Butyl acetate benzoate

Successful results have been obtained (Renfrew and Chaney, 1946) with ethyl formate methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec.-butyl and iso-amyl acetat ethyleneglycol diacetate ethyl monochloro- and trichloro-acetates methyl, n-propyl, n-octyl and n-dodecyl propionates ethyl butyrate n-butyl and n-amyl valerates ethyl laurate ethyl lactate ethyl acetoacetate diethyl carbonate dimethyl and diethyl oxalates diethyl malonate diethyl adipate di-n-butyl tartrate ethyl phenylacetate methyl and ethyl benzoates methyl and ethyl salicylates diethyl and di-n-butyl phthalates. The method fails for vinyl acetate, ieri.-butyl acetate, n-octadecyl propionate, ethyl and >i-butyl stearate, phenyl, benzyl- and guaicol-acetate, methyl and ethyl cinnamate, diethyl sulphate and ethyl p-aminobenzoate. 

Esters. re-Butyl acetate Ethyl acetate Ethyl benzoate. 

Alkali metal alkoxides, r-butyl acetate neat, 45°, 30 min, 98% yield of r-butyl ester from methyl benzoate. The rate constant for the reaction increases with increasing ionic radius of the metal and with decreasing polarity of the solvent. Equilibrium for the reaction is achieved in <10 sec. Other examples eire presented. " ... 

Figure 12.11 shows the pyrograms of vinyl paints from two monochromes by the Italian artist Piero Manzoni. The two paints are clearly different in composition acetic acid (peak 1) and benzene (peak 2) are present as common markers of the PVAc binder in both cases, but sample (a) contains dibutyl phthalate (peak 6) as external plasticizer. Peak 5 was recognized as bis(2-methylpropyl)-phthalate which is formed from dibutylphthalate isomerization, while butyl acetate (peak 3) and butyl benzoate (peak 4) are secondary products of recombination reactions occurring during the pyrolysis. Sample (b), however,... 

Figure 12.11 Pyrograms of a PVAc paint containing external plasticizers (a), and of a vinyl acetate/VeoVa copolymer (b). Peak assignments 1, acetic acid, 2, benzene, 3, butyl acetate, 4, butyl benzoate, 5, bis(2 methylpropyl) phthalate, 6, dibutylphthalate, 7, branched acrylates ranging from C7 to C9...

Plots of the left-hand side of these equations against X are curved, allowing easy distinction of an A2 mechanism. Excess acidity plots using equation (59) are shown for some ester hydrolyses in sulfuric acid at 25°C in Fig. 10, for 1-butyl acetate,29 and for methyl 2,6-dimethylbenzoate and methyl benzoate.41 The first ester (leftmost line in Fig. 10) clearly undergoes an A1 hydrolysis, specifically AAil 29 the parameters of the line are slope 1.552 + 0.027 intercept... 

Fig. 10 Excess acidity plots against X for the hydrolyses of some esters in aqueous H2SO4 at 25°C for methyl benzoate (open circles) and methyl 2,6-dimethylbenzoate (closed circles), data from ref. 41, and for r-butyl acetate (open triangles), data from ref. 29. PCT, protonation correction term.

The initial study of the La3 +-catalyzed methanolysis of carboxylate esters163 reported the apparent second-order rate constant for La2 + ( OCH3)2-catalyzed methanolysis of some representative examples of aryl esters (2, 5 and 2,4-dinitrophenyl acetate (14)), phenyl benzoate (15) and three aliphatic esters, ethyl acetate, isopropyl acetate (16) and tert-butyl acetate (17). Given in Table 6 are the rate constants for the La3+ and methoxide-catalyzed methanolysis of these esters along with... 

Fntity Benzyl propionate Butyl acetate Cinnamyl anthranilate. formate Citronellyl acelate. butyrate, isobutyrate. propionate, Delta-decalactone Diethyl malunate Dimethylbenzyl carbinyl acetate Delta-dodecalactone Ethyl p-anlsate. benzoate, butyrate, heptanoate, hexanoate. maltol. nonanoate Isoamyl butyrate, hexanoate. isovalerate, cinnamate Linalyl isobutyrate. propionate Mallol Methyl benzoate, cinnamate 2-Methyl-undecanal, Nerohdol Octanol. Octyl formaie Phencthyl isobuiyrate. isovalerate gamma- Indecalactone. 

Anionic micellar systems were found to increase the rate of the acid catalyzed hydrolysis of acetylsalicylic acid (Nogami et al., 1962), methantheline bromide (Nogami and Awazu, 1962), n-butyl acetate, t-butyl acetate, ethyl p-aminobenzoate, and ethyl o-aminobenzoate (Sakurada et al., 1967), but decreased that of methyl benzoate slightly (Sakurada et al., 1967). The acid catalyzed hydrolysis of anionic amphi-philes also generally tend to be accelerated by micellization (Table 5). The rates of the acid catalyzed hydrolyses of sodium sulfoethyl do-decanoate, sodium undecanoate, and sodium sulfobutyl caprylate are significantly greater in micellar than in non-micellar solutions while that of sodium dodecyl sulfoacetate is unaffected by micelle formation (Meguro and Hikota, 1968). 

The preparations of dextran, and certain ethers and esters of dextran have been the subjects of about fifteen recent patents. The dextran (of L. mesenteroides or dextraniczim) may be precipitated first from the culture by the addition of ethanol or acetone, or the culture itself may be treated directly with the appropriate halide and sodium hydroxide in either a single stage or a two-stage procedure. The benzyl ether of dextran, formed by the reaction of dextran with benzyl chloride and sodium hydroxide at 75-185° for three to ten hours, is soluble in acetone and other solvents, and may be used in lacquers. Mixed ether and ester derivatives of dextran, e. g., benzyl and phthalate or butyl and benzoate, have been used for forming films, coatings or molded products. A preparation of dextran acetate has also been patented. ... 

Palladium(II) acetate micro-encapsulated in polyurea is an economical and versatile heterogeneous catalyst for a range of phosphine-free cross-coupling reactions in both conventional solvents and supercritical carbon dioxide. The catalyst can be recovered by simple filtration and recycled up to four times [93]. The potential of these materials has been demonstrated by their efficacy in Suzuld-type couplings. Investigations have centered upon carbonylation reactions to prepare aryl esters from commercially available aryl iodides. Treatment of iodo-methyl benzene tvith 3 mol% of catalyst in butanol and triethylamine at 90 °C under an atmosphere of carbon monoxide afforded butyl-methyl benzoate in an excellent yield of 89% in 16 h. 

HA in n-butyl acetate HA in isobutyl acetate HA in 2-butyl acetate HA in n-amyl acetate HA in isoamyl acetate HA in n-octyl acetate HA in 2-ethylhexyl acetate HA in benzyl acetate HA in ethyl propionate HA in butyl propionate HA in butyl butyrate HA in ethyl benzoate HA in butyl alcohol HA in isopropyl alcohol HA in amyl alcohol HA 0.01 in i-amyl alcohol HA 0.001 in i-amyl alcohol HA in isobutyl alcohol HA in hexyl alcohol HA in isohexyl alcohol... 

BTO. See Tributyltin oxide t-BuAc. See t-Butyl acetate BUB. See Butyl benzoate... 

Aluminum acetate Aluminum caprylate Aluminum distearate Aluminum myristates/palmitates Aluminum stearate Aluminum tristearate N-2-Aminoethyl-3-aminopropyl trimethoxysilane Aminoethylethanolamine Aminomethyl propanol Aminopropyltriethoxysilane Aminopropyltrimethoxysilane Ammonium benzoate Ammonium borate Ammonium citrate dibasic Ammonium laureth sulfate Ammonium laureth-5 sulfate Ammonium laureth-7 sulfate Ammonium laureth-12 sulfate Ammonium laureth-30 sulfate Ammonium lauryl sulfate Ammonium maleic anhydride/diisobutylene copolymer Ammonium oleate Ammonium persulfate Ammonium polyacrylate Ammonium potassium hydrogen phosphate Ammonium stearate Ammonium sulfamate Ammonium thiocyanate Ammonium thiosulfate Amyl acetate Antimony trioxide Asbestos Asphalt Azelaic acid 2,2 -Azobisisobutyronitrile Barium acetate Barium peroxide Barium sulfatej Bentonite Benzalkonium chloride Benzene Benzethonium chloride Benzothiazyl disulfide Benzoyl peroxide Benzyl alcohol Benzyl benzoate 1,3-Bis (2-benzothiazolylmercaptomethyl) urea 1,2-Bis (3,5-di-t-butyl-4-hydroxyhydrocinnamoyl) hydrazine 4,4 -Bis (a,a-dimethylbenzyl) diphenylamine Bisphenol A Bis (trichloromethyl) sulfone Boric acid 2-Bromo-2-nitropropane-1,3-diol 1,4-Butanediol Butoxydiglycol Butoxyethanol Butoxyethanol acetate n-Butyl acetate Butyl acetyl ricinoleate Butyl alcohol Butyl benzoate Butyl benzyl phthalate Butyidecyl phthalate Butylene glycol t-Butyl hydroperoxide... 

Diethylene glycol propyl ether Propyl acetate Tetrahydrofurfuryl alcohol 1,1,2-Trichloroethane solvent, creams PEG-6 abietate solvent, creams/lotions Butyl octyl benzoate Hexyldecyl benzoate Octyidodecyl isostearate Petroleum distillates Polyglyceryl-3 diisostearate Tricaprin... 

Benzyl benzoate Bornyl acetate 2-Butanol n-Butyl acetate t-Butyl alcohol Butylene glycol dicaprylate/dicaprate Butyrolactone Caprylic/capric/lauric triglyceride Caprylic/capric/linoleic triglyceride Caprylic/capric triglyceride Caprylic/capric triglyceride PEG-4 esters Carbon tetrachloride Chlorobenzene Chloroform Coconut (Cocos nucifera) oil... 

In U.S. Patent 4,174,429 [54], Montedison characterized a large number of Mg/Ti/Cl/electron donor complexes based on a wide variety of ligands such as ethyl acetate, ethanol, ethyl benzoate, benzonitrile, ethylene carbonate, n-butyl acetate and diethyl ether, using TiClj prepared from hydrogen reduction of TiCl. ... 

Sabinol, 75 Saccharic acid, 33 Salicylaldehyde, 52 Salicylamide, 49 Salicylic acid, 40, 48, 51, 52 acetyl-, 13 Salicyluric acid, 49 Saligenin, 15 Santenone, 79 Scurvy, 18 Sodium alginate, 20 Sodium benzoate, 31 Sodium n-butyrate, 29 Sodium feri-butyl acetate, 29 Stilbestrol, 81, 84 Streptomycin, 70 Synovial fluid, 15, 16 Syringaldehyde, 53 Sulfadiazine, 14, 62 Sulfamerazine, 62 Sulfamezathine, 62 Sulfanilamide, 61, 63 Sulfapyridine, 61, 62 Sulfathiazole, 61... 

Figure 25 Confocal scanning microscopy images and the corresponding cross sections of polystyrene films, when printed from (a) the single solvent butyl acetate, or using a solvent mixture of (b) methyl benzoate and ethyl acetate, or (c) acetophenone and isopropyl acetate. Reprinted with permission from Tekin, E. de Gans, B.-J. Schubert, U. S. J. Mater. Chem. 2004,14,2627. Copyright 2010 the Royal Society of Chemistry.

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