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Vinyl acetate ester

Figure 71 compares the 2,000-1,000 cm-1 FTIR spectral region for the heat seal layers of the "good" and "bad" films, and the center opaque polyethylene layer for the "bad" film. Of particular interest is the carbonyl region between approximately 1,800 and 1,650 cm-1. The two heat seal surface spectra show mainly the vinyl acetate ester carbonyl band at 1,740 cm-1. For the middle polyethylene layer of the "bad" film, the shape and position of the carbonyl band is consistent with oxidative degradation of polyethylene. The peak maximum at... [Pg.668]

Vinyl acetate esters of acrylic acid acrylonitrile Acrylonitrile... [Pg.285]

Acetic acid is both a reactant and solvent in the manufacture of cellulose acetate, polyester fibers, and plastics. Other products that utilize acetic acid as a reactant include vinyl acetate, ester solvents, dyes, metallic salts, pharmaceuticals, and pesticides. Formic acid is used in textile dyeing and finishing, leather tanning and treatment, pharmaceuticals, and the synthesis of the versatile methyl formate solvent. n-Butanoic acid is used in the preparation of cellulose acetate butyrates used for lacquers and molding plastic compositions. The acid is also used for the production of useful coating ester solvents, plasticizers, and pharmaceuticals. [Pg.71]

The addition of carboxylic acids to terminal acetylenes is catalysed by a RulCaHii)2/PR3/maleic anhydride mixture and gives (34) as the main product.133 This stereochemistry has been exploited in the synthesis of vinyl acetate esters (scheme 41.134 Mixtures of 1- and 2-enol esters result from PhC=CH and RCOOH in the presence of RuCl 3 or Rudll phosphine complexes.136... [Pg.398]

Poly(vinyl acetals) Esters, ketones. Aliphatic hydrocarbons,... [Pg.247]

Figure 3 shows the production of acetaldehyde in the years 1969 through 1987 as well as an estimate of 1989—1995 production. The year 1969 was a peak year for acetaldehyde with a reported production of 748,000 t. Acetaldehyde production is linked with the demand for acetic acid, acetic anhydride, cellulose acetate, vinyl acetate resins, acetate esters, pentaerythritol, synthetic pyridine derivatives, terephthaHc acid, and peracetic acid. In 1976 acetic acid production represented 60% of the acetaldehyde demand. That demand has diminished as a result of the rising cost of ethylene as feedstock and methanol carbonylation as the preferred route to acetic acid (qv). [Pg.53]

Olefins add anhydrous acetic acid to give esters, usually of secondary or tertiary alcohols propjiene [115-07-1] yields isopropyl acetate [108-21-4], isobutjiene [115-11-7] gives tert-huty acetate [540-88-5]. Minute amounts of water inhibit the reaction. Unsaturated esters can be prepared by a combined oxidative esterification over a platinum group metal catalyst. Eor example, ethylene-air-acetic acid passed over a palladium—Hthium acetate catalyst yields vinyl acetate. [Pg.66]

Catalytic vinylation has been appHed to a wide range of alcohols, phenols, thiols, carboxyUc acids, and certain amines and amides. Vinyl acetate is no longer prepared this way in the United States, although some minor vinyl esters such as stearates may still be prepared this way. However, the manufacture of vinyl-pyrrohdinone and vinyl ethers still depends on acetylene. [Pg.114]

Under conditions of extreme acidity or alkalinity, acryhc ester polymers can be made to hydroly2e to poly(acryhc acid) or an acid salt and the corresponding alcohol. However, acryhc polymers and copolymers have a greater resistance to both acidic and alkaline hydrolysis than competitive poly(vinyl acetate) and vinyl acetate copolymers. Even poly(methyl acrylate), the most readily hydroly2ed polymer of the series, is more resistant to alkah than poly(vinyl acetate) (57). Butyl acrylate copolymers are more hydrolytically stable than ethyl acrylate copolymers (58). [Pg.164]

The combination of durability and clarity and the ability to tailor molecules relatively easily to specific applications have made acryflc esters prime candidates for numerous and diverse applications. At normal temperatures the polyacrylates are soft polymers and therefore tend to find use in applications that require flexibility or extensibility. However, the ease of copolymerizing the softer acrylates with the harder methacrylates, styrene, acrylonitrile, and vinyl acetate, allows the manufacture of products that range from soft mbbers to hard nonfilm-forming polymers. [Pg.171]

Cellulosics. CeUulosic adhesives are obtained by modification of cellulose [9004-34-6] (qv) which comes from cotton linters and wood pulp. Cellulose can be nitrated to provide cellulose nitrate [9004-70-0] which is soluble in organic solvents. When cellulose nitrate is dissolved in amyl acetate [628-63-7] for example, a general purpose solvent-based adhesive which is both waterproof and flexible is formed. Cellulose esterification leads to materials such as cellulose acetate [9004-35-7], which has been used as a pressure-sensitive adhesive tape backing. Cellulose can also be ethoxylated, providing hydroxyethylceUulose which is useful as a thickening agent for poly(vinyl acetate) emulsion adhesives. Etherification leads to materials such as methylceUulose [9004-67-5] which are soluble in water and can be modified with glyceral [56-81-5] to produce adhesives used as wallpaper paste (see Cellulose esters Cellulose ethers). [Pg.234]

Pentaerythritol in rosin ester form is used in hot-melt adhesive formulations, especially ethylene—vinyl acetate (EVA) copolymers, as a tackifier. Polyethers of pentaerythritol or trim ethyl ol eth an e are also used in EVA and polyurethane adhesives, which exhibit excellent bond strength and water resistance. The adhesives maybe available as EVA melts or dispersions (90,91) or as thixotropic, one-package, curable polyurethanes (92). Pentaerythritol spko ortho esters have been used in epoxy resin adhesives (93). The EVA adhesives are especially suitable for cellulose (paper, etc) bonding. [Pg.466]

Heteroatom functionalized terpene resins are also utilized in hot melt adhesive and ink appHcations. Diels-Alder reaction of terpenic dienes or trienes with acrylates, methacrylates, or other a, P-unsaturated esters of polyhydric alcohols has been shown to yield resins with superior pressure sensitive adhesive properties relative to petroleum and unmodified polyterpene resins (107). Limonene—phenol resins, produced by the BF etherate-catalyzed condensation of 1.4—2.0 moles of limonene with 1.0 mole of phenol have been shown to impart improved tack, elongation, and tensile strength to ethylene—vinyl acetate and ethylene—methyl acrylate-based hot melt adhesive systems (108). Terpene polyol ethers have been shown to be particularly effective tackifiers in pressure sensitive adhesive appHcations (109). [Pg.357]

In these equations I is the initiator and I- is the radical intermediate, M is a vinyl monomer, I—M- is an initial monomer radical, I—M M- is a propagating polymer radical, and and are polymer end groups that result from termination by disproportionation. Common vinyl monomers that can be homo-or copolymeri2ed by radical initiation include ethylene, butadiene, styrene, vinyl chloride, vinyl acetate, acrylic and methacrylic acid esters, acrylonitrile, A/-vinylirnida2ole, A/-vinyl-2-pyrrohdinone, and others (2). [Pg.219]

Plasticizers. Monomeric (mol wt 250—450) plasticizers (qv) are predominantiy phthalate, adipate, sebacate, phosphate, or trimeUitate esters. Organic phthalate esters like dioctyl phthalate (DOP) are by far the most common plasticizers in flexible PVC. Phthalates are good general-purpose plasticizers which impart good physical and low temperature properties but lack permanence in hot or extractive service conditions and are therefore sometimes called migratory plasticizers. Polymeric plasticizers (mol wt up to 5000 or more) offer an improvement in nonmigratory permanence at a sacrifice in cost, low temperature properties, and processibiHty examples are ethylene vinyl acetate or nitrile polymers. [Pg.327]

Many synthetic latices exist (7,8) (see Elastomers, synthetic). They contain butadiene and styrene copolymers (elastomeric), styrene—butadiene copolymers (resinous), butadiene and acrylonitrile copolymers, butadiene with styrene and acrylonitrile, chloroprene copolymers, methacrylate and acrylate ester copolymers, vinyl acetate copolymers, vinyl and vinyUdene chloride copolymers, ethylene copolymers, fluorinated copolymers, acrylamide copolymers, styrene—acrolein copolymers, and pyrrole and pyrrole copolymers. Many of these latices also have carboxylated versions. [Pg.23]

Almost all synthetic binders are prepared by an emulsion polymerization process and are suppHed as latexes which consist of 48—52 wt % polymer dispersed in water (101). The largest-volume binder is styrene—butadiene copolymer [9003-55-8] (SBR) latex. Most SBRlatexes are carboxylated, ie, they contain copolymerized acidic monomers. Other latex binders are based on poly(vinyl acetate) [9003-20-7] and on polymers of acrylate esters. Poly(vinyl alcohol) is a water-soluble, synthetic biader which is prepared by the hydrolysis of poly(viayl acetate) (see Latex technology Vinyl polymers). [Pg.22]

The principal use of the peroxodisulfate salts is as initiators (qv) for olefin polymerisation in aqueous systems, particularly for the manufacture of polyacrylonitrile and its copolymers (see Acrylonitrile polymers). These salts are used in the emulsion polymerisation of vinyl chloride, styrene—butadiene, vinyl acetate, neoprene, and acryhc esters (see Acrylic ester polymers Styrene Vinyl polymers). [Pg.96]

Organic peroxides are used in the polymer industry as thermal sources of free radicals. They are used primarily to initiate the polymerisation and copolymerisation of vinyl and diene monomers, eg, ethylene, vinyl chloride, styrene, acryUc acid and esters, methacrylic acid and esters, vinyl acetate, acrylonitrile, and butadiene (see Initiators). They ate also used to cute or cross-link resins, eg, unsaturated polyester—styrene blends, thermoplastics such as polyethylene, elastomers such as ethylene—propylene copolymers and terpolymers and ethylene—vinyl acetate copolymer, and mbbets such as siUcone mbbet and styrene-butadiene mbbet. [Pg.135]

Carbon Cha.in Backbone Polymers. These polymers may be represented by (4) and considered derivatives of polyethylene, where n is the degree of polymeriza tion and R is (an alkyl group or) a functional group hydrogen (polyethylene), methyl (polypropylene), carboxyl (poly(acryhc acid)), chlorine (poly(vinyl chloride)), phenyl (polystyrene) hydroxyl (poly(vinyl alcohol)), ester (poly(vinyl acetate)), nitrile (polyacrylonitrile), vinyl (polybutadiene), etc. The functional groups and the molecular weight of the polymers, control thek properties which vary in hydrophobicity, solubiUty characteristics, glass-transition temperature, and crystallinity. [Pg.478]

Tables 7 and 8 give properties of some diaHyl esters. DimethaHyl phthalate [5085-00-7] has been copolymerized with vinyl acetate and benzoyl peroxide, and reactivity ratios have been reported (75). Tables 7 and 8 give properties of some diaHyl esters. DimethaHyl phthalate [5085-00-7] has been copolymerized with vinyl acetate and benzoyl peroxide, and reactivity ratios have been reported (75).
In studies of the polymerization kinetics of triaUyl citrate [6299-73-6] the cyclization constant was found to be intermediate between that of diaUyl succinate and DAP (86). Copolymerization reactivity ratios with vinyl monomers have been reported (87). At 60°C with benzoyl peroxide as initiator, triaUyl citrate retards polymerization of styrene, acrylonitrile, vinyl choloride, and vinyl acetate. Properties of polyfunctional aUyl esters are given in Table 7 some of these esters have sharp odors and cause skin irritation. [Pg.87]

Small amounts of TAIC together with DAP have been used to cure unsaturated polyesters in glass-reinforced thermo sets (131). It has been used with polyfunctional methacrylate esters in anaerobic adhesives (132). TAIC and vinyl acetate are copolymerized in aqueous suspension, and vinyl alcohol copolymer gels are made from the products (133). Electron cure of poly(ethylene terephthalate) moldings containing TAIC improves heat resistance and transparency (134). [Pg.88]

Pubhcations on curing polymers with TAIC include TEE—propylene copolymer (135), TEE—propylene—perfluoroaHyl ether (136), ethylene—chlorotrifluoroethylene copolymers (137), polyethylene (138), ethylene—vinyl acetate copolymers (139), polybutadienes (140), PVC (141), polyamide (142), polyester (143), poly(ethylene terephthalate) (144), sdoxane elastomers (145), maleimide polymers (146), and polyimide esters (147). [Pg.88]

Vinyl acetate [108-05-4] (VAc), CH2=CHOOCCH2, the ethenyl ester of acetic acid, is primarily use for the manufacture of poly(vinyl acetate) [9003-20-7] (PVAc) and vinyl acetate copolymers. Poly(vinyl acetate) homo- and copolymers are found as components in coatings, paints and sealants, binders (adhesives, nonwovens, constmction products, and carpet-backing), and miscellaneous uses such as chewing gum and tablet coatings. AppHcations have grown over the years in a number of areas (1 4). [Pg.458]

Hydrolysis of vinyl acetate is catalyzed by acidic and basic catalysts to form acetic acid and vinyl alcohol which rapidly tautomerizes to acetaldehyde. This rate of hydrolysis of vinyl acetate is 1000 times that of its saturated analogue, ethyl acetate, ia alkaline media (15). The rate of hydrolysis is minimal at pH 4.44 (16). Other chemical reactions which vinyl acetate may undergo are addition across the double bond, transesterification to other vinyl esters, and oxidation (15—21). [Pg.459]

Poly(vinyl alcohol) can be derived from the hydrolysis of a variety of poly(vinyl esters), such as poly(vinyl acetate), poly(vinyl formate), and poly(vinyl ben2oate), and of poly(vinyl ethers). However, all commercially produced poly(vinyl alcohol) is manufactured by the hydrolysis of poly(vinyl acetate). The manufacturing process can be viewed as one segment that deals with the polymeri2ation of vinyl acetate and another that handles the hydrolysis of poly(vinyl acetate) to poly(vinyl alcohol). [Pg.482]

Chemistry. Poly(vinyl acetate) can be converted to poly(vinyl alcohol) by transesterification, hydrolysis, or aminolysis. Industrially, the most important reaction is that of transesterification, where a small amount of acid or base is added in catalytic amounts to promote the ester exchange. [Pg.484]

Commercial Hydrolysis Process. The process of converting poly(vinyl acetate) to poly(vinyl alcohol) on a commercial scale is compHcated on account of the significant physical changes that accompany the conversion. The viscosity of the poly(vinyl acetate) solution increases rapidly as the conversion proceeds, because the resulting poly(vinyl alcohol) is insoluble in the most common solvents used for the polymeri2ation of vinyl acetate. The outcome is the formation of a gel swollen with the resulting acetic acid ester and the alcohol used to effect the transesterification. [Pg.484]


See other pages where Vinyl acetate ester is mentioned: [Pg.98]    [Pg.186]    [Pg.370]    [Pg.482]    [Pg.98]    [Pg.186]    [Pg.370]    [Pg.482]    [Pg.419]    [Pg.420]    [Pg.530]    [Pg.162]    [Pg.171]    [Pg.172]    [Pg.278]    [Pg.363]    [Pg.358]    [Pg.84]    [Pg.202]    [Pg.244]    [Pg.454]    [Pg.461]    [Pg.463]    [Pg.470]    [Pg.484]    [Pg.502]   
See also in sourсe #XX -- [ Pg.145 ]




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