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ACRYLAMIDE COPOLYMER

Acrylamide copolymers are effective iron ore pellet binders (118). When the ore slurry in water has a pH above 8, anionic polymers are effective. If the ore is acid washed to remove manganese, then a cationic polymer is effective. [Pg.143]

Fig. 1. Functional monomers used in acrylamide copolymers. Methacrylamidopropyltrim ethyl ammonium chloride [51410-72-1] (1), acryloyloxyethyltrimethylammonium chioride [44992-01-0] (2), methacryloyloxyethyltrimethylammonium chloride [50339-78-1] (3), /V,/V-dimethy1aminoethy1 methacrylate [2867-47-2] (4), /V,/V-dimethylaminopropy1 acryl amide [3845-76-9] (5), diallyl dimethyl amm onium chloride... Fig. 1. Functional monomers used in acrylamide copolymers. Methacrylamidopropyltrim ethyl ammonium chloride [51410-72-1] (1), acryloyloxyethyltrimethylammonium chioride [44992-01-0] (2), methacryloyloxyethyltrimethylammonium chloride [50339-78-1] (3), /V,/V-dimethy1aminoethy1 methacrylate [2867-47-2] (4), /V,/V-dimethylaminopropy1 acryl amide [3845-76-9] (5), diallyl dimethyl amm onium chloride...
Many synthetic latices exist (7,8) (see Elastomers, synthetic). They contain butadiene and styrene copolymers (elastomeric), styrene—butadiene copolymers (resinous), butadiene and acrylonitrile copolymers, butadiene with styrene and acrylonitrile, chloroprene copolymers, methacrylate and acrylate ester copolymers, vinyl acetate copolymers, vinyl and vinyUdene chloride copolymers, ethylene copolymers, fluorinated copolymers, acrylamide copolymers, styrene—acrolein copolymers, and pyrrole and pyrrole copolymers. Many of these latices also have carboxylated versions. [Pg.23]

The most commonly used polymers are partially hydrolyzed polyacrylamides (32). The optimum degree of hydrolysis depends on the apphcation, injection water composition, and reservoir conditions (33,34). More salt-tolerant acrylamide copolymers may permit this technology in higher salinity injection water (35). Eield apphcations of cross-linked xanthan gum have also been reported (36). [Pg.190]

Organic cross-linkers, which include glyoxal (48) and formaldehyde (qv), have also been used. Use of hypohaUte salts (49) and epichlorohydrin (50) promotes gel stabiUty. Phenol—formaldehyde cross-linking systems have been used to produce stable acrylamide copolymer gels at temperatures above 75°C and brine hardness levels above 2000 ppm (51). [Pg.190]

Acrylamide copolymers designed to reduce undesired amide group hydrolysis, increase thermal stability, and improve solubility in saline media have been studied for EOR appHcations (121—128). These polymers stiH tend to be shear sensitive. Most copolymers evaluated for EOR have been random copolymers. However, block copolymers of acrylamide and AMPS also have utiHty (129). [Pg.192]

Acrylamide graft copolymers such as those with starch (qv)(131), dextran (132), and lignin (qv) (133), have been studied to try to reduce copolymer costs. A general disadvantage of acrylamide copolymers is greater cost compared to partially hydroly2ed polyacrylamides. [Pg.192]

Uenoyama, S and Hoffman AS. Synthesis and characterization of acrylamide-N-isopropyl acrylamide copolymer grafts on silicone rubber substrates. Radiat. Phys. Chem., 1988, 32, 605-608. [Pg.254]

Acrylamide copolymer, polypropylene glycol (water-based mud) [1409]... [Pg.5]

High fluid injection rates are often required. For this reason, friction reducers are often used in acid fracturing. These include polyacrylamide and acrylamide copolymers, guar gum, hydroxyethyl cellulose, and karaya gum (108)... [Pg.21]

Organic polymers have been used to increase the viscosity of acids. The primary application is in fracture acidizing. Binary and ternary acrylamide copolymers are the most commonly used chemicals for this application. Many of these polymers degrade rapidly in strong acids at temperatures >130 F development of more stable polymers suitable for high temperatures is desirable. Recently developed polymers for this application include acrylamide copolymers with ... [Pg.21]

Acrylamide copolymers designed to reduce undesired amide group hydrolysis, increase thermal stability, and improve solubility in saline media have been synthesized and studied for EOR applications. These polymers still tend to be shear sensitive. Acrylamide comonomers that have been used include 2-acrylamido-2-methylpropane sulfonate, abbreviated AMPS, (1,321-324), 2-sulfo-ethylmethacrylate (325,326), diacetone acrylamide (324, 326), and vinylpyrrolidinone (327,328). Acrylamide terpolymers include those with sodium acrylate and acrylamido-N-dodecyl-N-butyl sulfonate (329), with AMPS and N,N-dimethylacrylamide (330), with AMPS and N-vinylpyrrolidinone (331), and with sodium acrylate and sodium methacrylate (332). While most copolymers tested have been random copolymers, block copolymers of acrylamide and AMPS also have utility in this application (333). [Pg.37]

The hydrolysis of acrylamide copolymers in dilute alkaline conditions for long periods at high temperatures up to 120°C, as found in harsh reservoirs, has not been extensively studied. [Pg.108]

The rate of hydrolysis of acrylamide in copolymers with sodium acrylate or AMPS, 2-acrylamido-2-methylpropanesulfonic acid, decreased as the proportion of the anionic comonomers was increased. This effect was much more marked with AMPS than with sodium acrylate, and occurred at 90°, 108°, and 120°C. Typical results at 108°C [Figs. 1 and 2] show the increase in carboxylate content of acrylamide copolymers containing sodium acrylate and AMPS respectively. [Pg.110]

Figure 3. Initial rate constants for hydrolysis of acrylamide copolymers at 90, 108, and 120 °C. Figure 3. Initial rate constants for hydrolysis of acrylamide copolymers at 90, 108, and 120 °C.
Most polymers used in oil field operations and resource recovery are synthetic. The man-made materials in common use are polyO-amidoethylene) ( = polyacrylamide ), poly( 1-amidoethylene-r-( sodium 1-carboxylatoethylene ) ( = partially hydrolyzed polyacrylamide ), poly(l-amidoethylene-r-( sodium 1-(2-methylprop-1N-yl-1-sulfonate)amidoethylene) (AMPS-acrylamide copolymer), and xanthan gum. Xanthan gum is a synthetic because no one finds a pool or river contaminated with Xanthomonas compestris that experiences the right sequence of solute to naturally produce the exocellular gum polymer. A fermenter is a man made object, a tree is not. [Pg.174]

Kallin, E., Lonn, H., Norberg, T., and Elofsson, M. (1989) Derivatization procedures for reducing oligosaccharides, Part 3 Preparation of oligosaccharide glycosylamines, and their conversion into oligosaccharide-acrylamide copolymers./. Carbohydr. Chem. 8, 597-611. [Pg.1080]

Acrylamide-based products, in paper manufacture, 18 115 Acrylamide copolymers, functional monomers used in, 11 628 Acrylamide gels, 1 680 Acrylamide graft copolymers, 18 625 Acrylamide polymers, 1 292, 304-333. [Pg.10]

A similar polymer, composed of osmium complexed with bis-dichlorobipyridine, chloride, and PVI in a PVI—poly(acrylamide) copolymer (Table 2, compound 3), demonstrated a lower redox potential, 0.57 V vs SHE, at 37.5 °C in a nitrogen-saturated buffer, pH 5 109,156 adduct of this polymer with bilirubin oxidase, an oxygen-reducing enzyme, was immobilized on a carbon paper RDE and generated a current density exceeding 9 mA/cm at 4000 rpm in an O2-saturated PBS buffer, pH 7, 37.5 °C. Current decayed at a rate of 10% per day for 6 days on an RDE at 300 rpm. The performance characteristics of electrodes made with this polymer are compared to other reported results in Table 2. [Pg.639]

Adsorption inhibitors act by forming a film on the metal surface. The action of traditional oil-based red lead paint formulations presumably involves the formation of soaps and the precipitation of complex ferric salts that reinforce the oxide film. There has been substantial interest in recent years in development of replacements for lead-based and chromate-based inhibitor systems. Adsorption inhibitors based on pol3rmers have been of particular interest. In this volume, Johnson et al. and Eng and Ishida discuss inhibitors for copper 2-undecylimidazole is shown to be effective in acid media, where it suppresses the oxygen reduction reaction almost completely. Polyvlnyllmidazoles are shown to be effective oxidation inhibitors for copper at elevated temperatures. Also in this volume, Chen discusses the use of N-(hydroxyalkyl)acrylamide copolymers in conjunction with phosphate-orthophosphate inhibitor systems for cooling systems. [Pg.5]

The resulting acrylic acid/N-(hydroxyalky1) acrylamide copolymers were evaluated for their deposit control and dispersant activities as compared to the homopolymer of acrylic acid. Differences in the activities could be attributed to the incorporation of the N-hydroxylalkylacrylamide moiety into the polymer chain. [Pg.283]

After equilibrium, filtration, and pH adjustment, the residual calcium ion concentration was then titrated by EDTA solution. A higher residual calcium ion concentration indicates better inhibition activity and, therefore, more effectiveness in controlling calcium carbonate deposition in the treated water. As shown in Table III, at dosages of 1 to 5 ppm, the polyacrylic acid was more effective than the acrylic acid/N-(hydroxyalkyl)-acrylamide copolymers. [Pg.286]

The a-chymotrypsin-catalyzed hydrolysis of the p-nitroanilide group in acrylamide copolymers with monomer I proceeds with a rate comparable to that of the monomer... [Pg.733]

Brueggemeier, S. B., Wu, D., Kron, S. J., and Palecek, S. P. (2005) Protein-acrylamide copolymer hydrogels for array-based detection of tyrosine kinase activity from cell lysates. Biomacromolecules, 6, 2765-2775. [Pg.225]


See other pages where ACRYLAMIDE COPOLYMER is mentioned: [Pg.753]    [Pg.144]    [Pg.229]    [Pg.68]    [Pg.71]    [Pg.444]    [Pg.455]    [Pg.987]    [Pg.276]    [Pg.37]    [Pg.108]    [Pg.109]    [Pg.113]    [Pg.114]    [Pg.679]    [Pg.96]    [Pg.199]    [Pg.8]    [Pg.642]    [Pg.285]    [Pg.287]    [Pg.289]    [Pg.247]    [Pg.97]    [Pg.12]   
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See also in sourсe #XX -- [ Pg.78 , Pg.80 ]

See also in sourсe #XX -- [ Pg.137 ]




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2-Acrylamide-2-methyl propane-sulfonate copolymer

Acrylamide copolymer plastic

Acrylamide copolymer---emulsion

Acrylamide copolymers preparation

Acrylamide-HEMA copolymers

Acrylamide-starch graft copolymers

Acrylamide-starch graft copolymers applications

Acrylamide-starch graft copolymers production

Acrylamide/DADMAC copolymers

Acrylamide/acrylate copolymers

Acrylamide/acrylic acid copolymer

Block copolymers of acrylamide

Cationic acrylamide copolymer

Copolymers of acrylamide

DIMETHYL ACRYLAMIDE COPOLYMER

Dextran-grafted acrylamide copolymer

Electrolyte acrylamide copolymers

ISOPROPYL ACRYLAMIDE COPOLYMER

Light scattering acrylamide copolymers

Reduced viscosity acrylamide copolymers

Solution DADMAC/acrylamide copolymer

Surfactant acrylamide copolymers

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