Benzyl alcohol ethyl benzoate

Quinoline Cinnamyl alcohol p-Methylacetophenone Benzyl acetate Ethyl benzoate... [Pg.315]

Isoamyl acetate n-Amyl cyanide Benzene Benzyl ether 2 Bromoethyl acetate Chloroform Cinnamaldehyde Di-n amylarnine Di-n-butyl carbonate Diethvlacetic acid Diethylcnetnamme Diethyl formamide Diisobutyl ketone Diisopropvlamine Di-n-propvlamlme Ethyl alcohol Ethyl benzoate Ethyl ether Ethyl phenyUcetate Heptadecanol ... [Pg.452]

Phenetidine Ethyl fumarate Ethyl maleate Ethyl succinate Octyl alcohol sec-Octyl alcohol Butyl sulfide Quinoline Cinnamyl alcohol p-Methylacetophenone Benzyl acetate Ethyl benzoate 3-Phenylpropanol Phorone Naphthalene... [Pg.166]

Acetophenone Benzyl formate Methyl benzoate Methyl benzoate Phenyl acetate m-Dimethoxybenzene Propyl oxalate 2-Octanone Isoamyl lactate Octyl alcohol Ethyl benzoate Mesitylene Propylbenzene Benzyl ethyl ether Phorone... [Pg.210]

The catalyst is inactive for the hydrogenation of the (isolated) benzene nucleus and so may bo used for the hydrogenation of aromatic compounds containing aldehyde, keto, carbalkoxy or amide groups to the corresponding alcohols, amines, etc., e.g., ethyl benzoate to benzyl alcohol methyl p-toluate to p-methylbenzyl alcohol ethyl cinnamate to 3 phenyl 1-propanol. [Pg.873]

Fife and Benjamin, 1973. The reference reaction is attack by alkoxide on ethyl benzoate estimated from the known second order rate constant for attack by hydroxide in water at 25° (Bender, 1951) and allowing a factor of 10 for the higher reactivity of alkoxides (Gilchrist and Jencks, 1960). The pX,-value is taken as that of benzyl alcohol (Takahashi el al., 1971)... [Pg.246]

Other hydrides used for the conversion of esters to alcohols are magnesium aluminum hydride in tetrahydrofuran [89, 577] and magnesium bromohydride prepared by decomposition of ethylmagnesium bromide at 235° for 2.5 hours at 0.5mm [7055]. They do not offer special advantages (the latter giving only 35% yield of benzyl alcohols from ethyl benzoate). [Pg.156]

The oxidation of benzaldoxime with perchloryl fluoride (FClOj) has been reported [29 a) to give a complex mixture in which benzaldoxime benzoate and diphenyl oxadiazole are the main products. Sodium nitrohydroxamate [Na2(02NN0)] has been reported [99b) to oxidize benzyl chloride to a mixture of compounds from which benzyl alcohol, benzaldehyde, benzoic acid, 3,4,5-triphenylisoxazole, benzyl-ethyl-ether, phenylnitromethane and diphenyloxadiazole have been isolated. [Pg.172]

Methyl n-amyl carbinol. 247, 254 Methyl n-amyl ketone, 482 Methylaniline (mono), pure, from commercial methylaniline, 562, 570 P-Methylanthraquinone, 728, 740 Methyl benzoate, 780, 781 p-Methyl benzyl alcohol, 811,812 Methyl benzyl ketone, 727, 735 Methyl y-bromocrotonate, 926, 927 2-Methyl-2-butene, 239 Methyl n-butyl carbinol, 247,255 Methyl n-butyl ether, 314 Methyl n-butyl ketone, 475, 481 4-Methylcarbostyril, 855 p-Methylcinnamic acid, 719 4-Methylcoumarin, 853, 854 Methyl crotonate, 926, 927 Methylethylacetic acid, 354, 358 Methylethylethynyl carbinol, 468 Methyl ethyl ketone, 335, 336 purification of, 172 Methyl n-hexyl ether, 314 Methyl n-hexyl ketone, 335, 336 Methyl n-hexyl ketoxime, 348 Methyl hydrogen adipate, 938 Methyl hydrogen sebacate, 938,939 4-Methyl-7-hydroxycoumarin, 834 Methyl iodide, 287 Methyl isopropyl carbinol, 247,255 Methyl 4-keto-octanoate, 936... [Pg.1179]

Figure 25-12 Isocratic HPLC separation of a mixture of aromatic compounds at 1.0 mL/min on a 0.46 x 25 cm Hypersil ODS column (C,8 on 5-jxm silica) at ambient temperature ( 22 C) (1) benzyl alcohol (2) phenol (3) 3, 4 -dimethoxyacetophenone (4) benzoin (5) ethyl benzoate (6) toluene (7) 2,6-dimethoxytoluene (8) o-methoxybiphenyl. Eluent consisted ot aqueous buffer (designated A) and acetonitrile (designated B). The notation 90% B in the first chromatogram means 10 vol% A and 90 vol% B. The buffer contained 25 mM KH2P04 plus 0.1 g/L sodium azide adjusted to pH 3.5 with HCI.

Propyl chloride Chlorobenzene. Bromobenzene. a-bromnaphthalene Ethyl ether. , Ethylisoamyl ether Phenetol.. . Anisol. . . Ethyl acetate. Isobutyl acetate Ethyl benzoate Isobutyl alcohol Ethyl alcohol. Allyl alcohol. Methyl alcohol Benzyl alcohol. Acetone. . . Acetophenone. ... [Pg.220]

Nonactivated esters are reduced only slowly if at all in strongly acidic medium at a lead cathode [45], whereas alkyl benzoates are reduced to a mixture of benzyl alcohol and alkyl benzyl ether [45,46], and alkyl 4-imidazolecarboxylates similarly are reduced to a mixture of the corresponding alcohol and ether [76]. Phenyl and benzyl benzoate give predominantly esters [23,34], as do also ethyl o-chloro- and m-bromobenzoate [46]. [Pg.459]

Other reductions. Miller et report reduction of benzoic acid and of methyl benzoate to benzyl alcohol and of n-butyl caproate to n-butanol and n-hexanoL Russian investigators" report reduction of aliphatic and aromatic esters to aldehydes, of ortho esters to acetals, of acetals to ethers, and of benzyl ethyl ether to toluene. [Pg.134]

Fig. 2. Correlation of the rates of hydrogenation of 1-hexene with the parameters r 1, hexane 2, cyclohexane 3, dibutyl ether 4, diethyl ether 5, cumene 6, 1-butanol 7, ethyl benzene 8, 1-propanol 9, ethanol 10, toluene 11, methanol 12, benzene 13, ethyl acetate 14, tetrahydrofuran 15, 1,4-dioxane 16, benzyl alcohol 17, diethyl malonate 18, ethyl benzoate 19, 1,1,2,2-tetrachloroethane.

Diazepam IM/IV 40% Propylene glycol 10% Ethyl alcohol 5% Benzoate buffer 1.5% Benzyl alcohol Inject slowly (at least 1 min/mL) if giving IV. Do not use small veins. [Pg.338]

The use of electricity in reactions is clean and, at least in some cases, can produce no waste. Toxic heavy metal ions need not be involved in the reaction. Hazardous or expensive reagents, if needed, can be generated in situ where contact with them will not occur. The actual oxidant is used in catalytic amounts, with its reduced form being reoxidized continuously by the electricity. In this way, 1 mol% of ruthenium(III) chloride can be used in aqueous sodium chloride to oxidize benzyl alcohol to benzaldehyde at 25°C in 80% yield. The benzaldehyde can, in turn, be oxidized to benzoic acid by the same system in 90% yield.289 The actual oxidant is ruthenium tetroxide. Naphthalene can be oxidized to naphthoquinone with 98% selectivity using a small amount of cerium salt in aqueous methanesulfonic acid when the cerium(III) that forms is reoxidized to cerium(IV) electrically.290 Substituted aromatic compounds can be oxidized to the corresponding phenols electrically with a platinum electrode in trifluoroacetic acid, tri-ethylamine, and methylene chloride.291 With ethyl benzoate, the product is a mixture of 44 34 22 o/m/fhhy-... [Pg.92]

Diazepam is a lipid-soluble but water-insoluble substance. The solvent for parenteral diazepam, it consists of 40% propylene glycol, 10% ethyl alcohol, 5% sodium benzoate, and 1.5% benzyl alcohol. Injection site complications such... [Pg.196]

Acetate, CaHHOy needles from alcohol, mp 149-151 . Mi +22 (alcohol). Soly (g/100 ml of soln) carbon tetrachloride 50. petr ether l.O, ethyl acetate 7.9 acetone 2.7 chloroform 55.0 ethanol 2.5 benzene 26.0 isopropanol 2.0. Soly (g/100 ml of solvent) propylene glycol 0.1 dioxane 20.2 benzyl alcohol It.] benzyl benzoate 9.1. [Pg.1226]

Ethyl benzoate Copper chromium oxide 125 -4,500 Benzyl alcohol 4... [Pg.584]

Ethyl benzoate reacts with lithium aluminum hydride to give benzyl alcohol and ethanol. [Pg.838]

HA in n-butyl acetate HA in isobutyl acetate HA in 2-butyl acetate HA in n-amyl acetate HA in isoamyl acetate HA in n-octyl acetate HA in 2-ethylhexyl acetate HA in benzyl acetate HA in ethyl propionate HA in butyl propionate HA in butyl butyrate HA in ethyl benzoate HA in butyl alcohol HA in isopropyl alcohol HA in amyl alcohol HA 0.01 in i-amyl alcohol HA 0.001 in i-amyl alcohol HA in isobutyl alcohol HA in hexyl alcohol HA in isohexyl alcohol... [Pg.336]

Benzoylacetyl. See 1-Phenyl-1,2-propanedione Benzoyl alcohol. See Benzyl alcohol Benzoylaminoacetic acid. See Hippuric acid o-(Benzoylamino) diphenyl disulfide. See 2,2 -Dibenzamidodiphenyl disulfide Benzoylbenzene. See Benzophenone 2-Benzoyl benzoic acid methyl ester o-Benzoylbenzoic acid methyl ester. See o-M ethyl benzoyl benzoate 4-Benzoylbiphenyl... [Pg.460]

Ethyl benzoate Isopropyl alcohol Methyl propionate Propyl acetate solvent, cellulose esters Acetophenone Amyl formate Benzyl alcohol Benzyl formate Dibutyl tartrate Diethyl oxalate Epichlorohydrin Ethyl butyrate Ethylene glycol diacetate Ethyl propionate... [Pg.5688]

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