Polyvinyl retardation

Other components in PVAc-formulations are defoamers, stabilizers, filler dispersants, preservatives, thickeners (hydroxyethylcellulose, carboxymethylcellu-lose), polyvinyl alcohols, starch, wetting agents, tackifiers, solvents (alcoholes, ketone, esters), flame retardants and others. 

Approximately 10 million pounds of trichloroethylene are used aimually as a chain transfer agent in the production of polyvinyl chloride (McNeill 1979). Other chemical intermediate uses of trichloroethylene include production of pharmaceuticals, polychlorinated aliphatics, flame retardant chemicals, and insecticides (Mannsville 1992 Windholz 1983). Trichloroethylene is used as a refrigerant for low-temperature heat transfer (Cooper and Hickman 1982 lARC 1979 McNeill 1979) and in the aerospace industry for flushing liquid oxygen (Hawley 1981 Kuney 1986). 

In order to determine the sources of contamination, some water samples, including wastewaters and effluents from different industries were also sampled. Along the Cinca River and in the industrial area of Monzon, industrial effluents from two different industries were selected the first one produced EPS (Expandable polystyrene) treated with flame retardants and ABS (Acrylonitrile-butadiene-styrene), and the second one produced PVC (Polyvinyl chloride). As regards the Vero River, three industries were sampled the first one, a textile industry which produced polyester fibers treated with flame retardants, the second one produced epoxy... 

The plasticizer-range alcohols are largely used as feedstock for production of high molecular weight diesters of phthalic, adipic, azelaic, and sulftiric acids. All these are used primarily in plasticizers for polyvinyl chloride (PVC) and other plastics. The plastics industry also uses them as additives for heat stabilization, to control the viscosity of PVC plastisols, ultraviolet absorbers, flame retardants, and antioxidants. They are also found in synthetic, lubricants, agricultural chemicals, and defoamers. 

Until recently, halogen-free products were only available in Europe, but Sony has now adopted global design specifications to ensure that all their projects meet the same standards. Sony aims to have all product lines free of brominated flame retardants by the end of 2005 if substitutes are found to be safer. They also aim to phase out all uses of polyvinyl chloride (PVC) by 2005 as well as lead solder, and specified heavy metals. For example, a Walkman model has PVC-free cables and no brominated flame retardants or lead solder in the printed circuit board. 

Uses Plasticizer in lacquers, varnishes, polyvinyl chloride, polystyrene, nitrocellulose waterproofing agent hydraulic fluid and heat exchange medium fire retardant for plastics solvent mixtures synthetic lubricant gasoline additive to prevent pre-ignition. 

Antimony has few other uses except as an alloy to harden other materials. One recent development was to add antimony oxide to polyvinyl chloride (PVC pipe) to act as a flame retardant. 

When tested in other polymers, maleimides did not affect the rate of cross-linking in polydimethylsiloxane, polyisobutylene, and polyvinylchloride. In polyethylene, the addition of 5 wt.% of m-phenylene dimaleimide increased the G(X) from 1.8 to 7.2. In the polyvinylacetate the effect was even more pronounced the dose for gelation was reduced by about a factor of 50. Contrary to the cross-link enhancing effect found for m-phenylene dimaleimide, cross-linking was retarded in polyvinyl acetate by the addition of monomaleimides. When analyzing the mechanism of the reaction it was concluded that monomaleimides are not expected to affect cross-linking in saturated polymers. ... 

PBDEs are used in different resins, polymers, and substrates at levels ranging from 5 to 30% by weight (EU 2001). Plastic materials that utilize PBDEs as flame retardants include ABS polyacrylonitrile (PAN) polyamide(PA) polybutylene terephthalate (PBT) polyethylene (PE) cross-linked polyethylene (XPE) polyethylene terephthalate (PET) polypropylene (PP) polystyrene (PS) high-impact polystyrene (HIPS) polyvinyl chloride (PVC) polyurethane (PUR) and unsaturated polyester (UPE). These polymers and examples of their final products are summarized inTable 5-2 (Hardy 2002 WHO 1994a). 

PVC—Abbreviation used to denote polyvinyl chloride. A type of plastic material used for cable jacketing. Typically used in flame-retardant cables,... 

On an industrial scale, the most commonly used pastes are those based on polyvinyl chloride (PVC), the plastificators being the mentioned organic liquids. Pigments, fire-retardants, antistatic agents, as well as other ingredients usually added to PVC may also be introduced. 

Among the emerging pollutants of industrial origin, Bisphenol A [2,2 bis(4-hydroxydiphenyl)pro-pane] (BPA) has special relevance since it was one of the first chemicals discovered to mimic estrogens as endocrine disrupters.147 This compound was first reported by Dianin in 1891.1411 BPA is produced in large quantities worldwide, mainly for the preparation of polycarbonates, epoxy resins, and unsaturated polyester-styrene resins.149 The final products are used in many ways, such as coatings on cans, powder paints, additives in thermal paper, in dental composite fillings, and even as antioxidants in plasticizers or polymerization inhibitors in polyvinyl chloride (PVC). To a minor extent, BPA is also used as precursor for flame retardants such as tetrabromobisphenol A or tetrabromobisphenol-S-bis(2,3-dibromopropyl) ether.150 This substance can enter the environment... 

Wang, D.L., Liu, Y., Wang, D.Y., Zhao, C.X., Mou, Y.R., and Wang, Y.Z. 2007. A novel intumescent flame-retardant system containing metal chelates for polyvinyl alcohol. Polym. Deg. Stab. 92 1555-1564. 

Hydrogen chloride (HC1) and hydrogen bromide (HBr) are strong acids that dissociate entirely in water. Both may be present in fire gas, for example from polyvinyl chloride (PVC) or brominated flame retardants, and since the damage caused by the acidity is independent of the anion (Cl or Br ). The current discussion focuses on HC1, it is also applicable to HBr. 

Lawson, D.F. Kay, E.L. Flame and smoke retardants for polyvinyl chloride. PCT US Patent 3,957,723, assigned to The Firestone Tire Rubber Company, 1976. 

Reynolds (19) has given a preliminary report of experiments which show that persulphate resembles periodate In oxidising the l 2-glycol groups of which there are about 2% In polyvinyl alcohol although the reaction Is not quantitative. Conjugated unsaturated ketone groups axa also formed these may retard polymerisation. 

The chemicals used for coating and laminating are polymeric materials, either naturally occurring or produced synthetically. These include natural and synthetic rubbers, polyvinyl chloride, polyvinyl alcohol, acrylic, phenohc resins, polyurethanes, silicones, fluorochemicals, epoxy resins and polyesters." Coating formulations typically include auxiliaries such as plasticizers, adhesion promoters, viscosity regulators, pigments, fillers, flame retardants, catalysts and the like. ... 

Any post-consumer plastic stream will contain some halogens in the form of polyvinyl chloride, polyvinylidene chloride, brominated flame retardants, halogenated additives, food waste, or salt. Therefore, two issues must be considered. First, the gas stream resulting from the depolymerization of plastics must be scrubbed to remove any halogenated gases to satisfy emissions controls. Second, halogens in the liquid product must be minimized to increase its value and marketability. Therefore the Conrad process has been developed. It is a robust process unit that can accommodate a variable feedstream and produce a consistent product, free of nonhydrocarbon impurities by low feed preparation costs. 

PCAs (typically medium carbon chain length compounds of 50 - 60 wt% Cl) are also used as secondary plasticizers for polyvinyl chloride (PVC) and in other plastics (polyesters, polyolefins, polystyrene) and rubbers (neoprene). PCAs can partially replace primary plasticizers such as phthalates and phosphate esters [21]. As plasticizers, PCAs lend flame retardancy to the product, unlike phthalate esters [5]. They are added prior to the processing step for the polymer. 

Polyvinyl Chloride (PVQ Foams. Rigid PVC foam is inherently fire retardant because of the high chlorine content (56.7%). Flexible PVC foams present increased fire hazards because of the plasticizers they contain. Flammable plasticizers used include alkyl phthalates, as dioctyl phthalate. Non-burning types include alkyl aryl phosphates (phosphate esters). The latter types should improve resistance to ignition and reduce flame spread when compared to the usual phthalate plasticizers (38) (41). 

Use Manufacture of carbon tetrachloride, trichloroethylene, chlorinated hydrocarbons, polychloro-prene (neoprene), polyvinyl chloride, hydrogen chloride, ethylene dichloride, hypochlorous acid, metallic chlorides, chloracetic acid, chlorobenzene, chlorinated lime water purification, shrinkproofing wool, flame-retardant compounds, special batteries (with lithium or zinc) processing of meat, fish, vegetables, and fruit. For information, refer to the Chlorine Institute, 2001 L St., NW, Suite 506, Washington DC 20036. 

Use High-pressure lubricants, as flame retardants in plastics and textiles, as plasticizer for polyvinyl chloride in polyethylene sealants, and in detergents. 

Use Plasticizer for polyvinyl chloride, polystyrene, nitrocellulose fire-retardant for plastics air-filter medium solvent mixtures waterproofing additive to extreme pressure lubricants hydraulic fluid heat-exchange medium. 

Butoxyethanol acetate is primarily used as a high-boiling, retarder solvent (i.e., an active, slow-evaporating solvent which ensures smooth film formation) for nitrocellulose lacquers, acrylic enamels, epoxy resins, and multicolor lacquers (Leaf 1985 as cited in NIOSH 1990 Lewis 1993). 2-Butoxyethanol acetate is also a film-coalescing aid for polyvinyl acetate latex and is used in some ink and spot remover... 

The brittleness of polyvinyl chloride and polystyrene was decreased by blending with plasticizers or impact modifying polymers. The flammability of polystyrene and polyolefins was decreased by the addition of flame retardants and the Instability of polyvinyl chloride and polypropylene was reduced by the addition of stabilizers. — The strength and heat resistance of all of the general purpose plastics were Improved by reinforcing with fiberglass or graphite fibers. 

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