Hazard disposal

Aqueous Drawoffs from Hydrocarbon Vessels - Water or aqueous materials that are withdrawn continuously or intermittently from vessels where they directly contact hydrocarbons (e.g., process water from distillate drums, and spent wash water or spent caustic solution from settlers) must be disposed of in such a way that entraimnent or inadvertent withdrawal of hydrocarbon will not create a hazard. Disposal is therefore a function of hydrocarbon category, as follows ... 

Larkin, R.G. and Clark, J.E., Modeling density changes in hazardous disposal well plumes, in Underground Injection Science and Technology, Tsang, C.F. and Apps, J.A., Eds., Elsevier, New York, 2007. 

Task Quantity (000s) Units Soil Washing Stabilization/ Nonhazardous Disposal Hazardous Disposal... 

High-hazard Disposal in a Intrusion Not applicable Most... 

Special Hazards. Disposable clothing for hazardous work (as examples, in decontamination, or in atomic radiation at low levels) may be made from unsupported vinyls by welding. 

Summary statement a tabulation of the recommended exposure limit and toxic dose data, with a general physical description and briefly stated information about Are hazards, unique storage hazards, decomposition hazards, reactivity and incompatibility hazards, disposal hazards, etc., as applicable. 

MOLD CLEANING CLEANING HAZARD DISPOSAL OPERATE DAMAGE... 

Freeman, H. M., Standard Handbook of Hazardous Waste Treatment and Disposal, McGraw-Hill, New York, 1989. 

FREEMAN Standard Handbook of Hazardous Waste Treatment and Disposal... 

Federal regulations (40 CFR 261) classify acrylonitrile as a hazardous waste and it is Hsted as Hazardous Waste Number U009. Disposal must be in accordance with federal (40 CFR 262, 263, 264), state, and local regulations only at properly permitted faciUties. It is Hsted as a toxic pollutant (40 CFR 122.21) and introduction into process streams, storm water, or waste water systems is in violation of federal law. Strict guidelines exist for clean-up and notification of leaks and spills. Federal notification regulations require that spills or leaks in excess of 100 lb (45.5 kg) be reported to the National Response Center. Substantial criminal and civil penalties can result from failure to report such discharges into the environment. 

Thorium, uranium, and plutonium are well known for their role as the basic fuels (or sources of fuel) for the release of nuclear energy (5). The importance of the remainder of the actinide group Hes at present, for the most part, in the realm of pure research, but a number of practical appHcations are also known (6). The actinides present a storage-life problem in nuclear waste disposal and consideration is being given to separation methods for their recovery prior to disposal (see Waste treati nt, hazardous waste Nuclear reactors, waste managet nt). 

Exposure limits for siHcon carbide and powders of zirconium compounds (including zirconium dioxide) have been estabHshed by ACGIH. TLV—TWA s are 10 mg/m and 5 mg/m, respectively. OSHA guidelines for zirconium compounds call for a PEL of 5 mg/m. There are no exposure limits for siHcon nitride powder, but pmdent practice suggests a TLV—TWA of 0.1 mg/m. The soHd ceramics present no apparent health hazard. In machining such ceramics, however, care should be taken to prevent inhalation of respirable particles in amounts in excess of estabHshed limits. Disposal should be in approved landfills the materials are inert and should pose no danger to the environment. 

Solution Casting. The production of unsupported film and sheet by solution casting has generally passed from favor and is used only for special polymers not amenable to melt processes. The use of solvents was generally very hazardous because of their flammabiUty or toxic nature. The cost of recovery and disposal of solvents became prohibitive for many lower price film appHcations. The nature of the drying operations leads to problems with solvent migration and retention that are not problems with melt-processed polymers. 

Economic Considerations. The principal economic consideration is, of course, total installed system cost, including the initial cost of the flow primary, flow secondary, and related ancillary equipment as well as material and labor required for installation. Other typical considerations are operating costs and the requirements for scheduled maintenance. An economic factor of increasing importance is the cost of disposal at the end of normal flow meter service life. This may involve meter decontamination if hazardous fluids have been measured. 

Factors which may affect the cost of coal upgrading are environmental considerations such as toxicity, hazardous waste disposal, and carcinogenic properties (131). These and other environmental problems from process streams, untreated wastewaters, and raw products would figure significantly into the cost of commercialization. 

M. ModeU, "Detoxification and Disposal of Hazardous Organic Chemicals by Processing with Supercritical Water," Pinal Report, U.S. Medical Research and Development Command, 1985. 

California and Minnesota have placed restrictions on the disposal of fluorescent light tubes, which contain from 40—50 mg of mercury per tube, depending on size. After batteries, fluorescent lamps are the second largest contributor of mercury in soHd waste streams in the United States (3,14). A California law classifies the disposal of 25 or more fluorescent lamp tubes as hazardous waste. In Minnesota, all waste lamps generated from commercial sources are considered hazardous waste. Private homes are, however, exempt from the law (14). Other states have proposed similar regulations. Several companies have developed technologies for recovering mercury from spent lamps (14). 

Environmental Factors. The control, recovery, and disposal of mercury-bearing waste products are as important to the mercurials industry as the manufacturing process. The difficulties involved in removing mercury from waste-product streams and the problems of recovery or disposal have resulted in a substantial reduction in the number of manufacturers of mercury compounds as well as in the variety of mercury compounds being manufactured. Moreover, the manufacturing process used for a mercury compound may not necessarily be the most efficient or economical. Rather, the choice may depend on the nature of the by-products, the toxic hazard of the process, and the ease of recovery of the mercury from the waste-product stream. 

The surviving U.S. plants have embraced all types of waste treatment processes (see Wastes treatment, hazardous waste Wastes, industrial). The most desired poUution prevention processes are those which reduce the total amount of waste discharged. Treatment and disposal are less strongly emphasized options. Zero wastewater discharge faciHties and water recycling processes are becoming more common (55,56). 

When disposed of, all the nitroparaffins are considered to be hazardous waste. AH have the characteristic of ignitabHity however, 2-nitropropane also is a Hsted hazardous waste (U171) because of its toxicity. The preferred method of disposal is by incineration. GeneraHy, the nitroparaffins must be... 

Low molecular weight ether hydroperoxides are similarly dangerous and therefore ethers should be tested for peroxides and any peroxidic products removed from them before ethers are distilled or evaporated to dryness. Many ethers autoxidize so readily that peroxidic compounds form at dangerous levels when stored in containers that are not airtight (133). Used ether containers should be handled cautiously and if they are found to contain hazardous soHd ether peroxides, bomb-squad assisted disposal may be required (134). ZeoHtes have been used for removal of peroxide impurities from ethers (135). 

Clean Air Act and its amendments ia 1970, 1977, and 1990 1967 Air Quahty Standards and National Air Pollution Acts and 1970 National Environmental PoHcy Act) (2) better waste disposal practices (1965 SoHd Waste Disposal Act 1976 Resource Conservation and Recovery Act) (see Wastes, industrial Waste treatment, hazardous wastes) (i) reduced noise levels (1972 Noise Control Act) (4) improved control of the manufacture and use of toxic materials (1976 Toxic Substances Control Act) and (5) assignment of responsibiUty to manufacturers for product safety (1972 Consumer Product Safety Act) (15,16). 

Wastes contaminated with aniline may be Hsted as RCRA Hazardous Waste, and if disposal is necessary, the waste disposal methods used must comply with U.S. federal, state, and local water poUution regulations. The aniline content of wastes containing high concentrations of aniline can be recovered by conventional distillation. Biological disposal of dilute aqueous aniline waste streams is feasible if the bacteria are acclimated to aniline. Aniline has a 5-day BOD of 1.89 g of oxygen per gram of aniline. 

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