Alcohols benzyl alcohol

Aliy alcohol tert-Butyi alcohol Benzyl alcohol Phenethyi alcohol Ethylene glycol 1,2-Propylene glycol Glycerol Pentaerythritoi Pinacoi Phenol... 

Benzyl Alcohol and p-Phenylethyl Alcohols" ia ECT 1st ed., Vol. 2, pp. 483—489, by H. L. Simons and E. E. Polger, Harold L. Simons, Inc. (Benzyl alcohol), and E. T. Theimer, van Ametingen-Haebler, Inc. (P-Phenylethyl alcohol) "Benzyl Alcohol and P-Phenylethyl Alcohol" ia ECT 2nd ed., pp. 442—449, by William E. Ringk, Benzol Products Company (Benzyl alcohol), and E. T. Theimer, International Elavors Eragrances, Inc. (P-Phenylethyl... 

Alcohols. n-Butyl alcohol n-Hexyl alcohol alcohol Benzyl alcohol Glycerol Sucrose. 

Benzyl Alcohols. Benzyl alcohols of nearly all kinds undergo reduction when treated with acid in the presence of organosilicon hydrides. The most obvious exception to this is the behavior of benzyl alcohol itself. It resists reduction by the action of trifluoroacetic acid and triethylsilane, even after extended reaction times.26 Reducing systems consisting of triethylsilane and sulfuric acid/acetic acid or p-toluenesullonic acid/acetic acid mixtures also fail to reduce benzyl alcohol to toluene.134 As previously mentioned, substitution of boron trifluoride for trifluoroacetic acid results in the formation of modest yields of toluene, but only when a very large excess of the silane is used in order to capture the benzyl cation intermediate and suppress Friedel-Crafts oligomerization processes.129,143... 

Benzyl chloride undergoes all the transformations of the alkyl halides. Hydrolysis with hot aqueous alkalis yields the corresponding alcohol, benzyl alcohol C6H5.CH2OH, a colourless liquid which boils at 206°. (Chap. V. 4, p. 220.)... 

Photolytic. Photolysis of permethrin in aqueous solutions containing various solvents (acetone, hexane, and methanol) under UV light (1 >290 nm) or on soil in natural sunlight initially resulted in the isomerization of the cyclopropane moiety and ester cleavage. Photolysis products identified were 3-phenoxybenzyldimethyl acrylate, 3-phenoxybenzaldehyde, 3-phenoxybenzoic acid, mono-chlorovinyl acids, cis- and fra/is-dichlorovinyl acids, benzoic acid, 3-hydroxybenzoic acid, 3-hydroxybenzyl alcohol, benzyl alcohol, benzaldehyde, 3-hydroxybenzaldehyde, and 3-hydroxybenzoic acid (Holmstead et ah, 1978). 

Benzyl alcohol Benzyl alcohol, which is contained in some of these products as a preservative, has been associated with an increased incidence of neurological and other complications in premature infants that are sometimes fatal. 

Benzyl alcohol Benzyl alcohol, a preservative contained in the diluent supplied, has been associated with a fatal gasping syndrome in premature infants. 

Nitrobenzene Tetrachloretbene Amyl alcohol. .. Propyl alcohol. .. Benzyl alcohol. .. 28,530 30,390 33,190 33,750 35,920... 

Polycyclic Aromatic Hydrocarbons, Four-Ring Compounds Potassium Primary Alcohols Benzyl Alcohol Butanol, n Ethanol Methanol Primary Alcohols... 

In organic media, the process involves the reduction of V2O5 with isobutyl alcohol, benzyl alcohol and addition of orthophosphoric acid. 

Naftifine hydrochloride Naftin Cetyl alcohol, cetyl esters wax, isopropyl myristate, polysorbate 60, sorbitan monostearate, and stearyl alcohol Benzyl alcohol... 

Allyl alcohol n-Amyl alcohol tert-Amvl alcohol Benzyl alcohol... 

The cyclohexanol may be replaced by benzyl alcohol. Benzyl alcohol is reported to give a slightly increased rate of formation of diazomethane and a slightly more concentrated ethereal solution however, the over-all yield is somewhat lower. If only a small amount of diazomethane is wanted, concentrated aqueous sodium hydroxide may replace the solution of the alkoxide of cyclohexanol. The yield under these conditions is 40-50%. 

BENZYL ALCOHOL AND /J-PHENETHYL ALCOHOL. Benzyl alcohol [CAS 100-51-6], (1) /1-phenethyl alcohol (2) (2-phenylethauol) are the simplest of the aromatic alcohols, and. as such, are chemically similar. Their physical properties are given in Table I. 

Disposition in the Body. Rapidly hydrolysed to benzoic acid and benzyl alcohol benzyl alcohol then undergoes further oxidation to benzoic acid followed by conjugation with glycine to form hippuric acid. Excreted in the urine mainly as hippuric acid. 

Propyl chloride Chlorobenzene. Bromobenzene. a-bromnaphthalene Ethyl ether. , Ethylisoamyl ether Phenetol.. . Anisol. . . Ethyl acetate. Isobutyl acetate Ethyl benzoate Isobutyl alcohol Ethyl alcohol. Allyl alcohol. Methyl alcohol Benzyl alcohol. Acetone. . . Acetophenone. ... 

Reduction.—On reduction with sodium the acid yields the corresponding alcohol, benzyl alcohol, which by hydrogen iodide and phosphorus is further reduced to the hydrocarbon toluene. This last reducing agent also reduces the acid directly to the hydrocarbon. 

Benzyl benzoate is metabolized by rapid hydrolysis to benzoic acid and benzyl alcohol. Benzyl alcohol is then further metabolized to hippuric acid, which is excreted in the urine. 

Selective oxidation of benzylic alcohols Benzylic alcohols are selectively oxidized in the presence of primary alcohols. 

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