Intrinsic properties

We will reserve the word additive for substances, or mixtures of substances, capable of noticeably improving at least one property of the product in question, without altering the other intrinsic properties. 

This distinction between the characteristic eigenstates of the system with their intrinsic properties and the act of preparing the system in some state that may be a superposition of these eigenstates is essential to keep in mind when applying quantum mechanics to experimental observations. 

The lines of primary interest ia an xps spectmm ate those reflecting photoelectrons from cote electron energy levels of the surface atoms. These ate labeled ia Figure 8 for the Ag 3, 3p, and 3t7 electrons. The sensitivity of xps toward certain elements, and hence the surface sensitivity attainable for these elements, is dependent upon intrinsic properties of the photoelectron lines observed. The parameter governing the relative iatensities of these cote level peaks is the photoionization cross-section, (. This parameter describes the relative efficiency of the photoionization process for each cote electron as a function of element atomic number. Obviously, the photoionization efficiency is not the same for electrons from the same cote level of all elements. This difference results ia variable surface sensitivity for elements even though the same cote level electrons may be monitored. 

The intrinsic properties may be modified by substitution (31). Ba can be fuUy replaced by Sr or Pb and partly by Ca (<40 mol %). CaM, stabilized with 0.03 mol % La202, is also possible. The intrinsic properties of these M-ferrites vary somewhat and other factors such as sintering behavior and price of raw materials often dictate the commercial viabiUty. Large-scale production is concentrated on BaM and SrM. High quaUty magnets are generally based on SrM, and somewhat lower priced magnets are based on BaM. 

Intrinsic and Extrinsic Properties. The materials Fe, Co, and Ni and their alloys and oxides are mostly used for recording appHcations materials. Their magnetic properties are described by intrinsic and extrinsic parameters. The intrinsic properties (saturation magneti2ation, Af,... 

Thickness. The traditional definition of thermal conductivity as an intrinsic property of a material where conduction is the only mode of heat transmission is not appHcable to low density materials. Although radiation between parallel surfaces is independent of distance, the measurement of X where radiation is significant requires the introduction of an additional variable, thickness. The thickness effect is observed in materials of low density at ambient temperatures and in materials of higher density at elevated temperatures. It depends on the radiation permeance of the materials, which in turn is influenced by the absorption coefficient and the density. For a cellular plastic material having a density on the order of 10 kg/m, the difference between a 25 and 100 mm thick specimen ranges from 12—15%. This reduces to less than 4% for a density of 48 kg/m. References 23—27 discuss the issue of thickness in more detail. 

Table 12. Intrinsic Properties of Ternary R-Based Magnetic Materials ...

Fabric Composition. The method of fabric manufacture dictates many of the characteristics of the sheet, but intrinsic properties are firmly estabhshed by the base polymer selected. Properties such as fiber density, temperature resistance, chemical and light stabiUty, ease of coloration, surface energies, and others are a function of the base polymer. Thus, because nylon absorbs more moisture than polypropylene, spunbonded fabrics made from nylon are more water absorbent than fabrics of polypropylene. 

Apart from drese intrinsic properties, extrinsic effects can be produced in many oxides by variation of die metal/oxygen ratio drrough control of die atmospheric oxygen potential. The p-type contribution is increased as die oxygen pressure increases, and die n-type contribution as die oxygen pressure decreases. The pressure dependence of drese contributions can usually be described by a simple power dependence dins... 

Many inorganic solids lend themselves to study by PL, to probe their intrinsic properties and to look at impurities and defects. Such materials include alkali-halides, semiconductors, crystalline ceramics, and glasses. In opaque materials PL is particularly surface sensitive, being restricted by the optical penetration depth and carrier diffusion length to a region of 0.05 to several pm beneath the surface. 

As is true for macroscopic adhesion and mechanical testing experiments, nanoscale measurements do not a priori sense the intrinsic properties of surfaces or adhesive junctions. Instead, the measurements reflect a combination of interfacial chemistry (surface energy, covalent bonding), mechanics (elastic modulus, Poisson s ratio), and contact geometry (probe shape, radius). Furthermore, the probe/sample interaction may not only consist of elastic deformations, but may also include energy dissipation at the surface and/or in the bulk of the sample (or even within the measurement apparatus). Study of rate-dependent adhesion and mechanical properties is possible with both nanoindentation and... 

Thus this adhesion hysteresis is a result of a time-dependent roughening of the interface. It shows that roughness at an interface may actually develop as a result of bringing the two phases together as a result of the intrinsic properties of the surface molecules. 

Some rubber base adhesives need vulcanization to produce adequate ultimate strength. The adhesion is mainly due to chemical interactions at the interface. Other rubber base adhesives (contact adhesives) do not necessarily need vulcanization but rather adequate formulation to produce adhesive joints, mainly with porous substrates. In this case, the mechanism of diffusion dominates their adhesion properties. Consequently, the properties of the elastomeric adhesives depend on both the variety of intrinsic properties in natural and synthetic elastomers, and the modifying additives which may be incorporated into the adhesive formulation (tackifiers, reinforcing resins, fillers, plasticizers, curing agents, etc.). 

Rossiter (1986) demonstrated the procedure for the production process of crystalline common salt from brine. It was found that the optimal median size is determined by the entrainment limit in the crystallizer. The crystallizer had to be operated at maximum allowable temperature and the slurry density measured for quality constraints. It was also suggested that cost discontinuities should be imposed based on temperatures of the available heat sources, possible materials of construction and other intrinsic properties of the system. 

Proteins are the indispensable agents of biological function, and amino acids are the building blocks of proteins. The stunning diversity of the thousands of proteins found in nature arises from the intrinsic properties of only 20 commonly occurring amino acids. These features include (1) the capacity to polymerize, (2) novel acid-base properties, (3) varied structure and chemical functionality in the amino acid side chains, and (4) chirality. This chapter describes each of these properties, laying a foundation for discussions of protein structure (Chapters 5 and 6), enzyme function (Chapters 14-16), and many other subjects in later chapters. 

Grafting reactions alter the physical and mechanical properties of the polymer used as a substrate. Grafting differs from normal chemical modification (e.g., functionalization of polymers) in the possibility of tailoring material properties to a specific end use. For example, cellulose derivatization improves various properties of the original cellulose, but these derivatives cannot compete with many of the petrochemically derived synthetic polymers. Thus, in order to provide a better market position for cellulose derivatives, there is little doubt that further chemical modification is required. Accordingly, grafting of vinyl monomers onto cellulose or cellulose derivatives may improve the intrinsic properties of these polymers. 

Most transitions are indicative of a true behavioral change. Whether this change occurs spontaneously at a certain r, at which point the dynamics is converted to a new class and maintained thereafter, or develops gradually for the intermediate topologies, appears to be an intrinsic property of the chosen rule. 

In the tradition of previous reviews [1-22], this section addresses various aspects of nonaqueous electrolytes, including intrinsic properties, such as local structures caused by ion-ion and ion-solvent interactions and bulk properties, such as ionic conductivity, viscosity, and electrochemical stability (voltage window), and their relationships to intrinsic properties. 

In the last two decades experimental evidence has been gathered showing that the intrinsic properties of the electrolytes determine both bulk properties of the solution and the reactivity of the solutes at the electrodes. Examples covering various aspects of this field are given in Ref. [16]. Intrinsic properties may be described with the help of local structures caused by ion-ion, ion-solvent, and solvent-solvent interactions. An efficient description of the properties of electrolyte solutions up to salt concentrations significantly larger than 1 mol kg 1 is based on the chemical model of electrolytes. 

The intrinsic properties of an electrolyte evaluated at low concentrations of the salt and from the viscosity and permittivity of the solvent also determine the conductivity of concentrated solutions. Various systems were studied to check this approach. The investigated parameters and effects were ... 

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