Seriousness

A classic in its field, giving a splendid survey of solution physical chemistry from a chemist s point of view. While seriously out of date, it nevertheless provides physical insight into how molecules "behave" in mixtures. 

Unfortunately, the ideal-gas assumption can sometimes lead to serious error. While errors in the Lewis rule are often less, that rule has inherent in it the problem of evaluating the fugacity of a fictitious substance since at least one of the condensable components cannot, in general, exist as pure vapor at the temperature and pressure of the mixture. 

This chapter uses an equation of state which is applicable only at low or moderate pressures. Serious error may result when the truncated virial equation is used at high pressures. 

Two generally accepted models for the vapor phase were discussed in Chapter 3 and one particular model for the liquid phase (UNIQUAC) was discussed in Chapter 4. Unfortunately, these, and all other presently available models, are only approximate when used to calculate equilibrium properties of dense fluid mixtures. Therefore, any such model must contain a number of adjustable parameters, which can only be obtained from experimental measurements. The predictions of the model may be sensitive to the values selected for model parameters, and the data available may contain significant measurement errors. Thus, it is of major importance that serious consideration be given to the proper treatment of experimental measurements for mixtures to obtain the most appropriate values for parameters in models such as UNIQUAC. 

Vapor cloud explosions. Explosions which occur in the open air are vapor cloud explosions. A vapor cloud explosion is one of the most serious hazards in the process industries. Although a large toxic release may have a greater disaster potential, vapor cloud explosions tend to occur more frequently. Most vapor cloud explosions have been the result of leaks of flashing flammable liquids. 

The third of the major hazards and the one with the greatest disaster potential is the release of toxic chemicals. The hazard posed by toxic release depends not only on the chemical species but also on the conditions of exposure. The high disaster potential from toxic release arises in situations where large numbers of people are briefly exposed to high concentrations of toxic material, i.e., acute exposure. However, the long-term health risks associated with prolonged exposure at low concentrations, i.e., chronic exposure, also present serious hazards. 

I6I C. Warfarin baits need contain only 0 025% active principle, and rats are killed after ingesting about 5 doses the bait can be left down and the risk of acute toxicity to man or domestic animals is not serious. In common with other coumarin derivatives, warfarin reduces the clotting power of blood and death is caused by haemorrhages initiated by any slight injury. Warfarin is a vitamin K antagonist, and large oral doses of the vitamin can be given as an antidote. 

Work expands so as to fill the time available for its completion that law underlies this extraordinarily tunny and witty book (Stephen Potter in the Sunday Times) which also makes some painfully serious points for those in business or the Civil Service. 

The properties linked to storage and distribution do not directly affect the performance of engines and burners, but they are important in avoiding upstream incidents that could sometimes be very serious. We will examine in turn the problems specific to gasoline, diesel fuel, jet fuel and heavy fuel. 

It should be noted finally that adding gasoline to diesel fuel which was sometimes recommended in the past to improve cold behavior conflicts with the flash point specifications and presents a serious safety problem owing to the presence of a flammable mixture in the fuel tank airspace. Adding a kerosene that begins to boil at 150°C does not have the Scune disadvantage from this point of view. 

During storage, sediments decant with the water phase and deposit along with paraffins and asphalts in the bottoms of storage tanks as thick sludges or slurries (BS W). The interface between the water-sediment and the crude must be well monitored in order to avoid pumping the slurry into the refinery s operating units where it can cause serious upsets. 

Regardless of their presence in very small amounts, on the order of a few dozen ppm (Table 8.14), mineral salts cause serious problems during crude oil treatment. 

It was pointed out, that the periodical inspection of the steam drums has been become an absolute must especially under the circumstance, that the economical pressure results in smaller wall thickness, higher steam pressure and higher rotation speed. The conventional periodical inspection (hydrotest and visual inside inspection) is on one hand time consuming and therefore expensive and on the other hand the results of the hydrotest are doubtful and can result in a seriously damage of the roundness and balance of the steam drum. 

It was also shown, that serious defects were detected, which under normal circumstances could lead to dangerous situations in the following service periods and cannot be detected by the normal conventional testing method. 

Availability of a representative set of data examples. Such a set may significantly simplify construction of any automatic interpretation system. The example data is usually obtained from calibration pieces, however, they usually represent only the most common defects and are usually expensive to manufacture. Recently more and more data is stored as digital inspection records, unfortunately the stored data is rarely fully classified, as this would increase the cost of inspection (usually only the serious defects are given full description in the reports). 

Neural network classifiers. The neural network or other statistical classifiers impose strong requirements on the data and the inspection, however, when these are fulfilled then good fully automatic classification systems can be developed within a short period of time. This is for example the case if the inspection is a part of a manufacturing process, where the inspected pieces and the possible defect mechanisms are well known and the whole NDT inspection is done in repeatable conditions. In such cases it is possible to collect (or manufacture) as set of defect pieces, which can be used to obtain a training set. There are some commercially available tools (like ICEPAK [Chan, et al., 1988]) which can construct classifiers without any a-priori information, based only on the training sets of data. One has, however, always to remember about the limitations of this technique, otherwise serious misclassifications may go unnoticed. 

When heat-electric generating station turbine rotors are under operation there is a probability of forming surface cracks in axial canal and heat grooves. Evolution of the above defects can cause a serious crash. Therefore, in accordance with safety standards periodic inspection of the rotor component parts is required. 

With a standard image intensifier, characterized by a gain of more than x10,000, the quantum well effect is clearly avoided. Nevertheless this very high gain reduces the image dynamics unless strong attenuation is introduced at the tube output (iris or neutral filter). Also a standard intensifier is bulky, affected by pincushion distortion and magnetic fields which can be a serious limitation in some applications. 

Harkins and Jordan [43] found, however, that Eq. 11-26 was generally in serious error and worked out an empirical correction factor in much the same way as was done for the drop weight method. Here, however, there is one additional variable so that the correction factor/ now depends on two dimensionless ratios. Thus... 

This method suffers from two disadvantages. Since it measures 7 or changes in 7 rather than t directly, temperature drifts or adventitious impurities can alter 7 and be mistakenly attributed to changes in film pressure. Second, while ensuring that zero contact angle is seldom a problem in the case of pure liquids, it may be with film-covered surfaces as film material may adsorb on the slide. This problem can be a serious one roughening the plate may help, and some of the literature on techniques is summarized by Gaines [69]. On the other hand, the equipment for the Wilhelmy slide method is simple and inexpensive and can be just as accurate as the film balance described below. 

To first order, the dispersion (a-a) interaction is independent of the structure in a condensed medium and should be approximately pairwise additive. Qualitatively, this is because the dispersion interaction results from a small perturbation of electronic motions so that many such perturbations can add without serious mutual interaction. Because of this simplification and its ubiquity in colloid and surface science, dispersion forces have received the most significant attention in the past half-century. The way dispersion forces lead to long-range interactions is discussed in Section VI-3 below. Before we present this discussion, it is useful to recast the key equations in cgs/esu units and SI units in Tables VI-2 and VI-3. 

Other SFA studies complicate the picture. Chan and Horn [107] and Horn and Israelachvili [108] could explain anomalous viscosities in thin layers if the first layer or two of molecules were immobile and the remaining intervening liquid were of normal viscosity. Other inteipretations are possible and the hydrodynamics not clear, since as Granick points out [109] the measurements average over a wide range of surface separations, thus confusing the definition of a layer thickness. McKenna and co-workers [110] point out that compliance effects can introduce serious corrections in constrained geometry systems. 

The listing of techniques in Table Vlll-1 is not a static one. It is expanded over what it was a few years ago and is continuing to expand. Try, in an imaginative yet serious manner, to suggest techniques not listed in the table. Explain what their values might be and, of course, propose a suitable acronym for each. 

As might be expected, this simple picture does not hold perfectly. The coefficient of friction tends to increase with increasing velocity and also is smaller if the pavement is wet [14]. On a wet road, /x may be as small as 0.2, and, in fact, one of the principal reasons for patterning the tread and sides of the tire is to prevent the confinement of a water layer between the tire and the road surface. Similarly, the texture of the road surface is important to the wet friction behavior. Properly applied, however, measurements of skid length provide a conservative estimate of the speed of the vehicle when the brakes are first applied, and it has become a routine matter for data of this kind to be obtained at the scene of a serious accident. 

A number of friction studies have been carried out on organic polymers in recent years. Coefficients of friction are for the most part in the normal range, with values about as expected from Eq. XII-5. The detailed results show some serious complications, however. First, n is very dependent on load, as illustrated in Fig. XlI-5, for a copolymer of hexafluoroethylene and hexafluoropropylene [31], and evidently the area of contact is determined more by elastic than by plastic deformation. The difference between static and kinetic coefficients of friction was attributed to transfer of an oriented film of polymer to the steel rider during sliding and to low adhesion between this film and the polymer surface. Tetrafluoroethylene (Telfon) has a low coefficient of friction, around 0.1, and in a detailed study, this lower coefficient and other differences were attributed to the rather smooth molecular profile of the Teflon molecule [32]. 

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