Fuel electric vehicle

Because of the consciousness for environment and the economic situation for fuels, electric vehicles (EV) have become reconsidered. Higher energy density over 500 Wh kg is required for widespread of EV. Energy density of Li-ion battery system with rocking-chair mechanism is limited up to c.a. 250 Wh kg Theoretically Li-air, Li-S, and Zn-air can only be the candidates for this kind of high-energy battery overcoming the limitation of Li-ion system. So, Li-S system has been revived. 

Alternatives to coal and hydrocarbon fuels as a source of power have been sought with increasing determination over the past three decades. One possibility is the Hydrogen Economy (p, 40), Another possibility, particularly for secondary, mobile sources of power, is the use of storage batteries. Indeed, electric vehicles were developed simultaneously with the first intemal-combustion-cngined vehicles, the first being made in 1888. In those days, over a century ago, electric vehicles were popular and sold well compared with the then noisy, inconvenient and rather unreliable peU ol-engined vehicles. In 1899 an electric car held the world land-speed record at 105 km per hour. In the early years of this century, taxis in New York, Boston and Berlin were mainly electric there were over 20000 electi ic vehicles in the USA and some 10000 cars and commercial vehicles in London. Even today (silent) battery-powered milk delivery vehicles are still operated in the UK. These use the traditional lead-sulfuric acid battery (p. 371), but this is extremely heavy and rather expensive. 

See also Electric Vehicles Fuel Cells Fuel Cell Vehicles Office Equipment Storage Storage Technology. 

The poor efficiencies of coal-fired power plants in 1896 (2.6 percent on average compared with over forty percent one hundred years later) prompted W. W. Jacques to invent the high temperature (500°C to 600°C [900°F to 1100°F]) fuel cell, and then build a lOO-cell battery to produce electricity from coal combustion. The battery operated intermittently for six months, but with diminishing performance, the carbon dioxide generated and present in the air reacted with and consumed its molten potassium hydroxide electrolyte. In 1910, E. Bauer substituted molten salts (e.g., carbonates, silicates, and borates) and used molten silver as the oxygen electrode. Numerous molten salt batteiy systems have since evolved to handle peak loads in electric power plants, and for electric vehicle propulsion. Of particular note is the sodium and nickel chloride couple in a molten chloroalumi-nate salt electrolyte for electric vehicle propulsion. One special feature is the use of a semi-permeable aluminum oxide ceramic separator to prevent lithium ions from diffusing to the sodium electrode, but still allow the opposing flow of sodium ions. 

See also Automobile Performance Electric Vehicle Fuel Cell Vehicles Gasoline Engine Hybrid Vehicles. 

See also Batteries Capital Investment Decisions Consumption Economically Efficient Energy Choices Electricity Electric Power, Generation of Faraday, Michael Fuel Cells Fuel Cell Vehicles Magnetism and Magnets Oersted, Hans Christian Tesla, Nikola. 

See also Batteries Capacitors and Ultracapacitors Electric Motor Systems Emission Control, Vehicle Environmental Problems and Energy Use Flywheels Fuel Cells Fuel Cell Vehicles Flybrid Vehicles Materials Transportation, Evolution ofEnergy Use and. 

Electrical management, or power conditioning, of fuel cell output is often essential because the fuel cell voltage is always dc and may not be at a suitable level. For stationai y applications, an inverter is needed for conversion to ac, while in cases where dc voltage is acceptable, a dc-dc converter maybe needed to adjust to the load voltage. In electric vehicles, for example, a combination of dc-dc conversion followed by inversion may be necessary to interface the fuel cell stack to a, 100 V ac motor. 

Most urban rail service is electric-powered and most urban bus service is diesel-powered, although diesel rail and electric bus operations do exist, as noted above. The efficiency and environmental impacts of electricity depend gi eatly on the source of electric power. Although electric vehicles produce no tailpipe emissions, generation of electricity can produce significant emissions that can travel long distances, Eor example, coal-powered electricity plants produce particulate emissions that travel halfway across North America, Urban buses also can be powered by a variety of alternative fuels. 

As crude oil reserves dwindle, the marketplace will either transition to the electrifying of the transportation system (electric and fuel-cell vehicles and electric railways), with the electricity being produced by coal, natural gas, nuclear and renewables, or see the development of an industry to produce liquid fuel substitutes from coal, oil shale, and tar sands. It might also turn out to be a combination of both. The transition will vary by nation and will be dictated strongly by the fuels available, the economic and technological efficiencies of competitive systems, the relative environmental impacts of each technology, and the role government takes in the marketplace. 

Li ion batteries are heavily advertised as the future power sources for electric vehicles. This seems premature because the technology of heat management and many questions of safety are not solved. Fuel cells and several types of secondary batteries have a long history in the field of electric vehicle propulsion, with successes and failures. For information on electric vehicle batteries, see [16-22],... 

K. Tatsumi, A. Mabuchi, N. lwashita, H. Sa-kaebe, H. Shioyama, H. Fujimoto, S. Higuchi, in Batteries and Fuel Cells for Stationary and Electric Vehicle Applications (Eds A. R. Landgrebe, Z. Takehara) Electrochemical Society, Pennington, NJ, 1993, PV 93-8, p. 64. 

Small engines may incorporate the fuel cell as a power source. Fuel cells combine hydrogen and oxygen in a way that generates electricity, which drives a motor. Leading automobile manufacturers have already developed fuel-cell vehicles. 

The electrocatalytic oxidation of methanol has been widely investigated for exploitation in the so-called direct methanol fuel cell (DMFC). The most likely type of DMFC to be commercialized in the near future seems to be the polymer electrolyte membrane DMFC using proton exchange membrane, a special form of low-temperature fuel cell based on PEM technology. In this cell, methanol (a liquid fuel available at low cost, easily handled, stored, and transported) is dissolved in an acid electrolyte and burned directly by air to carbon dioxide. The prominence of the DMFCs with respect to safety, simple device fabrication, and low cost has rendered them promising candidates for applications ranging from portable power sources to secondary cells for prospective electric vehicles. Notwithstanding, DMFCs were... 

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