Filtration pressure

Pressure filtration avoids problems observed with vacuum filtration. When the water sampler itself can be pressurized to force the sample through an in-line filter into the receiving bottle, the number of transfer steps is minimized, thus reducing the potential risk of contamination. If the redox state of the water sample must be retained to prevent the precipitation of, for example, iron tmd manganese hydroxides in higher valence states, an inert gas such as nitrogen must be used for pressurization. 

Filter holders made of different materials are conunercially available (e.g., polycarbonate system from Sartorius Swinnex polypropylene apparatus fi-om Millipore, or TFE-Teflon cylinders fi om various companies). An intercomparison study of the different filtration systems, used for the preparation of coastal seawater samples for the determination of dissolved trace elements, showed good agreement between the various systems. The filtrates from off-line systems did not exhibit marked differences when compared with filtrates from the in-line systems (Bewers et al.. 1985). 

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The same moisture content of the produced cake can be obtained in shorter dewatering times if higher pressures are used. If a path of constant dewatering time is taken, moisture content is reduced at higher pressures with a parallel increase in cake production capacity. This is an advantage of pressure filtration of reasonably incompressible soHds like coal and other minerals. 

An indatable diaphragm or membrane has been used in membrane plate presses closely related to the conventional plate and frame presses. A pressure filtration period is foUowed by compression with the hydraulically operated membrane or by a hydraulically operated ram if dexible rim seals are fitted. This principle also is used in vertical presses that use either one or two endless cloth belts indexing between plates. Indatable membrane also may be used on a cylindrical filtration surface with or without a preceding pressure filtration stage. 

Pressure Filtration. High pressure drops have a twofold effect, ie, on capacity and on displacement dewatering which often follows. 

This reduction in permeabiUty due to cake consoHdation or coUapse may be so large that it may nullify or even overtake the advantage of using high pressures in the first place and there is then no reason for using the generally more expensive pressure filtration hardware. While a simple Hquid pump may be cheaper than the vacuum pump needed with vacuum filters, if air displacement dewatering is to foUow filtration in pressure filters, an air compressor has to be used and is expensive. 

Eor most industrial inorganic sohds such as minerals etc, the increase in with Ap is not too great, and thus should the material to be filtered be too fine for vacuum filtration, pressure filtration may be advantageous and give better rates. 

Pressure filters can treat feeds with concentrations up to and in excess of 10% sohds by weight and having large proportions of difficult-to-handle fine particles. Typically, slurries in which the sohd particles contain 10% greater than 10 ]lni may require pressure filtration, but increasing the proportion greater than 10 ]lni may make vacuum filtration possible. The range of typical filtration velocities in pressure filters is from 0.025 to 5 m/h and dry sohds rates from 25 to 250 kg nY/h. The use of pressure filters may also in some cases, such as in filtration of coal flotation concentrates, eliminate the need for flocculation. 

If ah of the nonfiltration operations are grouped together into a downtime, assumed to be fixed and known, an optimum filtration time in relation to p can be derived by optimizing the average dry cake production obtained from the cycle. Eor constant pressure filtration and where the medium resistance R and the specific cake resistance are constant, the fohowing equation appHes ... 

Since 1980, a number of new filters have appeared on the market, utilising some form of mechanical compression of the filter cake, either after a conventional pressure filtration process or as a substitute for it. In most designs the compression is achieved by inflating a diaphragm which presses the slurry or the freshly formed filter cake toward the medium, thus squee2ing an additional amount of Hquid out of the cake. 

There are many technical problems to be considered when developing a new commercial and viable filter. However, the filtration hardware in itself is not enough, as the control of a continuous pressure filter is much more difficult than that of its equivalents in vacuum filtration the necessary development may also include an automatic, computerized control system. This moves pressure filtration from low to medium or even high technology. Disk Filters. 

The test results reported show the advantages of pressure filtration quite clearly, ie, the dry cake production capacity obtained with the test soHds (coal suspensions) was raised 60 or 70% and the final moisture content of the cake reduced by as much as 5 to 7% by increasing the pressure drop from 60 to 200 kPa. Further increases in the operating pressure bring about less and less return in terms of capacity and moisture content. 

The so-called hyperbar vacuum filtration is a combination of vacuum and pressure filtration in a pull—push arrangement, whereby a vacuum pump of a fan generates vacuum downstream of the filter medium, while a compressor maintains higher-than-atmospheric pressure upstream. If, for example, the vacuum produced is 80 kPa, ie, absolute pressure of 20 kPa, and the absolute pressure before the filter is 150 kPa, the total pressure drop of 130 kPa is created across the filter medium. This is a new idea in principle but in practice requires three primary movers a Hquid pump to pump in the suspension, a vacuum pump to produce the vacuum, and a compressor to supply the compressed air. The cost of having to provide, install, and maintain one additional primary mover has deterred the development of hyperbar vacuum filtration only Andrit2 in Austria offers a system commercially. 

The BHS-Fest Filter. A different approach to the use of a dmm for pressure filtration is made in the BHS-Fest filter (Fig. 24). This permits a separate treatment of each filter section, in which the pressure may vary from vacuum to a positive pressure pressure regulation is much less difficult than in the conventional enclosed dmm-type pressure filter. 

Because gravity is too weak to be used for removal of cakes in a gravity side filter (2), continuously operated gravity side filters are not practicable but an intermittent flow system is feasible in this arrangement the cake is first formed in a conventional way and the feed is then stopped to allow gravity removal of the cake. A system of pressure filtration of particles from 2.5 to 5 p.m in size, in neutralized acid mine drainage water, has been described (21). The filtration was in vertical permeable hoses, and a pressure shock associated with relaxing the hose pressure was used to aid the cake removal. 

As more and more of the filtrate is removed, the slurry graduaUy thickens and may become thixotropic. The soHds content of the thickened slurry may be higher than that obtained with conventional pressure filtration, by as much as 10 or 20%. A range of velocity gradients from 70 to 500 L/s has been suggested as necessary to prevent cake formation and to keep the thickening slurry ia a fluid state (27). 

D. Blankmeister and Th. Triebert, Dewatering Fltrafme Coal Slurries by Means of Pressure Filtration, Aufbereitungstechnik Nr. 1/1986, pp. 1—5. 

R. Bott, H. Anlauf, and W. Stahl, Continuous Pressure Filtration ofWeyFine Coal Concentrates, Aufbereitungstechnik, Nr.5/Mai 1984, pp. 245—258. 

Theoretical studies (30) comparing the abihty to dewater compressible sohds by sedimenting and filtering centrifuges to pressure filters, have shown that at high G levels, scroU decanters produce drier cakes than pressure filtration. 

Soluble impurities can be extracted by washing with deionized or distilled water foUowed by filtration (1,12,26). Powders prepared by wet chemical synthesis are often washed and filtered for purification prior to use. The dewatering (qv) process can be enhanced by pressure filtration. Organic solvents can be used to remove water-insoluble impurities and wash-water sensitive materials. 

The cyanide, which crystallizes in the anhydrous state from aqueous solution, is recovered by evaporation under reduced pressure, filtration, and drying. Because the crystal size is significantly larger than sodium cyanide it can be sold in powder form without excessive dusting. However, it tends to cake in the shipping container and is often compacted and granulated to larger sizes. 

Significant improvements were made in the 1980s and early 1990s in high capacity, automated variable volume filters that incorporate automatic pressure filtration, expression, washing, and air displacement. Some of the large plate-and-frame automatic presses can operate at up to 2 MPa (ca 285 psig), with up to 100 chambers (25,26). 

High Pressure Filtration Using the Tube Filter Press A Technical and Economic Review, Alfa-Dyne Inc., Cleveland, Ohio, 1991 J. Quilter, Indust. Miner. Mag, Energy Suppl, 29 (Mar. 1983). 

In cake or surface filtration, there are two primary areas of consideration continuous filtration, in which the resistance of the filter cake (deposited process solids) is veiy large with respec t to that of the filter media and filtrate drainage, and batch pressure filtration, in which the resistance of the filter cake is not veiy Targe with respect to that of the filter media and filtrate drainage. Batch pressure filters are generally fitted with heavy, tight filter cloths plus a layer of precoat and these represent a significant resistance that must be taken into account. Continuous filters, except for precoats, use relatively open cloths that offer little resistance compared to that of the filter cake. 

Vacuum or Pressure The vast majority of all continuous filters use vacuum to provide the driving force for filtration. However, if the feed slurry contains a highly volatile hquid phase, or if it is hot, saturated, and/or near the atmospheric pressure boiling point, the use of pressure for the driving force may be required. Pressure filtration might also be used where the required cake moisture content is lower than that obtainable with vacuum. 

Since most batch-type filters operate under pressure rather than vacuum, the following discussion will apply primarily to pressure filtration and the various types of pressure filters. 

Constant-Pressure Filtration For constant-pressure filtration Eq. (18-51) can be integrated to give the following relationships between total time and filtrate measurements ... 

For a given constant-pressure filtration, these may be simplified to 9... 

It is advisable to start a constant-pressure filtration test, like a comparable plant operation, at a low pressure, and smoothly increase the pressure to the desired operating level. In such cases, time and filtrate-quantity data shoulci not be taken until the constant operating pressure is reahzed. The value of r calculated from the extrapolated intercept then reflec ts the resistance of both the filter medium and that part of the cake deposited during the pressure-buildup period. When only the total mass of diy cake is measured for the tot cycle time, as is usually true in vacuum leaf tests, at least three runs of different lengths should be made to permit a rehable plot of 0/V against W. If rectification of the resulting three points is dubious, additional runs should be made. 

FIG. 18-108 Bomb filter for small-scale pressure filtration tests. [Silverhlatt etal., Cbem. Eng., 81(9), 132 (1974), hy permission.]... 

Constants C and K can be determined from several measurements of filtrate volumes taken at different time intervals. There are some doubts as to the actual constancy of C and K during constant pressure filtration. Constants C and K depend on r (specific volumetric cake resistance), which, in turn, depends on the pressure drop across the cake. This AP causes some changes in the cake, especially during the initial stages of filtration. When the cake is very thin, the main portion of the total pressure drop is exerted on the filter medium. As the cake becomes thicker, the pressure drop through the cake increases rapidly but then levels off to a constant value. Isobaric filtration shows insignificant deviation from the expressions developed. For approximate calculations, it is possible to neglect the resistance of the filter plate, provided the cake is not too thin. Then the filter plate resistance, Rf, is equal to zero, C = 0, and r = 0. Hence, a simplified equation is = Kr. 

The dynamics of variable-rate and -pressure filtrations can be illustrated by pressure profiles that exist across the filter medium. Figure 7 shows the graphical representation of those profiles. According to this plot, the compressed force in the cake section is ... 

This type of filter allows pressurized filtration of a slurry mixture to remove solids. A set of filter plates is sandwiched together in series with a configuration similar to the plates on a plate-and-frame heat exchanger. After the plates are compressed... 

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