Reinforcement resin

Reinforcing Resins. Reinforcement and stiffness of a compound can also be achieved with the use of reactive resins. Resins consisting of two-component systems of resorcinol or resorcinol condensation products and a methylene donor such as hexamethoxymethylmel amine (HMMM) or hexamethyltetramine (HMT) are the most popular in tires. These materials can be prereacted and added to the formula, or for more effective results they can react in situ ie, they can be added separately into the formula and react when the tire is vulcanized. 

The resins have wide appHcation. In nonreinforced form they serve as insulating coatings for electrical coils (46—47). As fiber reinforced resins, they can be made by reaction injection mol ding into laminates, castings, and coatings (48—49). Fiber-reinforced resins are used in marine appHcations (recreational boats) automotive parts (50) bathroom countertops and shower stalls and tubs and more recendy as baUistic protection for military vehicles and aircraft. 

The PAI resin is utilized for small, simple parts. Because of its stiff melt flow, the resin is available in compression moldable powder. Grades include neat, filled, and glass-reinforced resins it is also available in solution for use as an enamel. Because of high prices ( 33—44/kg) the market is limited, estimated at 150—300 tons for the mol ding resin. Resins competing with PAI include PEI, polyethersulfones, and thermoset resins. 

Epoxy resin has a higher strength at elevated temperatures than polyester resins but is not as resistant to attack by some fluids. Some glass-reinforced epoxy-resin pipe is made with a polyester-resin hner. The coefficient of thermal expansion of glass-reinforced resin pipe is higher than that for carbon steel but mu less than that for plastics. 

Glass-reinforced polyester is the most widely used reinforced-resin system. A wide choice of polyester resins is available. The bisphenol resins resist strong acids as well as alkahne solutions. The size range is 2 through 12 in the temperature range is shown in Table 10-17. Diameters are not standardized. Adhesive-cemented socket joints and hand-lay-up reinforced butt joints are used. For the latter, reinforcement consists of layers of glass cloth saturated with adhesive cement. 

Distillation trays constiircted of porous catalyticaUy active material and reinforcing resins Method described for removing or replacing catalyst on trays as a hquid slurry Catalyst bed placed in downcomer, designed to prevent vapor None specified Wang et al., Chinese Patent 1,060,228 (1992) Jones, U.S. Patent, 5,1.3.3,942 (1992)... 

Some rubber base adhesives need vulcanization to produce adequate ultimate strength. The adhesion is mainly due to chemical interactions at the interface. Other rubber base adhesives (contact adhesives) do not necessarily need vulcanization but rather adequate formulation to produce adhesive joints, mainly with porous substrates. In this case, the mechanism of diffusion dominates their adhesion properties. Consequently, the properties of the elastomeric adhesives depend on both the variety of intrinsic properties in natural and synthetic elastomers, and the modifying additives which may be incorporated into the adhesive formulation (tackifiers, reinforcing resins, fillers, plasticizers, curing agents, etc.). 

R. G. Weatherhead, Fibre Reinforced Resin System, FRP Technology, Applied Sciences, London (1980). 

Typical Properties of Glass-Fiber-Reinforced Resins [10]... 

Face-seal materials can be chosen from filled, molded or reinforced resins with which water, hydraulic fluids, mineral oils or synthetic oils are all compatible. Their maximum temperature in service depends on the brittle point of the resin but, generally, the range is from —50°C to 100°C (122°F to 212°F). Abrasion resistance is generally good but, as far as possible, resins are not used in the presence of foreign solids. 

The above model has been successfully used to describe the thermomechanical behaviour of iron-particle reinforced resins. More precisely, the importance of this model is that it provides a quantitative means for assessing the adhesion efficiency between the phases and its effect on the thermomechanical properties of the composite. Moreover, by using this model the thermomechanical behaviour, as well as the extent of the mesophase developed in particulates could be described. The... 

Kevlar fibers are supplied by DuPont as Kevlar-29 and 49. The former is characterized by high tensile strength and the latter by high initial modulus(4). Some Kevlar-29 end uses are in ropes and cables, which are as strong as steel at one-fifth the weight, and in ballistic vests. Some Kevlar-49 end uses are in reinforcing resins and composites for aerospace structures, boat hulls, and sport equipments. 

Heat-bonding process Glass fiber mat is embedded into the exterior surface of the pipe liner. This serves as an adhesion key for the reinforcement resin. This is an expensive process owing to the necessity for strict control over the surface fusion process. 

Adhesive Performance of Surface-Activated Polyolefin Surfaces with Respect to Reinforcement Resins... 

The lap shear test involves measuring the adhesive shear strength between two surface fluorinated polyolefin sheet tokens that are adhesively secured with a reinforcement resin. The tokens are individually reinforced with steel backing plates to eliminate flexural distortion in the shear joint. Lap shear tests carried out with various reinforcing polyester-type resins, contrasting fluorination and oxyfluorination as surface treatment, are shown in Table 16.8. 

ISO 3597-2 2003 Textile-glass-reinforced plastics - Determination of mechanical properties on rods made of roving-reinforced resin - Part 2 Determination of flexural strength ISO 5893 2002 Rubber and plastics test equipment - Tensile, flexural and compression types (constant rate of traverse) - Specification ISO 6721-3 1995 Plastics - Determination of dynamic mechanical properties - Part 3 Flexural vibration - Resonance-curve method... 

ISO 3597-4 2003 Textile-glass-reinforced plastics - Determination of mechanical properties on rods made of roving-reinforced resin - Part 4 Determination of apparent interlaminar... 

Short glass fibre reinforcement the main thermoplastics are offered in such grades. Some short carbon or aramid fibre reinforced resins are also marketed. 

Table 6.13 displays the strength and modulus of a 60% glass fibre reinforced resin for various fibre forms. The properties are roughly ... 

Table 6.13 Examples of properties for a 60% glass fibre reinforced resin according to tbe fibre forms...

In a sandwich structure, the foam is used as the core with two skins of reinforced resin sheets firmly stuck on the foam to obtain high rigidity. The sandwich composite behaves as an I-beam see Figure 6.11. 

Activation of the surface by fluorination for adhesion with the reinforcement resin This is a cost-effective mass production technology, which... 

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