Determinant factor

In the applications where the compactness of the energy conversion system is the determining factor as in the case of engines, it is important to know the quantity of energy contained in a given volume of the fuel-air mixture to be burned. This information is used to establish the ultimate relations between the nature of the motor fuel and the power developed by the motor it is of prime consideration in the development of fuels for racing cars. 

Finally, sulfur has a negative effect on the performance of the catalyst itself. One sees for example in Figure 5.23 that the initiation temperature increases with the sulfur level in the diesel fuel, even between 0.01% and 0.05%. Yet, in the diesel engine, characterized by relatively low exhaust temperatures, the operation of the catalyst is a determining factor. One can thus predict an ultimate diesel fuel desulfurization to levels lower than 0.05%. 

The addition of hydrogen and the diminution of carbon are priorities demand for hydrogen is becoming a determinant factor. 

Acrylonitrile reacts with the sodium salt of 4.5-dimethvl-A-4-thiazoline-2-thione (73J (R4 = R5 = Me) to yield 3-(2-cyanoethyl)-4.5-dimethyl-A-4-thiazoline-2-thione (74) (R4 = R, = Me) (Scheme 35 (160). Humphlett s studies of this reaction showed that the size of the R4 substituent is a determinant factor for the S versus N ratio (161. 162). If R4 == H, 100% of the N-substituted product (74) is obtained this drops to 50% when R4 = methyl, and only the S-substituted product (75) is obtained when R4 = phenyl. The same trend is observed with various CH2 = CH-X (X = C00CH3. COCH3) reagents (149). The S/N ratio also depends on the electrophilic center for CH2 = CH-X systems thus S-reaction occurs predominantly with acrylonitrile, whereas N-substitution predominates with methvlvinvlketone (149). 

Prices for the different material groups (F —F ) are largely influenced by product size and shape and the quantity of production. Apart from product shape, the main price-determining factor is the performance factor K Prices for the powder, a sintered anisotropic ring, and a sintered anisotropic segment are roughly on the order of 1, 2, and 5, respectively. 

The selection of a process can be complex, requiring carehil evaluation of the many variables for each appHcation. The hemihydrate process is energy efficient, but this may not be an overriding consideration when energy is readily available from an on-site sulfuric acid plant. The energy balance in the total on-site complex may be the determining factor. 

Hydrothermal Synthesis Systems. Of the unit operations depicted in Figure 1, the pressurized sections from reactor inlet to pressure letdown ate key to hydrothermal process design. In consideration of scale-up of a hydrothermal process for high performance materials, several criteria must be considered. First, the mode of operation, which can be either continuous, semicontinuous, or batch, must be determined. Factors to consider ate the operating conditions, the manufacturing demand, the composition of the product mix (single or multiple products), the amount of waste that can be tolerated, and the materials of constmction requirements. Criteria for the selection of hydrothermal reactor design maybe summarized as... 

Thiols are shipped ia every conceivable container size. Dmms and cans can be of carbon steel for most thiols, provided color is not a determining factor. Tmck, rail, and isocontainer shipments should be set up to utilize a vapor return line from the tank to the shipping container. This substantially minimizes the amount of odor that escapes. Phillips Petroleum Company and Atochem North America can supply further information regarding the handling and properties of many thiols. 

In most ores, sufficient Fe is already present. For some ores, it is necessary to add metallic iron. In practice, the oxidation potential of the solution can be monitored and controlled using the Fe /Fe ratio. Very high leaching efficiencies with H2SO ate common, eg, 95—98% dissolution yield of uranium (39). If acid consumption exceeds 68 kg/1 of ore treated, alkaline leaching is preferred. The comparative costs of acid, sodium hydroxide, and sodium carbonate differ widely in different areas and are the determining factor. 

Generally the harder the ceramic, the better its wear resistance however, other properties such as fracture toughness may play the dominant role. If a ceramic is mated with a metal hardness is the determining factor, but when a ceramic is mated with another ceramic fracture toughness appears to determine the wear rate (54). 

Under polymerisation conditions, the active center of the transition-metal haHde is reduced to a lower valence state, ultimately to which is unable to polymerise monomers other than ethylene. The ratio /V +, in particular, under reactor conditions is the determining factor for catalyst activity to produce EPM and EPDM species. This ratio /V + can be upgraded by adding to the reaction mixture a promoter, which causes oxidation of to Examples of promoters in the eadier Hterature were carbon tetrachloride, hexachlorocyclopentadiene, trichloroacetic ester, and hensotrichloride (8). Later, butyl perchlorocrotonate and other proprietary compounds were introduced (9,10). 

Applications. Initial appHcations have been largely in military and aerospace areas. These include hydrauHc seals for military aircraft and fuel seals and diaphragms for both military and civiHan aircraft. Shock mounts for EZ are used on aircraft engines. Large fabric-reinforced boot seals are used in the air intake system on the M-1 tank. The material s useful temperature range, fuel and fatigue resistance, and fire resistance were determining factors in this appHcation. 

A feed stream to be clarified or thickened can exist at any state represented within this diagram. As it becomes concentrated owing to sedimentation, it may pass through all the regimes, and the settling rate in any one may be the size-determining factor for the required equipment. 

Analytical instruments play an increasingly important role in modern analytical chemistry. The trend is not limited in chemistry but in all phases of natural science and technology, as one easily can watch in rapid progresses in molecular biology, nano-materials technology, and the related bio-medical reseai ch. Instiaimental developments can now even be a determining factor in the advancement of science itself. 

The initial moisture content is a determinant factor in the rate of heat transfer to the center of the core mat [226,227]. At short press closing times the rapid temperature rise occurs at the same time for both lower and higher moisture content percentages indicating that the steam condensation front reaches the core at the same rate and that this is then determined more by local permeability rather than local moisture content. The slope of the rise is similar as it is the balance of horizontal and vertical permeability which controls the rate of steam flow to the core layer. Furthermore, water remains in the surface layer in a quantity such as... 

During fatigue the stress amplitude usually remains constant and brittle failure occurs as a result of crack growth from a sub-critical to a critical size. Clearly the rate at which these cracks grow is the determining factor in the life of the component. It has been shown quite conclusively for many polymeric materials that the rate at which cracks grow is related to the stress intensity factor by a relation of the form... 

The determining factor in convection is the flow boundary layer. Outside the boundary layer, the fluid is considered to have achieved a maximum velocity at an infinite distance from the surface. 

A summary of essential items to be taken into account in determining the target levels is presented in Table 6.20. The table shows that the process is the main determining factor for industrial ventilation. 

The area of design failure criteria impacts, and is a quantitative measure of, the success of a design. Fundamentally, design failure criteria are the statement of the design requirements. The manner in which individual laminae as well as laminates fail is but a part of design failure criteria. Failure of laminae and laminates, as in Chapters 2 and 4, is a fundamental portion of all strength-related failure criteria, but those failures are also determining factors in stiffness-related failure criteria. 

Although direct methods for small and medium size systems require more CPU time than disk based methods, this is in many cases irrelevant. For the user the determining factor is the time from submitting the calculation to the results being available. Over the years the speed of CPUs has increased much faster than the speed of data transfer to and from disk. Many modem machines have quite slow data transfer to disk compared to CPU speed. Measured by the elapsed wall clock time, disk based HF methods are often the slowest in delivering the results, despite the fact that they require the least CPU time. 

The Dunning-Huzinaga type basis sets do not have the restriction of the Pople style basis sets of equal exponents for the s- and p-functions, and they are tlierefore somewhat more flexible, but computationally also more expensive. The major determining factor. 

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