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Hydrolysis, acid-catalyzed

As an example, experimental kinetic data on the hydrolysis of amides under basic conditions as well as under acid catalysis were correlated with quantitative data on charge distribution and the resonance effect [13]. Thus, the values on the free energy of activation, AG , for the acid catalyzed hydrolysis of amides could be modeled quite well by Eq. (5)... [Pg.183]

Hydrolysis (Sections 20 10 and 20 11) Ester hydrolysis may be catalyzed either by acids or by bases Acid catalyzed hydrolysis is an equilibrium controlled process the reverse of the Fischer esterification Hydrolysis in base IS irreversible and is the method usual ly chosen for preparative purposes... [Pg.849]

The mechanism of acid catalyzed ester hydrolysis is presented m Figure 20 4 It IS precisely the reverse of the mechanism given for acid catalyzed ester formation m Section 19 14 Like other nucleophilic acyl substitutions it proceeds m two stages A... [Pg.849]

FIGURE 20 4 The mecha nism of acid catalyzed ester hydrolysis Steps 1 through 3 show the formation of the tetrahedral intermediate Dissociation of the tetrahe dral intermediate is shown in steps 4 through 6... [Pg.850]

On the basis of the general mechanism for acid catalyzed ester hydrolysis shown in Figure 20 4 write an analogous sequence of steps for the spe cific case of ethyl benzoate hydrolysis... [Pg.851]

Unlike Its acid catalyzed counterpart ester hydrolysis m aqueous base is irreversible O O... [Pg.852]

In an extension of the work described m the preceding section Bender showed that basic ester hydrolysis was not concerted and like acid hydrolysis took place by way of a tetrahedral intermediate The nature of the experiment was the same and the results were similar to those observed m the acid catalyzed reaction Ethyl benzoate enriched m 0 at the carbonyl oxygen was subjected to hydrolysis m base and samples were isolated before saponification was complete The recovered ethyl benzoate was found to have lost a por tion of Its isotopic label consistent with the formation of a tetrahedral intermediate... [Pg.855]

Section 20 11 Ester hydrolysis m basic solution is called saponification and proceeds through the same tetrahedral intermediate (Figure 20 5) as m acid catalyzed hydrolysis Unlike acid catalyzed hydrolysis saponification is irreversible because the carboxylic acid is deprotonated under the reac tion conditions... [Pg.876]

Because cyano groups may be hydrolyzed to carboxylic acids (Section 20 19) the Sand meyer preparation of aryl nitriles is a key step m the conversion of arylammes to sub stituted benzoic acids In the example just cited the o methylbenzomtnle that was formed was subsequently subiected to acid catalyzed hydrolysis and gave o methylbenzoic acid in 80-89% yield... [Pg.948]

This reaction has been used m an imaginative way to determine the ring size of glycosides Once all the free hydroxyl groups of a glycoside have been methylated the glycoside is subjected to acid catalyzed hydrolysis Only the anomeric methoxy group IS hydrolyzed under these conditions—another example of the ease of carbocation for matron at the anomeric position... [Pg.1059]

Basing your answers on the general mechanism for the first stage of acid catalyzed acetal hydrolysis... [Pg.1067]

Phlonzm is obtained from the root bark of apple pear cherry and plum trees It has the molecular formula C21H24O10 and yields a compound A and D glucose on hydrolysis in the pres ence of emulsin When phlorizin is treated with excess methyl iodide in the presence of potassium carbonate and then subjected to acid catalyzed hydrolysis a compound B is obtained Deduce the structure of phlorizin from this information... [Pg.1068]

Whereas acid catalyzed hydrolysis of peptides cleaves amide bonds indiscriminately and eventually breaks all of them enzymatic hydrolysis is much more selective and is the method used to convert a peptide into smaller fragments... [Pg.1130]

Manufacture of Fatty Acids and Derivatives. Splitting of fats to produce fatty acids and glycerol (a valuable coproduct) has been practiced since before the 1890s. In early processes, concentrated alkaU reacted with fats to produce soaps followed by acidulation to produce the fatty acids. Acid-catalyzed hydrolysis, mostly with sulfuric and sulfonic acids, was also practiced. Pressurized equipment was introduced to accelerate the rate of the process, and finally continuous processes were developed to maximize completeness of the reaction (105). Lipolytic enzymes maybe utilized to spHt... [Pg.135]

Some unsaturated ketones derived from acetone can undergo base- or acid-catalyzed exothermic thermal decomposition at temperatures under 200°C. Experiments conducted under adiabatic conditions (2) indicate that mesityl oxide decomposes at 96°C in the presence of 5 wt % of aqueous sodium hydroxide (20%), and that phorone undergoes decomposition at 180°C in the presence of 1000 ppm iron. The decomposition products from these reactions are endothermic hydrolysis and cleavage back to acetone, and exothermic aldol reactions to heavy residues. [Pg.487]


See other pages where Hydrolysis, acid-catalyzed is mentioned: [Pg.475]    [Pg.42]    [Pg.655]    [Pg.330]    [Pg.336]    [Pg.466]    [Pg.475]    [Pg.422]    [Pg.475]    [Pg.42]    [Pg.655]    [Pg.330]    [Pg.336]    [Pg.466]    [Pg.475]    [Pg.422]    [Pg.168]    [Pg.83]    [Pg.159]    [Pg.681]    [Pg.684]    [Pg.746]    [Pg.848]    [Pg.849]    [Pg.851]    [Pg.852]    [Pg.1067]    [Pg.1133]    [Pg.1228]    [Pg.119]    [Pg.239]    [Pg.423]    [Pg.357]    [Pg.272]   
See also in sourсe #XX -- [ Pg.173 ]

See also in sourсe #XX -- [ Pg.22 , Pg.47 , Pg.172 ]

See also in sourсe #XX -- [ Pg.172 ]

See also in sourсe #XX -- [ Pg.172 ]

See also in sourсe #XX -- [ Pg.11 , Pg.361 ]

See also in sourсe #XX -- [ Pg.11 , Pg.361 ]

See also in sourсe #XX -- [ Pg.1003 , Pg.1008 , Pg.1011 , Pg.1012 ]

See also in sourсe #XX -- [ Pg.851 ]

See also in sourсe #XX -- [ Pg.193 , Pg.193 ]




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1- Phenylcyclohexene oxides acid-catalyzed hydrolysis

Acetals, acid catalyzed hydrolysis

Acid catalyzed hydrolysis of aliphatic diazo compounds

Acid catalyzed hydrolysis reaction rate

Acid-Catalyzed Amide Hydrolysis and Alcoholysis

Acid-Catalyzed Epoxide Hydrolysis

Acid-Catalyzed Ester Hydrolysis and Transesterification

Acid-Catalyzed Hydrolysis of Glycofuranosides

Acid-catalyzed ester hydrolysis

Acid-catalyzed ester hydrolysis correlation

Acid-catalyzed ester hydrolysis mechanism

Acid-catalyzed ester hydrolysis rate constants

Acid-catalyzed hydrolysis pesticides

Acid-catalyzed hydrolysis, of epoxide

Acid—base catalyzed formation and hydrolysis of epoxides

Aliphatic epoxides acid-catalyzed hydrolysis

Amide acid-catalyzed hydrolysis

Amino acids hydrolysis, metal-catalyzed

BeMiller, J. N., Acid-catalyzed Hydrolysis of Glycosides

Carboxylic acid esters base-catalyzed hydrolysis

Carboxylic acids hydrolysis, metal-catalyzed

Deprotection by Acid-Catalyzed Hydrolysis

Enol ethers, acid-catalyzed hydrolysis

Epoxides acid-catalyzed hydrolysis

Glycosides acid-catalyzed hydrolysis

Hydrolysis acid-catalyzed, of glycosides

Hydrolysis, acetic-acid-catalyzed

Indene oxides acid-catalyzed hydrolysis

Isocyanides, acid catalyzed hydrolysis

Mechanism acid catalyzed hydrolysis

Oximes, acid catalyzed hydrolysis

Proteins acid-catalyzed hydrolysis

Quinoline-2-carboxylic-acid, 8-hydroxymethyl ester hydrolysis, metal-catalyzed

Reactions acid-catalyzed hydrolysis

Saponins, acid-catalyzed hydrolysis

Tertiary epoxides acid-catalyzed hydrolysis

The Acid-Catalyzed Hydrolysis of Glycopyranosides

Vinyl epoxides acid-catalyzed hydrolysis

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