Recovery methods

Enhanced oil recovery (EOR) techniques seek to produce oil which would not be recovered using the primary or secondary recovery methods discussed so far. Three categories of enhanced oil recovery exist ... 

Gas fractionation plants require considerable investment and in many situations would not be economic. However, less complete NGL recovery methods may still prove cost effective. 

A considerable percentage (40% - 85%) of hydrocarbons are typically not recovered through primary drive mechanisms, or by common supplementary recovery methods such as water flood and gas injection. This is particularly true of oil fields. Part of the oil that remains after primary development is recoverable through enhanced oil recovery (EOR) methods and can potentially slow down the decline period. Unfortunately the cost per barrel of most EOR methods is considerably higher than the cost of conventional recovery techniques, so the application of EOR is generally much more sensitive to oil price. 

NMR spectroscopy is always struggling for increased sensitivity and resolution, as well as more efficient use of the instrument time. To this end, numerous improvements of the simple inversion-recovery method have been proposed over the years. An early and unportant modification is the so-called fast mversion recovery... 

The well-known inaccuracy of numerical differentiation precludes the direct calculation of pressure by the insertion of the computed velocity field into Equation (3.6). This problem is, however, very effectively resolved using the following variational recovery method Consider the discretized form of Equation (3.6) given as... 

Note that the displacements are found using the working equations of the scheme stresses are found via the variational recovery method. 

STRESS. Applies the variational recovery method to calculate nodal values of pressure and, components of the stress. A mass lumping routine is called by STRESS to diagonalize the coefficient matrix in the equations to eliminate the... 

Normally, a slight excess of sulfuric acid is used to bring the reaction to completion. There are, of course, many side reactions involving siHca and other impurity minerals in the rock. Fluorine—silica reactions are especially important as these affect the nature of the calcium sulfate by-product and of fluorine recovery methods. Thermodynamic and kinetic details of the chemistry have been described (34). 

Pish silage prepared by autolysis of rainbow trout viscera waste was investigated as a substrate for the plastein reaction using pepsin (pH 5.0), papain (pH 6—7), and chymotrypsin (pH 8.0) at 37°C for 24 h (152). Precipitation with ethanol was the preferred recovery method. Concentration of the protein hydrolysate by open-pan evaporation at 60°C gave equivalent yields and color of the final plastein to those of the freeze-dried hydrolysate. 

Compression. Compression is the simplest and the least effective of the four recovery methods. It was the first process used for the recovery of hydrocarbon Hquids from natural gas but is used only ia isolated cases. The most significant appHcation of the compression process is for gas-cycling plants where the natural gas Hquids are removed and the remaining gas is returned to the production formation. Figure 3 is a schematic of a typical gas-cycle plant. 

Other recovery methods have been used (10). These include leaching ores and concentrates using sodium sulfide [1313-82-2] and sodium hydroxide [1310-73-2] and subsequentiy precipitating with aluminum [7429-90-3], or by electrolysis (11). In another process, the mercury in the ore is dissolved by a sodium hypochlorite [7681-52-9] solution, the mercury-laden solution is then passed through activated carbon [7440-44-0] to absorb the mercury, and the activated carbon heated to produce mercury metal. Mercury can be extracted from cinnabar by electrooxidation (12,13). 

The definition of heavy oil is usually based on API gravity or viscosity, but the definition is quite arbitrary. Although there have been attempts to rationalize the definition based on viscosity, API gravity, and density (2,3), such definitions, based on physical properties, are inadequate, and a more precise definition would involve some reference to the recovery method. 

Recovery methods are based either on mining combined with some further processing or operation on the oil sands m situ (Fig. 6). The mining methods are appHcable to shallow deposits, characterized by an overburden ratio (ie, overburden depth-to-thickness of tar sand deposit) of ca 1.0. Because Athabasca tar sands have a maximum thickness of ca 90 m and average ca 45 m, there are indications that no more than 10% of the in-place deposit is mineable within 1990s concepts of the economics and technology of open-pit mining. 

Feed Composition. Feed composition has a substantial effect on the economics of a distillation. Distillations tend to become uneconomical as the feed becomes dilute. There are two types of dilute feed cases, one in which the valuable recovered component is a low boiler and the second when it is a high boiler. When the recovered component is the low boiler, the absolute distillate rate is low but the reflux ratio and the number of plates is high. An example is the recovery of methanol from a dilute solution in water. When the valuable recovered component is a high boiler, the distillate rate, the reflux relative to the high boiler, and the number of plates all are high. An example for this case is the recovery of acetic acid from a dilute solution in water. For the general case of dilute feeds, alternative recovery methods are usually more economical than distillation. 

The annualized capital cost (ACC) is the product of the CRF and TCC and represents the total instaUed equipment cost distributed over the lifetime of the project. The ACC reflects the cost associated with the initial capital outlay over the depreciable life of the system. Although investment and operating costs can be accounted for in other ways such as present-worth analysis, the capital recovery method is preferred because of its simplicity and versatUity. This is especiaUy true when comparing somewhat similar systems having different depreciable lives. In such decisions, there are usuaUy other considerations besides economic, but if all other factors are equal, the alternative with the lowest total annualized cost should be the most viable. 

Micromechanical theories of deformation must be based on physical evidence of shock-induced deformation mechanisms. One of the chapters in this book deals with the difficult problem of recovering specimens from shocked materials to perform material properties studies. At present, shock-recovery methods provide the only proven teclfniques for post-shock examination of deformation mechanisms. The recovery techniques are yielding important information about microscopic deformations that occur on the short time scales (typically 10 -10 s) of the compression process. 

The technique for measurement which is most easily interpreted is the inversion-recovery method, in which the distribution of the nuclear spins among the energy levels is inverted by means of a suitable 180° radiofrequency pulse A negative signal is observed at first, which becomes increasingly positive with time (and hence also with increasing spin-lattice relaxation) and which... 

Static pressure recovery method. The diameters are selected in such a way that the same static pressure is available before every connection. The duct reduction is selected in such a way that the gain of static pressure is in balance with the friction losses up to the next connection point. This method may result in fewer control devices at connection points or outlets. Low velocities and large diameters at the end of the system may be the result of this design approach. 

Recovery methods, including adsorption, absorption and condensation... 

Concentration and Composition The average concentration of organic compounds in a waste gas determines the applicability of the abatement method. Recovery methods usually require high inlet concentrations. They may need a concentrator prior to actual treatment, which increases the investment cost. 

The technologies used in the control of gaseous organic compound emissions include destruction methods such as thermal and catalytic incineration and biological gas treatment and recovery methods such as adsorption, absorption, condensation, and membrane separation. The most common control methods are incineration, adsorption, and condensation, as they deal with a wide variety of emissions of organic compounds. The most common types of control equipment are thermal and fixed-bed catalytic incinerators with recuperative heat recovery, fixed-bed adsorbers, and surface condensers. The control efficiencies normally range between 90% and 99%. 

The sulfur is carried to the top of the oxidizer by a froth created by the aeration of the solution and passes into the thickener. The function of the thickener is to increase the weight percent of sulfur, which is pumped to one of the alternate sulfur recovery methods. 

Secondary recovery, infill drilling, various pumping techniques, and workover actions may still leave oil, sometimes the majority of the oil, in the reservoir. There are further applications of technology to extract the oil that can be utilized if the economics justifies them. These more elaborate procedures are called enhanced oil recovery. They fall into three general categories thermal recoveiy, chemical processes, and miscible methods. All involve injections of some substance into the reservoir. Thermal recovery methods inject steam or hot water m order to improve the mobility of the oil. They work best for heavy nils. In one version the production crew maintains steam or hot water injection continuously in order to displace the oil toward the production wells. In another version, called steam soak or huff and puff, the crew injects steam for a time into a production well and then lets it soak while the heat from the steam transfers to the resei voir. After a period of a week or more, the crew reopens the well and produces the heated oil. This sequence can be repeated as long as it is effective. 

The alternative large scale recovery method to precipitation is ultrafiltration. For concentration of viscous exopolysaccharides, ultrafiltration is only effective for pseudoplastic polymers (shearing reduces effective viscosity see section 7.7). Thus, pseudoplastic xanthan gum can be concentrated to a viscosity of around 30,000 centipoise by ultrafiltration, whereas other polysaccharides which are less pseudoplastic, are concentrated only to a fraction of this viscosity and have proportionally lower flux rates. Xanthan gum is routinely concentrated 5 to 10-fold by ultrafiltration. 

Early methods of following the reaction relied upon quantitative recovery of the anthracene derivative from the reaction mixture and in view of the extreme insolubility of these derivatives, this is one of the few reactions that can be accurately studied by product recovery methods. More recently, of course, the uv spectroscopic method has been used, the formation of the anthracene spectrum with time being measured. 

Thermal recovery methods involve the use of steam and in-situ combustion. Thermal EOR processes add heat to the reservoir to reduce the viscosity of the oil or to vaporize it. In addition, these processes use steam or oil combustion... 

When or if the reservoir is successfully simulated, the engineer can turn to optimizing petroleum recovery, and theoretical ideas can be applied to models for various enhanced recovery methods to select optimal procedures and schedules (see Chapter 7). 

Coal used in power stations has the potential to be partly replaced by fuels derived from pre-treated plastics and paper waste, reducing both dependency on fossil fuels and reliance on landfill. APME reports on a project in the Netherlands which it co-sponsored to develop a substitute fuel from plastics. The environmental assessment of the project compared the environmental impacts of coal substitution with other plastics recovery methods, including gasification in feedstock recycling and energy recovery from plastics waste in cement kilns. The study also compared coal substitution with the generation of power from burning biomass. 

Cobalt catalysts such as HCo(CO)4 are widely used for hydroformyla-tion of higher alkenes, despite the higher temperatures and pressures required. The main reason for this is that these catalysts are also efficient alkene isomerization catalysts, allowing a mix of internal and terminal alkenes to be used in the process. Catalyst recovery is more of a problem here, involving production of some waste and adding significantly to the complexity of the process. A common recovery method involves treating the catalyst with aqueous base to make it water soluble, followed by separation and subsequent treatment with acid to recover active catalyst (4.3). 

Approximately 60% to 70% of the oil in place cannot be produced by conventional methods [22]. Enhanced oil-recovery methods gain importance in particular with respect to the limited worldwide resources of crude oil. The estimated worldwide production from enhanced oil-recovery projects and heavy-oil projects at the beginning of 1996 was approximately 2.2 million barrels per day (bpd). This is approximately 3.6% of the world s oil production. At the beginning of 1994, the production had been 1.9 million bpd [1254]. 

Micellar flooding is a promising tertiary oil-recovery method, perhaps the only method that has been shown to be successful in the field for depleted light oil reservoirs. As a tertiary recovery method, the micellar flooding process has desirable features of several chemical methods (e.g., miscible-type displacement) and is less susceptible to some of the drawbacks of chemical methods, such as adsorption. It has been shown that a suitable preflush can considerably curtail the surfactant loss to the rock matrix. In addition, the use of multiple micellar solutions, selected on the basis of phase behavior, can increase oil recovery with respect to the amount of surfactant, in comparison with a single solution. Laboratory tests showed that oil recovery-to-slug volume ratios as high as 15 can be achieved [439]. 

The problems of enhanced oil-recovery methods have been summarized by Bragg [230] ... 

The state of the art in chemical oil recovery has been reviewed [1732]. More than two thirds of the original oil remains unrecovered in an oil reservoir after primary and secondary recovery methods have been exhausted. Many chemically based oil-recovery methods have been proposed and tested in the laboratory and field. Indeed, chemical oil-recovery methods offer a real challenge in view of their success in the laboratory and lack of success in the field. The problem lies in the inadequacy of laboratory experiments and the limited knowledge of reservoir characteristics. Field test performances of polymer, alkaline, and micellar flooding methods have been examined for nearly 50 field tests. The oil-recovery performance of micellar floods is the highest, followed by polymer floods. Alkaline floods have been largely unsuccessful. The reasons underlying success or failure are examined in the literature [1732]. 

---