Amyl Valerate

Successful results have been obtained (Renfrew and Chaney, 1946) with ethyl formate methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec.-butyl and iso-amyl acetat ethyleneglycol diacetate ethyl monochloro- and trichloro-acetates methyl, n-propyl, n-octyl and n-dodecyl propionates ethyl butyrate n-butyl and n-amyl valerates ethyl laurate ethyl lactate ethyl acetoacetate diethyl carbonate dimethyl and diethyl oxalates diethyl malonate diethyl adipate di-n-butyl tartrate ethyl phenylacetate methyl and ethyl benzoates methyl and ethyl salicylates diethyl and di-n-butyl phthalates. The method fails for vinyl acetate, ieri.-butyl acetate, n-octadecyl propionate, ethyl and >i-butyl stearate, phenyl, benzyl- and guaicol-acetate, methyl and ethyl cinnamate, diethyl sulphate and ethyl p-aminobenzoate. 

Valerian-Sl, n. valerian oil. -sSure, /. valeric acid, valerianic acid. -sMureamylather, m. amyl valerate. -sSuresalz, n. salt of valeric acid, valerate. 

Indeed, it was found that amyl alcohol is converted into amyl nitrite and nitrate by the action of nitric oxides resulting from the decomposition of nitrocellulose. These substances are then oxidized to form valeric acid and amyl valerate products distinguishable by their characteristic smell. 

The slight solubility of yellow phosphorus in several other liquids has been notioed— e.g. ethyl chloride, ethylene chloride, chloroform, bromoform, ohloral, acetic ether, acetone aldehyde, cacodyl sulphide, allyl thiooyanate, mercury methide, valerianic acid, amyl valerate, fusel oil, benzoyl chloride, stannic chloride, ethyl nitrite, nicotine, coniine, cavutchin, styrene, aniline, quinoline, creosote, etc. J. Hartmann found that 100 grms. of bile at 38-5° dissolved 0 02424 grm. of phosphorus, and more at a higher temp. 

Esters.— The simplest class of compounds present in essential oils are the esters or ethereal salts (p. 140). In our early discussion of these compounds in the aliphatic series it was stated that the odor and flavor of common fruits is probably due to ester compounds and that certain empirical mixtures of esters are used as artificial fruit essences. Artificial apple essence, for example, may be prepared by mixing certain proportions of ethyl nitrite, ethyl acetate and amyl valerate with chloroform, aldehyde and alcohol. An example of an essential oil which consists of a single ester is oil of wintergreen. vAdxh is the methyl ester of salicylic acid, ortho-hydroxy benzoic acid (p. 714). 

Amyl acetate Amyl butyrate Amyl valerate Aenthol Anisyl formate Benzyl acetate Benzyl isobutyrate Butyric acid Cinnamyl valerate Cognac essential oil Diacetyl Dipropyl ketone Ethanol Ethyl acetate... 

N-Pentyl-1-pentanamine. See Di-n-amylamine Pentyl pentanoate. See Amyl valerate Pentyl pentylamine. See Di-n-amylamine p-t-Pentylphenol. See p-t-Amylphenol Pentylphenylacetate. See Amyl phenylacetate... 

Pentyl propanoate Pentyl propionate n-Pentyl propionate. See Amyl propionate Pentyl salicylate. See Amyl salicylate Pentyltrichlorosilane. See Amyltrichlorosilane Pentyl valerate. See Amyl valerate Pentyl vinyl carbinol. See 1-Octen-3-ol n-Pentyl vinyl carbinol acetate. See 1-Octen-3-yl acetate... 

Amyl phenylacetate Amyl valerate Amyris (Amyris balsamifera) oil trans-Anethole Anisaldehyde diethyl acetal Anise (Pimpinella anisum) extract p-Anisonitrile Anisyl alcohol o-Anisyl alcohol p-Anisyl isobutyrate Bay (Pimenta acris) oil Benzaldehyde propylene glycol acetal Benzothiazole Benzylacetone 2-Benzylheptanol Benzyl isoamyl ether Benzyl isovalerate Benzyl methyl ether Benzyl octanoate ... 

Fluometuron Meturon 4L Meturon 80DF 2167-23-9 Aztec BU-50-AL Aztec BU-50-WO 2,2-Di (t-butylperoxy) butane Perhexa 22 2173-56-0 Amyl valerate... 

Dimethyl octanal 2-Ethyl hexyl vinyl ether Menthol d-Neomenthol Rhodinol (-)-Rhodinol C10H20O2 Amyl valerate Butyl hexanoate Butyl isohexanoate Capric acid... 

AMYL VALERATE. (CHjljCHCHjCOOCsH,. Laboratory tests indicated that 1100 alloy was resistant to concentrated amyl valerate at ambient temperature. Amyl valerate is handled in aluminum containers. See also Ref (7) pp. 20, 21. 

---