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Chlorination Hydrocarbons

Other nonpolymeric radical-initiated processes include oxidation, autoxidation of hydrocarbons, chlorination, bromination, and other additions to double bonds. The same types of initiators are generally used for initiating polymerization and nonpolymerization reactions. Radical reactions are extensively discussed in the chemical Hterature (3—15). [Pg.220]

Solvent Resistance. Poly(vinyl alcohol) is virtually unaffected by hydrocarbons, chlorinated hydrocarbons, carboxyhc acid esters, greases, and animal or vegetable oils. Resistance to organic solvents increases with increasing hydrolysis. This resistance has promoted the use of PVA in the manufacture of gloves for use when handling organic solvents (73). [Pg.479]

Asphalts characteristically contain very high molecular weight molecular polar species, called asphaltenes, which are soluble in carbon disulfide, pyridine, aromatic hydrocarbons, chlorinated hydrocarbons, and tetrahydrofiiran. [Pg.359]

Chlorination of Hydrocarbons or Chlorinated Hydrocarbons. Chlorination at pyrolytic temperatures is often referred to as chlorinolysis because it involves a simultaneous breakdown of the organics and chlorination of the molecular fragments. A number of processes have been described for the production of carbon tetrachloride by the chlorinolysis of various hydrocarbon or chlorinated hydrocarbon waste streams (22—24), but most hterature reports the use of methane as the primary feed. The quantity of carbon tetrachloride produced depends somewhat on the nature of the hydrocarbon starting material but more on the conditions of chlorination. The principal by-product is perchloroethylene with small amounts of hexachloroethane, hexachlorobutadiene, and hexachloroben2ene. In the Hbls process, a 5 1 mixture by volume of chlorine and methane reacts at 650°C the temperature is maintained by control of the gas flow rate. A heat exchanger cools the exit gas to 450°C, and more methane is added to the gas stream in a second reactor. The use of a fluidi2ed-bed-type reactor is known (25,26). Carbon can be chlorinated to carbon tetrachloride in a fluidi2ed bed (27). [Pg.531]

Chlorotoluene [95-49-8] (l-chloto-2-methylben2ene, OCT) is a mobile, colorless Hquid with a penetrating odor similar to chlorobenzene. It is miscible ia all proportions with many organic Hquids such as aUphatic and aromatic hydrocarbons, chlorinated solvents, lower alcohols, ketones, glacial acetic acid, and di- -butylamine it is iasoluble ia water, ethylene and diethylene glycols, and triethanolamine. [Pg.52]

This powerful drying agent is suitable for use with hydrogen, argon, helium, nitrogen, hydrocarbons, chlorinated hydrocarbons, esters and higher alcohols. [Pg.55]

Maxwell s correlation was generated from hydrocarbon data only. Ludwig states that the Drickamer and Bradford correlation is good for hydrocarbons, chlorinated hydrocarbons, glycols, glycerine and related compounds, and some rich hydrocarbon absorbers and strippers. [Pg.55]

Solvents. NBRs are soluble in aromatic hydrocarbons, chlorinated hydrocarbons, ketones, esters and nitroparaffin compounds. Solvents with high evaporation rate are acetone, methyl ethyl ketone, chloroform and ethyl acetate, among others. Solvents with slow evaporation rate are nitromethane, dichloropentenes, chloro-toluene, butyl acetate and methyl isobutyl ketone. [Pg.658]

Stable isotopes Organo-metallic constituents Agrochemical contaminants Aliphatic and aromatic hydrocarbons Chlorinated hydrocarbons... [Pg.265]

Polymerization of triphenylmethyl methacrylate in the presence of a chiral anion catalyst results in a polymer with a helical structure that can be coated onto macroporous silica [742,804). Enantioselectivity in this case results from insertion and fitting of the analyte into the helical cavity. Aromatic compounds and molecules with a rigid nonplanar structure are often well resolved on this phase. The triphenylmethyl methacrylate polymers are normally used with eluents containing methanol or mixtures of hexane and 2-propanol. The polymers are soluble in aromatic hydrocarbons, chlorinated hydrocarbons and tetrahydrofuran which, therefore, are not suitable eluents. [Pg.461]

See Bromine pentafluoride Hydrogen-containing materials Chlorine Hydrocarbons Chlorine trifluoride Methane Fluorine Hydrocarbons Iodine heptafluoride Carbon, etc. [Pg.191]

Hydrocarbon Microbiology biodegradation mechanisms of oil products (gasoline, kerosene, diesel, etc.), pyrolysis, polycyclic aromatic hydrocarbons, chlorinated solvents, and ether fuels refining processes (e.g., oil product microbial desulfurization) and oil production processes (e.g., bacterial corrosion). [Pg.330]

Ethers, glycols, amines, nitriles, hydrocarbons, chlorinated Reverse osmosis [522,523]... [Pg.439]

Organic compounds such as the chlorinated solvents also include a wide range of compounds and do not easily fit into the structural classification as described for petroleum hydrocarbons. Chlorinated hydrocarbons are commonly discussed in terms of their relative density (i.e., LNAPL or DNAPL) or degree of halogenation and degree of volatility (i.e., volatile, semi-volatile). [Pg.92]

Continuous measurement of NOx emissions in vent gases —Continuous emissions measurements of total hydrocarbons —Chlorine emissions monitoring —Hold-test-release protocols... [Pg.86]

PVC is attacked by aromatic hydrocarbons, chlorinated solvents, esters, ethers and ketones. Resistance to oils, greases and alcohols is variable. [Pg.317]

Unsatisfactory against aldehydes, aromatic amines, esters, ethers, ketones, polyglycol ethers, aliphatic and aromatic hydrocarbons, chlorinated solvents, insecticides, essential oils Possible for special grades... [Pg.353]

PPEs are handicapped by an inherent sensitivity to fire and to common chemicals, such as hydrocarbons, chlorinated solvents and concentrated mineral acids. They have rather high coefficients of friction and are slightly attacked by UV and weathering, requiring UV protection. The number of producers is limited. [Pg.464]

PVFs are not sensitive to strong acids and bases, aromatic and aliphatic hydrocarbons, chlorinated solvents, greases and oils. [Pg.525]

Polysulfones are handicapped by light and UV sensitivity requiring an efficient protection for outdoor exposure sensitivity to environmental stress cracking and attacks by chemicals such as aromatic hydrocarbons, chlorinated solvents and ketones the cost (justified by the performances) sometimes an insufficient fire resistance, but special grades are marketed. [Pg.535]

Solvents Polysulfones resist acids at medium concentrations, alcohols, aliphatic hydrocarbons, greases, oils, gasoline, chlorine water They are attacked by aromatic hydrocarbons, chlorinated solvents, ketones, esters, phenols, aldehydes, amines Good to limited resistance against oils, greases, aliphatic hydrocarbons, certain alcohols Unsatisfactory against aldehydes, esters, ethers, ketones, aromatic hydrocarbons, chlorinated solvents, amines, certain alcohols, phenols. .. [Pg.641]


See other pages where Chlorination Hydrocarbons is mentioned: [Pg.311]    [Pg.165]    [Pg.115]    [Pg.263]    [Pg.41]    [Pg.936]    [Pg.206]    [Pg.897]    [Pg.439]    [Pg.115]    [Pg.59]    [Pg.344]    [Pg.359]    [Pg.364]    [Pg.368]    [Pg.625]    [Pg.630]    [Pg.639]   
See also in sourсe #XX -- [ Pg.28 ]




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Additives chlorinated hydrocarbons

Aliphatic chlorinated hydrocarbons

Aliphatic hydrocarbons chlorinated ethanes

Aliphatic hydrocarbons chlorinated ethylenes

Aliphatic hydrocarbons chlorinated methanes

Aliphatic hydrocarbons chlorination

Anaerobic oxidation, chlorinated hydrocarbons

Arctic chlorinated hydrocarbons

Aromatic hydrocarbons chlorinated

Aromatic hydrocarbons chlorine atom reactions

Aromatic hydrocarbons reactions with chlorine dioxide

Bioaccumulation, chlorinated hydrocarbons

Carcinogenic chlorinated hydrocarbons

Carcinogenic chlorinated hydrocarbons mutagenicity

Chemicals chlorinated hydrocarbons

Chloride chlorinated hydrocarbons

Chlorinated aliphatic hydrocarbon wastes

Chlorinated arene hydrocarbons

Chlorinated compounds aliphatic hydrocarbon

Chlorinated fluorinated hydrocarbons CFCs)

Chlorinated hydrocarbon / plastic

Chlorinated hydrocarbon / plastic rubber

Chlorinated hydrocarbon concentrations

Chlorinated hydrocarbon exposure

Chlorinated hydrocarbon exposure symptoms

Chlorinated hydrocarbon pesticides, detection

Chlorinated hydrocarbon reaction

Chlorinated hydrocarbon side products

Chlorinated hydrocarbon toxicity

Chlorinated hydrocarbons

Chlorinated hydrocarbons 14 INDEX

Chlorinated hydrocarbons Chlorofluorocarbons

Chlorinated hydrocarbons absorption properties

Chlorinated hydrocarbons analysis

Chlorinated hydrocarbons biotransformation

Chlorinated hydrocarbons chemical classes

Chlorinated hydrocarbons chloracne

Chlorinated hydrocarbons early

Chlorinated hydrocarbons eliminating

Chlorinated hydrocarbons history

Chlorinated hydrocarbons metabolic pathways

Chlorinated hydrocarbons phosgene

Chlorinated hydrocarbons reaction with

Chlorinated hydrocarbons removal

Chlorinated hydrocarbons resistance

Chlorinated hydrocarbons structures

Chlorinated hydrocarbons, detection

Chlorinated hydrocarbons, determination

Chlorinated hydrocarbons, determining

Chlorinated polyaromatic hydrocarbons

Chlorinated polyaromatic hydrocarbons, determination

Chlorinated polycyclic aromatic hydrocarbons

Chlorinated polycyclic aromatic hydrocarbons Cl-PAHs)

Chlorinated solvents and aromatic hydrocarbons

Chlorination of hydrocarbons

Chlorination, hydrocarbon cores

Chlorine atoms aromatic hydrocarbons, reactions with

Chlorine reaction with hydrocarbons

Coastal waters chlorinated hydrocarbons

Combustion of chlorinated hydrocarbons

Dechlorination chlorinated hydrocarbon metabolism

Degradation of chlorinated hydrocarbons

Ecotoxicology of Chlorinated Aromatic Hydrocarbons

Electrokinetic Removal of Chlorinated Aliphatic Hydrocarbons

Fluorinated chlorinated hydrocarbons

From chlorinated hydrocarbon solvents

From chlorinated hydrocarbons

Great Lakes chlorinated hydrocarbons

Ground water chlorinated hydrocarbons

Hydrocarbon, chlorinate, exposure

Hydrocarbon, chlorinate, exposure symptoms

Hydrocarbons chlorinated, BCFs

Hydrocarbons persistent chlorinated

Hydrocarbons, chlorinate

Hydrocarbons, chlorination cracking

Hydrocarbons, saturated, chlorination

Hydroxyl radical chlorinated hydrocarbons

Insecticide poisoning chlorinated hydrocarbons

Insecticides chlorinated hydrocarbon

Lipophilic chlorinated hydrocarbon

Methanol, properties chlorinated hydrocarbons

Nucleus-chlorinated aromatic hydrocarbons

Organic chlorinated hydrocarbons

Organic compounds chlorinated hydrocarbons

Organic contaminants, environmental chlorinated hydrocarbons

Oxidation chlorinated hydrocarbon metabolism

Paraffinic hydrocarbons chlorination

Pesticides chlorinated hydrocarbon insecticides

Pesticides, chlorinated hydrocarbon

Pesticides, classes chlorinated hydrocarbon

Photolysis chlorinated hydrocarbons

Properties of chlorinated hydrocarbon

Removal of chlorinated hydrocarbons

Side-chain-chlorinated aromatic hydrocarbons

Solvent, solvents chlorinated hydrocarbon

Solvents chlorinated hydrocarbons, determination

Solvents, chlorinated hydrocarbons

The pyrolysis of chlorinated hydrocarbons

Unimolecular decompositions of brominated and chlorinated hydrocarbons

Vapor pressure, chlorinated-hydrocarbons

Water chlorinated hydrocarbons

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