Importance, reasons for

An important reason for low coordination of iodide ions is that high coordination implies a high oxidation state of the central atom, which often (but not always) means high oxidising power— and this means oxidation of the easily oxidised iodide ligands. Thus the nonexistence of, for example, phosphorus(V) pentaiodide is to be explained by the oxidation of the iodide ligands and reduction of phosphorus to the -(-3 state, giving only PI3, not PI5. 

In spite of its deficiencies, the Mulliken population scheme is very popular. One reason is that it is very easy to implement so it is available in many software packages. Probably the most important reason for its popularity is the fact... 

An important reason for the ongoing interest in these copolymers is that vinyl acetate reduces hydrophilidty so that appHcations that require less moisture-sensitive films such as those employed to set hair are less prone to plasticize and become tacky under high humidity conditions (139) (Fig. 5). 

Once the control system is in place, its operation and maintenance become a major concern. Important reasons for an operation and maintenance (O M) program (2) are (1) the necessity of continuously meeting emission regulations, (2) prolonging control equipment life, (3) maintaining produc-... 

Chronic Pulmonary Toxicity Chronic damage to the lungs may be due to several subsequent exposures or due to one large dose that markedly exceeds the capacity of pulmonary defense, clearance, and repair mechanisms. Chronic pulmonary toxicity includes emphysema, chronic bronchitis, asthma, lung fibrosis, and lung cancer. The single most important reason for chronic pulmonary toxicity is tobacco smoke, which induces all types of chronic pulmonary toxicity, with the exception of fibrosis. 

Interestingly enough, both protons at C-11 are exchanged quite readily in 12-keto steroids. In these compounds C-11 is the only possible enolization site where the axial (/3) proton is probably expelled first. During ketonization, the deuteron attack is more likely to occur from the less hindered a-side. By this sequence the proton which was originally at the lla-equato-rial position becomes axial and readily available for expulsion in the next enolization step. Thus, isomerization of the C-11 hydrogens may be an important reason for the facile exchange at this position. (For a more detailed discussion of the mechanism of enolization and ketonization reactions, see ref 114.)... 

There are several important reasons for protein subunits to associate in oligomeric structures. 

In this book we have decided to concentrate on purely synthetic applications of ionic liquids, just to keep the amount of material to a manageable level. FFowever, we think that synthetic and non-synthetic applications (and the people doing research in these areas) should not be treated separately for a number of reasons. Each area can profit from developments made in the other field, especially concerning the availability of physicochemical data and practical experience of development of technical processes using ionic liquids. In fact, in all production-scale chemical reactions some typically non-synthetic aspects (such as the heat capacity of the ionic liquid or product extraction from the ionic catalyst layer) have to be considered anyway. The most important reason for close collaboration by synthetic and non-synthetic scientists in the field of ionic liquid research is, however, the fact that in both areas an increase in the understanding of the ionic liquid material is the key factor for successful future development. 

One of the most important reasons for using tosylates in S j2 reactions is stereochemical. The S]s]2 reaction of an alcohol via an alkyl halide proceeds with hvo inversions of configuration—one to make the halide from the alcohol and one to substitute the halide—and yields a product with the same stereochemistry as the starting alcohol. The SN2 reaction of an alcohol via a tosylate, however, proceeds with only one inversion and yields a product of opposite stereochemistry to the starting alcohol. Figure 17.5 shows a series of reactions on the R enantiomer of 2-octanol that illustrates these stereochemical relationships. 

One of the most important reasons for man s progress in understanding and controlling his environment is his ability to communicate knowledge to the next generation. It isn t necessary for each twentieth century scientist to invent the atomic description of matter. This was invented by John Dalton in the nineteenth century, and Dalton recorded his ideas in the scientific literature together with the observations that led him to the model. By study of this and subsequent literature a modern scientist can appraise the nature of the description, the facts it will explain, and the limitations. He is quickly able to approach the frontiers of knowledge—the frontiers defined by the limitations in our accepted models of the behavior of matter. 

The problem of low specific surface (which, however, has a beneficial effect on the corrosion rate) cannot be solved so easily. This was one important reason for the development of the alkaline Mn02 / zinc cell known as "alkaline" or "PAM" (primary alkaline manganese dioxide). 

Fabrication techniques, especially the preparation of thin films of functional materials, have made major progress in recent years. Thin-film solid electrolytes in the range of several nanometers up to several micrometers have been prepared successfully. The most important reason for the development of thin-film electrolytes is the reduction in the ionic resistance, but there is also the advantage of the formation of amorphous materials with stoichiometries which cannot be achieved by conventional techniques of forming crystalline compounds. It has often been observed that thin-film electrolytes produced by vacuum evaporation or sputtering provide a struc-... 

An alternative approach to the representation of results for solid-liquid flow is to use the two-layer model which will be described in the following section. It will be seen that the coefficient of friction between the particles and the wall of the pipe is an important parameter in the model. It is suggested that its complete absence in equation 5.24 may be an important reason for the extent of the scatter. Unfortunately, it is a quantity which has been measured in only a very few investigations. It is interesting to note that the form of equation 5.19 was obtained by NEWITT et alP2) using a force balance similar to that... 

The important reason for the quasi-steady-state approach arises from the difficulty in obtaining a solution to the transient convection problem for two-phase situations. 

The synthesis of poly(organophosphazenes), POPs, is a research area that has involved a lot of effort in the past by many scientists active in the phosphazene domain. There are several important reasons for this, basically related to the high cost of the starting products [44] used to prepare POPs, to difficulties in carefully controlling the reactions involved in the preparative processes [38] and to the need for accurately predicting both molecular weight and molecular weight distribution of the POPs produced [38,45]. 

One important reason for the emergence of Paracelsian alchemical illustration may have been its function as a psychological compensation for the rejection of Catholic imagery by the Protestants and the resulting spiritual and emotional insecurity experienced by many of the faithful. It is not merely coincidental that Paracelsian iconography should appear in Protestant areas where traditional Catholic icons had been destroyed. (The development of a specihcally Catholic interest in alchemy, however, was a phenomenon of the mid-seventeenth century developed in the work of Athanasius Kircher and other Jesuits.) ... 

An important reason for this lack of experimental work is that the zeta-potential cannot be easily determined independent of the electrophoretic mobility [284] however, in the case of proteins (as well as some other charged colloids), the intrinsic charge obtained by titration is a parameter that can be measured independent of the electrophoretic mobility. The charge obtained from electrophoretic measurements (i.e., the net charge) via the preceding theories is generally not the same as the charge obtained from titration (i.e., the in-... 

There are a number of important reasons for discussing the reactions of organic compounds in the troposphere ... 

The most important reasons for applying process control are as follows ... 

Tea , in this work, refers only to the plant Camellia sinensis, its leaves, and the extracts and infusions thereof. Leaf, bark, stem, root, or flower extracts of scores of other plants are also sold as teas , creating confusion. An important reason for the consumption of these other teas , a.k.a. herbal teas or tisanes , is their lack of methylxanthines, unlike beverages prepared from Camellia sinensis which are naturally rich in these substances, especially caffeine. 

---