, he noticed the plates contained images made by the uranium salts. Bec-querel s initial discovery in 1896 was further developed by Marie Curie (1867-1934) and Pierre Curie (1859-1906). Marie Curie coined the word radioactive to describe the emission from uranium. [Pg.38]

Three main forms of radioactive decay involve the emission of alpha particles, beta particles, and gamma rays. An alpha particle is equivalent to the nucleus of a helium atom. Beta particles are nothing more than electrons. Gamma rays are a form of electromagnetic radiation. [Pg.38]

Electrons Changing Energy Level in the Bohr Atom [Pg.40]

Kris (1999). Basic Ideas and Concepts in Nuclear Physics An Introductory Approach, 2nd edition. Philadelphia Institute of Physics Publishers. [Pg.78]

Kenneth S. (1987). Introductory Nuclear Physics. New York Wiley. [Pg.78]

Seaborg, Glenn T., and Loveland, Walter D. (1990). The Elements beyond Uranium. New York Wiley. [Pg.78]

As a physical chemist, George Stoney made significant contributions to our understanding of molecular motion. However, this Irish scientist is better known for assigning a name to negative atomic charges, electrons, while addressing the Royal Society of Dublin in 1891. [Pg.78]

The ancient Greek philosophers Leucippus and Democritus beheved that atoms existed, but they had no idea as to their nature. Centuries later, in 1803, the English chemist John Dalton, guided by the experimental fact that chemical elements cannot be decomposed chemically, was led to formulate his atomic theory. Dalton s atomic theory was based on the assumption that atoms are tiny indivisible entities, with each chemical element consisting of its own characteristic atoms.  [Pg.78]

Unless otherwise noted, all art on this page is C Cengage Learning 2014 [Pg.268]

The mass of this particle, called the electron, had to be less than one-thousandth of that of a hydrogen atom (whose mass was known). But this indicated that some particles of matter are smaller than atoms, an idea that was supposedly precluded by the modern atomic theory. Obviously, this negatively charged particle was only a piece of an atom. The implication was that atoms were not indivisible. [Pg.269]

Although the nuclear atom fit the dramatic results of the experiment, there was a major problem According to Maxwell s electromagnetic theory, such an atom shouldn t be stable. (The equations of electrodynamics summarized by [Pg.269]

FIGURE 9.7 Sir Joseph John Thomson (1856 1940). Thomson is usually credited as the discoverer of the electron, although many people contributed to its identification as a basic building block of matter. Seven of his research assistants, who were also heavily involved in understanding the structure of matter, would eventually win Nobel Prizes. [Pg.269]

Current chemical concepts are essentially based on the fact that matter is fundamentally constituted by nucleus and electrons and that such systems follow the laws of quantum mechanics. [Pg.1]

According to quantum mechanics, any system as an atom or a molecule is described by a function of both the coordinates of the particles constituting the system and the time. They are normally referred to as wave functions, ij/, because of their mathematical expressions which correspond to those traditionally used for describing undulatory processes. itself does not have physical meaning, it is only a mathematical function that can also have negative value or be an [Pg.1]

A particular case specially interesting for chemists are the functions dealing with stationary states, i.e. states that are stable in time and not changing spontaneously without external influence. In these cases the functions are state functions. [Pg.2]

The Schrodinger equation is a fundamental relationship-analogous to the Newton equation in classical mechanics-to be applied in the description of quantum systems as the atomic ones. [Pg.2]

to have only one value in each and every point, [Pg.2]

Atoms are composed of protons, neutrons, and electrons. The protons and neutrons reside in the highly dense nucleus around which the electrons orbit The nucleus is of the order of a few femtometers in diameter with the associated protons and neutrons being 1.7 fm in diameter. The size of the atom, on the other hand, can range from 62 pm (for Helium) to 520 pm (for Cesium). [Pg.23]

The structure of the atom was revealed in 1911 as a result of Ernst Rutherford s interpretation of the 1909 Geiger-Marsden experiment (Rutherford 1911). [Pg.23]

Secondary Ion Mass Spectrometry An Introduction to Principles and Practices, First Edition. Paul van der Heide. [Pg.23]

Rutherford is also generally credited for the discovery of the proton (Rutherford 1919) even though first recorded by Wilhelm Wien. The neutron was discovered much later by Chadwick (Chadwick 1932). The electron was discovered by J.J. Thompson in 1897 (Thomson 1897). Interestingly, Chadwick was the student of Rutherford and Geiger, whereas Rutherford was a student of J.J. Thompson. [Pg.24]

Free atoms prefer to exist in the neutral (zero charge) state. This results when the number of protons equals the number of electrons within the atom. Note Protons have a unit charge of+1, whereas electrons have a unit charge of -1 (neutrons have no charge). The number of protons within the nucleus of an atom is described by the atom s atomic number (Z). This number appears in the periodic table above the elements symbol (see Appendix A.l). The sum of protons and neutrons within the nucleus of a specific atom, or more specifically, that for a specific isotope of an element is defined by the atomic mass number (A), which is also referred to as the mass number. [Pg.24]

The Ford circles that represent the Farey sequence of order 4 represent the periodic table of the elements in complete detail. In particular, they predict the appearance of electron shells with n = 1,6, consisting of 2, 8, 8, 18, 18 and 32 electrons, in this order. [Pg.14]

The news about recalls of toys or products because of the presence of excessive lead is unfortunately very common. The U.S. Consumer Product Safety Commission in charge of protecting the public from um-easonable risks of injury or death from thousands of types of consumer products continues to issue recalls due to the presence of lead in various items. Besides the presence of lead in many painted toys, children s sports, bibs, and furniture products, and jewelry, the newest scare was generated when more than a few dozen handbags from popular retailers were tested for lead levels ranging from nearly three times to more than 195 times higher than the level agreed to in a 2010 settlement between Center for Environmental Health and dozens of retailers, producers and distributors of the products.  [Pg.77]

While lead amounts are limited by federal law in children s products, no federal standard exists for lead in adult handbags, purses, and wallets. Health problems linked to lead exposure encompass an increased risk of heart attacks, strokes, and high blood pressure, among other health problems. However, as of June 2012, there is no safe level of lead exposure, especially for pregnant women and young children. [Pg.77]

The reactivity and chemical properties of the elements are highly dependent on the atomic structure. The atom is comprised of two major components  [Pg.77]

The nucleus, which contains most of the mass of the atom and is made predominantly of two types of snbparticles  [Pg.77]

The space around the nucleus containing electrons, which are negatively charged particles with very low mass that orbit in a cloud surrounding the nucleus. Since an atom must be electronically neutral the number of electrons exactly matches the number of protons. [Pg.78]


These effects were recorded in Greece around 2500 years ago and not long afterwards Democritus proposed an atomic structure for all matter. The magnetic compass seems to have taken another 1500 years to appear and magnetic theory a further half century. [Pg.270]

For many studies of single-crystal surfaces, it is sufficient to consider the surface as consisting of a single domain of a unifonn, well ordered atomic structure based on a particular low-Miller-mdex orientation. However, real materials are not so flawless. It is therefore usefril to consider how real surfaces differ from the ideal case, so that the behaviour that is intrinsic to a single domain of the well ordered orientation can be distinguished from tliat caused by defects. [Pg.285]

Much surface work is concerned with the local atomic structure associated with a single domain. Some surfaces are essentially bulk-temiinated, i.e. the atomic positions are basically unchanged from those of the bulk as if the atomic bonds in the crystal were simply cut. More coimnon, however, are deviations from the bulk atomic structure. These structural adjustments can be classified as either relaxations or reconstructions. To illustrate the various classifications of surface structures, figure A1.7.3(a ) shows a side-view of a bulk-temiinated surface, figure A1.7.3(b) shows an oscillatory relaxation and figure A1.7.3(c) shows a reconstructed surface. [Pg.287]

Most metal surfaces have the same atomic structure as in the bulk, except that the interlayer spaciugs of the outenuost few atomic layers differ from the bulk values. In other words, entire atomic layers are shifted as a whole in a direction perpendicular to the surface. This is called relaxation, and it can be either inward or outward. Relaxation is usually reported as a percentage of the value of the bulk interlayer spacing. Relaxation does not affect the two-dimensional surface unit cell synuuetry, so surfaces that are purely relaxed have (1 x 1) synuuetry. [Pg.288]

The three-dimensional synnnetry that is present in the bulk of a crystalline solid is abruptly lost at the surface. In order to minimize the surface energy, the themiodynamically stable surface atomic structures of many materials differ considerably from the structure of the bulk. These materials are still crystalline at the surface, in that one can define a two-dimensional surface unit cell parallel to the surface, but the atomic positions in the unit cell differ from those of the bulk structure. Such a change in the local structure at the surface is called a reconstruction. [Pg.289]

At a surface, not only can the atomic structure differ from the bulk, but electronic energy levels are present that do not exist in the bulk band structure. These are referred to as surface states . If the states are occupied, they can easily be measured with photoelectron spectroscopy (described in section A 1.7.5.1 and section Bl.25.2). If the states are unoccupied, a teclmique such as inverse photoemission or x-ray absorption is required [22, 23]. Also, note that STM has been used to measure surface states by monitoring the tunnelling current as a fiinction of the bias voltage [24] (see section BT20). This is sometimes called scamiing tuimelling spectroscopy (STS). [Pg.293]

Certain materials, most notably semiconductors, can be mechanically cleaved along a low-mdex crystal plane in situ in a UFIV chamber to produce an ordered surface without contamination. This is done using a sharp blade to slice tire sample along its preferred cleavage direction. For example. Si cleaves along the (111) plane, while III-V semiconductors cleave along the (110) plane. Note that the atomic structure of a cleaved surface is not necessarily the same as that of the same crystal face following treatment by IBA. [Pg.304]

AFM measures the spatial distribution of the forces between an ultrafme tip and the sample. This distribution of these forces is also highly correlated with the atomic structure. STM is able to image many semiconductor and metal surfaces with atomic resolution. AFM is necessary for insulating materials, however, as electron conduction is required for STM in order to achieve tiumelling. Note that there are many modes of operation for these instruments, and many variations in use. In addition, there are other types of scaiming probe microscopies under development. [Pg.310]

Herzberg G 1937 Atomic Spectra and Atomic Structure (New York Prentice-Hall)... [Pg.1149]

Figure Bl.19.14. A sequence of STM images taken during tire construction of a patterned array of xenon atoms on a Ni(lOO) surface. Grey scale is assigned according to the slope of the surface. The atomic structure of the nickel surface is not resolved. Each letter is 5 mn from top to bottom. (Taken from [ ], figure 1.)... Figure Bl.19.14. A sequence of STM images taken during tire construction of a patterned array of xenon atoms on a Ni(lOO) surface. Grey scale is assigned according to the slope of the surface. The atomic structure of the nickel surface is not resolved. Each letter is 5 mn from top to bottom. (Taken from [ ], figure 1.)...
Magnussen O M, Hotios J, Beitei G, Koib D M and Behm R J 1991 Atomic structure of ordered copper adiayers on singie-crystaiiine goid eiectrodes J. Vac. Sc/. Technol. B 9 969... [Pg.1723]

Hegenbart G and Mussig Th 1992 Atomic force microscopy studies of atomic structures on AgBr(111) surfaces Surf. Sc/. Lett. 275 L655... [Pg.1726]

The atomic structure of a surface is usually not a simple tennination of the bulk structure. A classification exists based on the relation of surface to bulk stnicture. A bulk truncated surface has a structure identical to that of the bulk. A relaxed surface has the synnnetry of the bulk stnicture but different interatomic spacings. With respect to the first and second layers, lateral relaxation refers to shifts in layer registry and vertical relaxation refers to shifts in layer spacings. A reconstructed surface has a synnnetry different from that of the bulk synnnetry. The methods of stnictural analysis will be delineated below. [Pg.1813]

Aono M and Souda R 1985 Quantitative surface atomic structure analysis by low energy ion scattering spectroscopy Japan. J. Appl. Phys. Part 1 24 1249-62... [Pg.1825]

Koinuma M and Uosaki K 1996 Atomic structure of bare p-GaAs(IOO) and electrodeposited Cu on p-GaAs (100) surfaces in H2SO4 solutions An AFM study J. Eiectroanai. Chem. 409 45-50... [Pg.2759]

What are the principal differences in physical and chemical properties between any one metal from Group I and any one metal from Group IV and any one transition metal How far can you explain these differences in terms of their different atomic structures ... [Pg.61]

Fig. 1. Structure adapted hierarchical description of Coulomb interactions in biological macromolecules. Filled circles (level 0) represent atoms, structural units (li vel 1) are surrounded by a single-line border, and clusters (level 2) are surrounded by a double-line border. Fig. 1. Structure adapted hierarchical description of Coulomb interactions in biological macromolecules. Filled circles (level 0) represent atoms, structural units (li vel 1) are surrounded by a single-line border, and clusters (level 2) are surrounded by a double-line border.
Many molecules are obtained and used in a crystalline form, the nature of which can have e significant impact on their properties and behaviour. Moreover, it is sometimes possible foi a given material to exist in more than one crystalline form, depending upon the conditions under which it was prepared. This is the phenomenon of polymorphism. This can be important because the various polymorphs may themselves have different properties. It is Iberefore of interest to be able to predict the three-dimensional atomic structure(s) that a gi en molecule may adopt, for those cases where it is difficult to obtain experimental data and also where one might wish to prioritise molecules not yet synthesised. [Pg.517]

Birktoft J J and D M Blow 1972. The structure of Crystalline Alpha-Chymotrypsin V. The Atomic Structure of Tosyl-Alpha-Qiymotrypsin at 2 Angstroms Resolution. Journal of Molecular Biology 68 187-240. [Pg.574]

The Hydrogenic atom problem forms the basis of much of our thinking about atomic structure. To solve the corresponding Schrodinger equation requires separation of the r, 0, and (j) variables... [Pg.25]

The development of the structural theory of the atom was the result of advances made by physics. In the 1920s, the physical chemist Langmuir (Nobel Prize in chemistry 1932) wrote, The problem of the structure of atoms has been attacked mainly by physicists who have given little consideration to the chemical properties which must be explained by a theory of atomic structure. The vast store of knowledge of chemical properties and relationship, such as summarized by the Periodic Table, should serve as a better foundation for a theory of atomic structure than the relativity meager experimental data along purely physical lines. ... [Pg.33]

Th ere are sim ilar expression s for sym m etry related in tegrals (sslyy), etc. For direct comparison with CNDO, F is computed as in CNDO. The other INDO parameters, and F, are generally obtained [J. I. Slater, Quantum Theory of Atomic Structure, McGraw-Hill Book Company, Vol. 1, New York, I960.] from fits to experimental atomic energy levels, although other sources for these Slater-Con don parameters are available. The parameter file CINDO.ABP contains the values of G and F (columns 9 and 10) in addition to the CNDO parameters. [Pg.279]

A representation of atomic structure. The various spheres are not drawn to scale. The lump of iron on the left would contain almost a million million million million (10 ) atoms, one of which is represented by the sphere in the top center of the page. In turn, each atom is composed of a number of electrons, protons, and neutrons. For example, an atom of the element iron contains 26 electrons, 26 protons, and 30 neutrons. The physical size of the atom is determined mainly by the number of electrons, but almost all of its mass is determined by the number of protons and neutrons in its dense core or nucleus (lower part of figure). The electrons are spread out around the nucleus, and their number determines atomic size but the protons and neutrons compose a very dense, small core, and their number determines atomic mass. [Pg.336]

Coulson, C. A. and McWeeney, R. (1979) Coulson s Valence, Oxford University Press, Oxford. Herzberg, G. (1944) Atomic Spectra and Atomic Structure, Dover, New York. [Pg.288]

Processes in which solids play a rate-determining role have as their principal kinetic factors the existence of chemical potential gradients, and diffusive mass and heat transfer in materials with rigid structures. The atomic structures of the phases involved in any process and their thermodynamic stabilities have important effects on drese properties, since they result from tire distribution of electrons and ions during tire process. In metallic phases it is the diffusive and thermal capacities of the ion cores which are prevalent, the electrons determining the thermal conduction, whereas it is the ionic charge and the valencies of tire species involved in iron-metallic systems which are important in the diffusive and the electronic behaviour of these solids, especially in the case of variable valency ions, while the ions determine the rate of heat conduction. [Pg.148]

Kabsch, W., et al. Atomic structure of the actin DNAse I complex. Nature 347 37-44, 1990. [Pg.119]


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